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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    European journal of soil science 47 (1996), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The analysis of free lipids in 12 soils from three representative types of Mediterranean forest has been carried out in an attempt to describe diagnostic molecules reflecting differences between the ecosystems and the intensity of the soil organic matter turnover. The study centred on the analysis by gas chromatography–mass spectrometry of the soil compounds extracted with petroleum ether from soils in central Spain, developed under monospecific formations of stone pine (Pinus pined), evergreen oak (Quercus rotundifolia) and Spanish juniper (Juniperus thurifera), the lipid extracts from their leaves also being analysed as reference material.The comparison between the distribution patterns of alkanes and fatty acids in plant lipids and the corresponding soil lipids was used to assess the extent to which the former accumulate in soil or are substituted by other biogenic or diagenetic homologues. In general, the alkane patterns showed the greatest variation in soils under oak, and the differences between lipid patterns in plant and soil were greatest in the juniper forests. As indicators of the vegetation type, the soil fatty acids had little value.Up to 60 major cyclic compounds were identified, including mainly di- and sesquiterpenes, in addition to some monoterpenes and nonterpenic naphthalenes and decalins. Of these major constituents, 33 compounds were found in soil but were not present in plant extracts, and 18 compounds were identified in plants but were not in the soils. The results suggest an arrangement of the soil samples based on the composition of the signature lipid assemblages.
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 69 (1996), S. 764-766 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Carbon nitride thin films obtained by dual ion beam sputtering have been investigated by electron energy-loss spectroscopy (EELS), transmission electron microscopy, and Fourier transform infrared spectroscopy. The nitrogen content in the films depends on deposition conditions. A maximum value of N/C=0.8 has been achieved. A new peak at 286.7 eV energy loss in the C K-edge EELS spectra has been assigned to C=N bonds with C in the sp2 hybridization state. In addition, experimental evidences are presented of the formation of β-C3N4 crystallites embedded in a layer of a polymer like CNx amorphous phase. An evaluation of the experimental parameters that lead to the highest N content in the films is also included. © 1996 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 4655-4660 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 49 (1998), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Frequent applications of chicken manure to a volcanic-ash soil resulted in an increased crop yield several years after the applications ceased. Improved nutrient cycling through the soil organic matter (SOM) was thought be the cause of this. An area that for several years had been under either unimproved fallow or continuous bean-maize intercropping (with chicken manure application) was planted with maize intercropped with the legume Arachis pintoi. Soil samples were fractionated into several sizes of aggregates and incubated for 6 weeks in intact form and after crushing the aggregates. Between 1.2 and 3.1% of the C in any aggregate size class exited in easily decomposable (i.e. not physically or chemically protected) form. Less than 0.8% of the macroaggregate C was physically protected by the aggregate structure. More than 97% of the C in any aggregate size class can be considered resistant. The large-or small-macroaggregate-protected SOM (i.e. in aggregates 〉 2000 μm and 250–2000 μm, respectively). once made available, was more easily decomposed than the unprotected SOM. The large SOM content (45.8–57.3 g C kg−1) but yet limited mineralizability indicates that mechanisms other than soil macroaggregation are important for protecting SOM in this soil. Binding of organic molecules onto allophane minerals is likely to be such a mechanism.The larger yield and nutrient uptake by the maize in the former bean-maize plots compared with the former fallow plots could not be explained by differences in SOM decomposition. We think that the frequent application of chicken manure to the former bean-maize plots increased the available phosphorus in these strongly P-sorbing soils by increasing the cycling of organic-P or by blocking some of the P-reactive sites. This, however, needs to be further investigated.
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  • 5
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 982-988 
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The crystal structure of Pb(O3PC6H5) has been solved from X-ray powder diffraction data. Crystal data: triclinic, a = 13.6907 (5), b = 9.3327 (4), c = 7.0432 Å, α = 106.188 (3), β = 94.927, γ = 96.977°, V = 851.04 (8) Å3, space group P{\bar 1} and Z = 4. Initial positional parameters for Pb atoms were obtained from direct methods using 556 structure factors in the 2θ range 9–63°. All remaining non-H atoms were located from successive difference-Fourier maps. The final agreement factors were Rwp = 0.055, Rp = 0.042 and RF = 0.017. There are 22 atoms in the asymmetric part of the unit cell and 66 positional parameters have been refined with the help of soft constraints. The lead coordination environment is irregular due to a marked inert pair effect. The three-dimensional structure of this organic inorganic compound is layered with inorganic layers built up from CPO3 tetrahedra and PbO6 units. 31P MAS and CP-MAS (cross-polarization magic angle spinning) NMR studies have been carried out to confirm the triclinic symmetry with two independent structural units. In optimum conditions two 31P resonance signals are observed, indicating that there are two crystallographically independent P atoms with closely similar environments. The thermal behavior of this material has been studied and the thermal decomposition products identified.
