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  • Polymer and Materials Science  (13)
  • Prostaglandins
  • 1990-1994  (9)
  • 1985-1989  (6)
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 188 (1987), S. 651-663 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The transition from the nematic melt to the solid state in a rigid rod-like copolymer was found to be characterized by unusual thermodynamic and kinetic properties. The transition occurred with negligible volume changes. The enthalpy and the entropy of the transition were found to be lower by at least one order of magnitude in comparison to the values usually observed for a crystal to nematic transition. The ordered solid state displays a glass transition and its structure is characterized by high symmetry, i.e., an orthorhombic one. Dielectric relaxation studies, investigations on the plastic flow properties of the solid state and studies on the dynamical mechanical properties revealed a high degree of rotational freedom already at room temperature in the solid state. These experimental findings led us to the conclusion that the solid state displays a three-dimensional positional long range order but is rotationally disordered with respect to rotations about the long axes of the rod-like molecules. The structure is similar to those of plastic crystals known for spherical molecules such as cyclopentane, or to smectic E modifications known for rod-like molecules. Also the properties reported above for the rod-like copolymers resemble those reported in the literature for plastic crystals.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 1399-1414 
    ISSN: 0887-624X
    Keywords: plasma polymers ; oxidation ; XPS ; FTIR ; SEM ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Long-term compositional changes were observed when n-hexane plasma polymers were stored in air at ambient temperature. These post-deposition changes were monitored over periods exceeding one year using XPS, grazing angle FTIR, and SEM. A rapid initial increase in the oxygen content was followed by a slower oxygen uptake, which continued for many months. In contrast to the reported autocatalytic acceleration of the oxidation of polyolefins, the rate of oxidation of n-hexane plasma polymers was found to decrease continuously, and it did not proceed to the same extent toward higher oxidation states. The plasma polymer coatings did not show physical manifestations of oxidative degradation such as cracking, reduction in thickness, or loss of physical integrity. Comparison of the XPS and FTIR data suggested that the top few nanometers of the plasma polymer coatings oxidized at a faster rate than the “bulk.” The experimental data were interpreted using a model comprising reactions known from the oxidative degradation of polyolefins: carbon-centered radicals, trapped in the course of the plasma deposition, combine with atmospheric oxygen to form metastable peroxy radicals and hydroperoxides, which decompose to generate a variety of stable product groups such as hydroxyl, carbonyl, and carboxylic groups. There was broad agreement between the XPS data and the time dependence of particular species in model calculations. © 1994 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 4 (1992), S. 690-691 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Advanced Materials 2 (1990), S. 497-498 
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
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  • 6
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The preconcentration voltammetric behavior of technetium at a carbon paste electrode modified with thenoyltrifluoroacetone (TTA) has been investigated. It is demonstrated that enrichment of technetium on the electrode surface by complex formation with TTA is possible. Deposition of Tc(IV) takes place due to a purely chemical reaction resulting probably Tc(TTA)4. Enhanced accumulation occurs if a reductive electrode potential of -0.4 V is applied, which presumably causes fixation in the form of Tc(TTA)3. In the subsequent voltammetric scan a characteristic peak at about -40 and +40 mV, respectively, is obtained. Tc(VII) is not deposited, unless a reduction potential of at least -0.6 V is applied, with the pH of the solution optimally chosen at 3.5. Therefore, it is possible to discriminate between Tc(IV) and Tc(VII).
    Additional Material: 5 Ill.
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  • 7
    ISSN: 1045-4861
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Numerous carrier systems have been developed for the controlled delivery of biologically active molecules such as drugs and diagnostic agents. The biophysical interactions between the biologically active molecules and their carriers, however, may denature the former and lead to reduced biological activity. In this study, a model nondenaturing carrier comprised of a nanocrystalline (10-7 m) tin oxide core and a surface-charge-reducing organic bonding layer (GF292) was synthesized. A subsequently bound protein (human transferrin) showed significant retained conformation by immunoelectron microscopy. In the synthesis of targeted drug systems and vaccines, nanocrystalline cores treated with appropriate surface-modifying agents may be suitable carriers.
    Additional Material: 5 Ill.
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  • 8
    ISSN: 0009-286X
    Keywords: Kunststoffe ; Rohrleitungen ; Schwei7szlig;en ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 9
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methods of immobilizing soil contamination. A number of remedial measures can bei applied to contain or immobilize contaminants which threat to pollute groundwater, soil or air. Some are still conceptional in character, others are in practical use. So far, bentonite/cement-based slurry walls have often been constructed to regulate the groundwater flow in contaminated areas. In general, clay layers are used as bottom seal whenever available. Investigations, however, have shown that conventional and many natural materials do not exhibit the resistance to aggressive leachates which is necessary to retain the contamination over extended periods of time. In the proposed concept a partial or complete encapsulation of the contamination is recommended using barriers resistent to aggressive leachates, thus containing the contamination. This can be achieved by new silica gel containing materials and in some cases by suitable geotextiles. Extensive tests of such materials are presently under way at various abandoned waste sites in the F. R. Germany. Remedial action can then be planned and executed to decontaminate the site in ample time and without the risk of further contamination. New results are reported obtained during a one year test period with water glass of low alkalinity and high SiO2/Na2O ratio. Their resistance to leachates, low syneresis, and high hardness was accomplished by the two-component system Dynagrout PPN, developed by Dynamit Nobel.
    Additional Material: 1 Ill.
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  • 10
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Rigid chain molecules have the tendency to display fluid liquid crystalline phases within a limited temperature range. This range depends on the particular chemical structure of the chain molecules. The chain rigidity as well as the intrinsic dynamical and elastic properties of the liquid crystalline melt can successfully be used to obtain high strength, high stiffness polymers, which can be melt processed. The rigid chain polymers display unusual thermodynamical, dynamical, structural, rheological and mechanical properties.
    Additional Material: 9 Ill.
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