ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Polymer and Materials Science  (82)
  • COMMUNICATIONS AND RADAR  (5)
  • 1990-1994  (28)
  • 1985-1989  (25)
  • 1980-1984  (34)
  • 1920-1924
  • 1
    Electronic Resource
    Electronic Resource
    Ca2+ binding cyclic octapeptides having an alternating sar and a hydrophobic amino acid in the sequence (1989)
    New York : Wiley-Blackwell
    Biopolymers 28 (1989), S. 1235-1246 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyclic octapeptides having alternating Sar and hydrophobic amino acid sequences, such as cyclo[Lys(Z)-Sar-Leu-Sar-Leu-Sar-Leu-Sar] (C8KL), cyclo[Glu(OMe)-Sar-Lys(Z)-Sar-Leu-Sar-Leu-Sar] (C8KE), and cyclo[Lys(Suc)-Sar-Leu-Sar-Leu-Sar-Leu-Sar][C8K(Suc)L, Suc represents succinic acid], were synthesized. These cyclic octapeptides formed a complex selectively with Ca2+. Upon complexation, trans peptide bonds of Sar residues were isomerized to cis peptide bonds. C8KL and C8KE showed very similar characteristics of Ca2+ binding, extraction of Ca2- from an aqueous solution to a chloroform solution, and Ca2+ transport through a liquid chloroform membrane. C8KL transported Ca2+ across the lipid bilayer membrane above the phase-transition temperature, while C8KE and C8K(Suc)L did not. Therefore, the transport of Ca2+ through the lipid bilayer membrane is very sensitive to the hydrophobicity of the carrier molecule.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360280705
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Antistatic modification of polyester with carboxyterminated poly(oxyethylene) (1994)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 217 (1994), S. 129-137 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Carboxy-terminierte Polyoxyethylene (PEO-acid) mit zahlenmittleren Molekulargewichten Mn = 8400, 3300 und 1000 wurden zur antielektrostatischen Modifizierung von Polyethylenterephthalat (PET) verwendet. Fasern aus PET-PEO-acid-Blends mit 2,0 oder 5,0 Gew.-% PEO-acid wurden bei 285°C mit einem normalen Extruder aus der Schmelze gesponnen und anschließend bei 80°C um das ca. 4,5fache verstreckt. Die Verarbeitbarkeit beim Verspinnen und Verstrecken war bei Verwendung von PEO-acid mit hohen Molekulargewichten ausgezeichnet. Die anti-elektrostatischen Eigenschaften wurden ebenfalls mit steigendem PEO-acid-Molekulargewicht besser. Da eine Umesterung beim Verspinnen nur in geringem Ausmaß stattfand, blieben die mechanischen Eigenschaften der Blend-Fasern gegenüber den PET-Fasern nahezu unverändert.
    Notes: Carboxy-terminated poly(oxyethylenes) (PEO-acid) with number-average molecular weights Mn = 8400, 3300, and 1000 were used for antielectrostatic modification of poly(ethylene terephthalate) (PET). The blend PET fibers containing 2.0 and 5.0 wt.-% of PEO-acids were melt-spun at 285°C with an ordinary extruder and then drawn about 4.5-fold at 80°C. The processabilities of spinning and drawing were excellent at higher molecular weights of PEO-acid. The anti-electrostatic properties of the blend fibers became also improved with increasing molecular weight of PEO-acid. Since little ester interchange reaction took place between PET and PEO-acid during meltspinning, the blend fibers could retain almost the same mechanical properties as the original PET fiber.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1994.052170113
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Strategy for the synthesis of large peptides: An application to the total synthesis of human parathyroid hormone [hPTH(1-84)] (1981)
    New York : Wiley-Blackwell
    Biopolymers 20 (1981), S. 1823-1832 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A strategy suitable for the synthesis of larger peptides is proposed. It involves the following four considerations: (1) all of the side-chain functional groups are protected by benzyl-type protective groups; (2) a water-soluble carbodiimide, 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide, is used for the fragment-condensation reactions together with 1-hydroxybenzotriazole as the additive; (3) all the protective groups are cleaved simultaneously by the HF method in the final stage of the synthesis; and (4) side products formed are detected and removed by an efficient high-performance liquid chromatography procedure. The usefulness of these procedures is demonstrated taking the synthesis of human parathyroid hormone [hPTH(1-84)] as an example.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1981.360200907
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Synthesis and conformation of the cyclic octapeptides cyclo(Phe-Pro)4, cyclo(Leu-Pro)4, and cyclo[Lys(Z)-Pro]4 (1983)
    New York : Wiley-Blackwell
    Biopolymers 22 (1983), S. 2191-2206 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cyclic octapeptides, cyclo(X-Pro)4, where X represents Phe, Leu, or Lys(Z), were synthesized and their conformations investigated. A C2-symmetric conformer containing two cis peptide bonds was found in all of these cyclic octapeptides. The numbers of available conformations due to the cis-trans isomerization of Pro peptide bonds depended on the nature of the solvent and X residue: they decreased in the following order: cyclo[Lys(Z)-Pro]4 〉 cyclo(Leu-Pro)4 〉 cyclo(Phe-Pro)4 in CDCl3. 13C spin-lattice relaxation times (T1) of these cyclic octapeptides were measured, and the contribution of segmental mobility to T1 was found to vary with the nature of the X residue.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360221006
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Computer building of β-helical polypeptide models (1984)
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 23-38 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A general method is presented for computing the atomic coordinates of helices in which a dipeptide is the repeating unit. The method will generate both single- and double-stranded model helices having idealized bond lengths and angles, and any arbitrary, user-specified, pitch and number of residues per turn. The variation of inter- and intrastrand hydrogen bonds with pitch and number of residues per turn can thus be examined. An application of the method is the construction of a β-helix having pitch of 6.3 Å per turn and 4.85 residues per turn, a model which can pack nicely into the unit cell of crystals of cation-bound gramicidin A.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360230104
