ISSN:
1434-4475
Schlagwort(e):
Carbon disulfide
;
Phthalide
;
3(2H)-Benzofuranone
;
3-(Bis(alkylthio)methylene)-3H-isobenzofuran-1-ones
;
2-(Bis(alkylthio)methylene)-3(2H)-benzofuranones
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Summary 3(Bis(alkylthio)methylene)-3H-isobenzofuran-1-ones2a–e and 2-(bis(alkylthio)methylene)-3(2H)-benzofuranone derivatives4a–c are obtained by reaction of phthalides1a–d or 3(2H)-benzofuranone (coumaranone3), respectively, with carbon disulfide under basic conditions followed by alkylation. The reaction behaviour of the new compounds2 and4 is investigated. 2-((2-Dimethylthio-1-oxo)ethyl)benzoic acid N,N-dimethylamide (7a) and 2-((2-dimethylthio-1-oxo)ethyl)-benzoic acid 2-methylpiperidide (7b) are surprisingly formed instead of the methylthio substitution products by treatment of2a with the corresponding amine in the presence of aluminum chloride.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF00810773
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