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  • 6
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 376 (1995), S. 473-473 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] FISHER ETAL. REPLY - The comments by Davidson et al. about the rainforests and the wooded communities of the cerrados are not relevant to our paper1, which was about the 35 million hectares (MHa) of treeless grasslands in Colombia and Venezuela and the 50 MHa (24%) of the cerrados of ...
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 376 (1995), S. 731-732 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SIR - Beach deposits of the Arenisca de Aren Formation1 (southern Pyrenees, Maastrichtian, Upper Cretaceous) are rich in dinosaur eggs and bones, distributed over an area of about 15 km2 along the northern flank of the Tremp syncline (Fig. 1). At one locality (Bastus, Lleida) ...
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Applied microbiology and biotechnology 46 (1996), S. 587-592 
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract Antibiotics can disturb the production of biogas during anaerobic digestion. This study shows a systematic approach to understanding how the different bacterial populations involved in the final conversion of organic matter into methane are inhibited by 15 antimicrobial agents with different specificities and modes of action. The results obtained show the following trends: (i) some inhibitors, such as the macrolide erythromycin, lack any inhibitory effect on biogas production; (ii) some antibiotics, with different specificities, have partial inhibitory effects on anaerobic digestion and decrease methane production by interfering with the activity of propionic-acid- and butyric-acid-degrading bacteria,␣(e.g. antibiotics that interfere with cell wall synthesis, RNA polymerase activity and protein synthesis, especially the aminoglycosides); (iii) the protein synthesis inhibitors chlortetracycline (IC50 40 mg l−1) and chloramphenicol (IC50 15–20 mg l−1) are very powerful inhibitors of anaerobic digestion. The majority of the antibiotics tested lacked activity against acetoclastic methanogens, being active only on the acetogenic bacteria. However, chloramphenicol and chlortetracycline could cause the complete inhibition of the acetoclastic methanogenic archaea.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Applied microbiology and biotechnology 47 (1997), S. 324-328 
    ISSN: 1432-0614
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract The toxicity of chlorinated aliphatic hydrocarbons on acetoclastic methanogens in anaerobic granular sludge was determined using a standardized anaerobic bioassay method. Most of the chloroaliphatics tested were strong inhibitors of methanogenesis. Tri- and tetrachloride derivatives of methane and ethane were the most highly toxic compounds tested, with concentrations of less than 18 mg/l resulting in 50% inhibition (IC50) of the methanogenic activity. Dichlorinated compounds were less toxic, with IC50 values ranging from 40 mg/l to 100 mg/l. On the other hand, perchlorinated derivatives of ethane and ethene were scarcely inhibitory at concentrations near their maximum water solubility. The toxicity caused by chlorinated aliphatic hydrocarbons was reversible. The comparison of structurally related compounds indicated that unsaturated chloroaliphatics were less toxic than their saturated counterparts. A reverse correlation between the electric dipole moment of these compounds and their methanogenic toxicity is discussed.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Oecologia 103 (1995), S. 358-364 
    ISSN: 1432-1939
    Keywords: Clutch size ; Energy constraints ; Ficedula hypoleuca ; Pied Flycatcher ; Reproductive success
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract We performed a food provisioning experiment in a population of Pied Flycatchers Ficedula hypoleuca breeding at high altitude in central Spain to test if food availability before and during laying determines clutch size. Food was provided to one of two pairs with the same date of initiation of nest-building (15 dyads of subsequently reproducing pairs were thus created). Food provisioning began on the day of initiation of nest-building and ended on the day after the last egg was laid. Although laying date was unaffected by the experiment, clutch size in the experimental treatment was significantly larger. This result could indicate that food availability at laying (1) proximately constrained clutch size or (2) that females evaluated future conditions for incubating eggs and feeding nestlings based on food availability at laying. Reproductive success (proportion of eggs that resulted in fledged young) was significantly reduced in the experimental treatment. This effect suggest that supplemented females were tricked by the experiment into laying more eggs than the number of eggs they were able to incubate with success and the number of nestlings they were able to feed, a source of error in clutch size adjustment which could be common in non-experimental situations.
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