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    The cystine-stabilized α-helix: A common structural motif of ion-channel blocking neurotoxic peptides (1991)
    New York : Wiley-Blackwell
    Biopolymers 31 (1991), S. 1213-1220 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Neurotoxic peptides from venoms of scorpions and honey bees exhibit a consensus pattern in the two disulfide bridgings related to the sequence portions Cys-X-Cys and Cys-X-X-X-Cys. A revised three-dimensional structure of charybdotoxin, as determined by two-dimensional nmr spectroscopy, confirms that the consensus cystine dislocation generates in all these toxins a common structural element, i.e., the cystine-stabilized α-helical (CSH) motif, which may be correlated with their common ion channel blocking activity.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360311009
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    Reactivity of N-alkylated cyclic iminoether salts having vinyl groups, 2Part 1: cf.9. Polymerization and copolymerization of 2-isopropenyl-3-methyl-2-oxazolinium salts (1986)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 187 (1986), S. 1807-1817 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: 3-Methyl-2-isopropenyl-2-oxazolinium salts (4a, b) were prepared by alkylation of 2-isopropenyl-2-oxazoline (2). Their preparation is much easier than that of their vinyl analogues, 3-methyl-2-vinyl-2-oxazolinium salts, which cannot be isolated due to their high tendency to polymerization. 4a, however, was found, to show a low tendency toward radical and anionic polymerization, but it can be smoothly radically copolymerized with some vinyl monomers. The copolymerization parameters of 4a were determined and discussed in comparison with those of 2.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1986.021870801
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    A peculiar temperature-dependent behavior of iodine species at the formation of chromophore between iodine and aqueous poly(vinyl alcohol) (1984)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 185 (1984), S. 749-755 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The blue colored complex between poly(vinyl alcohol) (PVA) and iodine was prepared at 5°C by mixing an aqueous solution of PVA with an aqueous ethanolic solution of iodine containing boric acid. The absorption spectrum of the system shows bands at 226 nm (A), 290 nm (B), 355 nm (C), and 650 nm (D). Their relative absorbances change largely depending on temperature. When the system is gradually warmed, the chromophoric band D decays and the intensity of band A increases. By lowering the temperature again to 5°C the concentration of chromophore increases. It was found that the decay and the re-formation of the chromophore are reversible in the temperature range 5 to 15°C. Above 15°C, contrarily, hysteresis effects are encountered for the re-formation. Thus, when the chromophore is re-formed at 5°C, the spectra shows an isosbestic point at 420 nm, between bands C and D. The dependence on temperature of bands B and C is quite independent from each other, which strongly indicates that the latter band should be assigned to another iodide species than the I-3 ion (band B) and the I- ion (band A). Based on these experimental data a new mechanism is proposed involving the complex ion I-3 · I2 which is supposed to be a precursor of the chromophoric pentaiodide ion I5-.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1984.021850411
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    13C NMR study of O-(2-hydroxypropyl)cellulose (1985)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 186 (1985), S. 61-70 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The proton-decoupled signal of methyl carbons of O-(2-hydroxypropyl)cellulose (HPC) (1b, m ≥ 1) was found to be split into two peaks. The results of experiments on lanthanide shift and the dependence of the relative intensities of both peaks on the molecular weight of poly(oxypropylene) [poly(propylene oxide)] (PPO) indicated that the low-field peak results from the terminal hydroxypropyl groups and the high-field peak from the inside oxypropylene units. From the ratio between the intensities of the two peaks and the molar substitution (MS) (average number of oxypropylene units per anhydroglucose (AHG) unit), the degree of substitution (DS) (average number of hydroxyl groups substituted per AHG unit) was calculated. This new method could be applied to samples of low-MS to which the conventional method based on the 1H NMR technique alone was inapplicable. From the analysis of 13C NMR spectra of HPC samples differing in MS, an authentic structural picuture of the HPC molecule could be proposed.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1985.021860107
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Characteristics of rectifying devices with thin films of polyphthalocyanine (1989)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 190 (1989), S. 2693-2701 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Chemically and thermally stable thin films of polyphthalocyanine were prepared by a simple evaporation-polymerization method. The rectifying characteristics of metal/semiconductor/metal (MSM) type sandwich devices with the film were studied. A Schottky type device metal (Cu, Al, Ti)/polyphthalocyanine/Cu shows reproducible rectifying characteristics when Ti is selected as a counter electrode. The reproducibility is improved by pre-oxidation treatment of the surface of Cu substrate. Best electric parameters for the device are as follows: rectifying ratio = 14; threshold potential difference = 0,61 V; saturation current = 2,5 · 10-6 A · cm-2; barrier height = 0,75 eV; diode ideality parameter = 4,23. Doping of five kinds of quinones [p-benzoquinone (p-BQ), tetrabromo-p-benzoquinone (p-TBBQ) tetrachloro-p-benzoquinone (p-TCBQ) tetrachloro-o-benzoquinone (o-TCBQ) 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ)] and 2,5-cyclohexadien-1,4-diylidenedimalodinitrile (TNCR) in thin films of polyphthalocyanine affected electrocharacteristics in some cases. The diode ideality parameter decreases to 2,17 at 0,90 · 10-6 mol · cm-1 of p-TBBQ, and the rectifying ratio increases to about fourteen times by doping p-TBBQ and p-TCBQ. The doped device shows a rectifying response up to 1 kHz.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1989.021901103
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...