ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
catena-Poly[cadmium-[μ-(2-aminoethanol-N:O)-μ-[μ-cyano-1κN:2κC– [trans-bis(cyano-C)nickel(II)]-μ-cyano-1κN:2κC]-μ-(1,5-diaminopentane-N:N')]], [Cd{Ni(CN)4}(C2H7NO)(C5H14N2)], (1), has a three-dimensional structural unit comprised of a distorted Cd-cornered rectangular box edged by catena-μ-1,5-diaminopentane, catena-μ-2-aminoethanol and catena-μ-trans-NC-Ni(CN)2-CN bridges. The void space in one of the frameworks is filled with another to give a doubly interpenetrating framework structure. catena-Poly[[(2-aminoethanol-N,O)cadmium]-[μ-[μ-cyano-1κN:2κC– [trans-bis(cyano-C)nickel(II)]-μ-cyano-1κN:2κC]-μ-(1,6-diaminohexane-N:N')] monohydrate], [Cd{Ni(CN)4}(C2H7NO)(C6H16N2)].H2O, (2), contains 2-aminoethanol ligands chelated to Cd, which decreases the number of catena-μ-bridges about the Cd2+ ion to four, two each of catena-μ-1,6-diaminohexane and catena-μ-trans-NC-Ni(CN)2-CN, giving a distorted adamantoid unit. The void space is occupied by two other frameworks and a water molecule to give a triply interpenetrated framework.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270195011899
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