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  • Articles  (162)
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  • 1995-1999  (162)
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (158)
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  • Articles  (162)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 1585-1592 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polycyclotrimerization of a flexible aromatic dicyanate with a Schiff base structure was studied by means of differential scanning calorimetry (DSC). The study on dynamic DSC evaluated an apparent activation energy (Ea) of 75.8 kJ/mol and autocatalytic first-order kinetics with rate expression Af(α) = 1.96 X 105 (1 + 4.39 α) (1 - α) min-1. The kinetic feature can be explained by a proposed mechanism consisting of hydroxyl-catalyzed and autocatalytic paths. The lower value of Ea compared with other aromatic dicyanates is due to the electron-withdrawing linkage of the inherent imine ( - CH=N) structure. The kinetic feature is affected by the content of the residual impurities (e.g., phenols or absorbed water) in the corresponding sample. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The Zener pinning effect with growing second-phase particles in Al2O3-ZrO2 composite systems were studied by two-dimensional (2-D) computer simulations using a diffuse-interface field model. In these systems, all second-phase particles are distributed at grain corners and boundaries. The second-phase particles grow continuously, and the motion of grain boundaries of the matrix phase is pinned by the second-phase particles which coarsen through the Ostwald ripening mechanism, i.e., long-range diffusion. It is shown that both matrix grains and second-phase particles grow following the power-growth law, Rtm - R0m = kt with m = 3. It is found that the mean size of the matrix phase (D) depends linearly on the mean size of the second-phase particles (r) for all volume fractions of second phase from 10% to 40%, which agrees well with experimental results. It is shown that D/r is proportional to the volume fraction of the second phase (f) as f−1/2 for a volume fraction less than 30%, which agrees with Hillert and Srolovitz's predictions for 2-D systems, while experimental results from 2-D cross sections of three-dimensional (3-D) Al2O3-rich systems showed that either a f−1/2 or a f−1/3 relation might be possible. It is also found that D/r is not proportional to f−1/3 and f−1 in 2-D simulations, which suggests that the Zener pinning effect can be very different in 2-D and 3-D systems.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: To understand the influence of processing parameters on the microstructure of plasma-sprayed deposits, smallangle neutron scattering measurements were made of the processing-parameter-dependent specific surface area of the voids in gray alumina deposits. These studies indicate that the voids are in the form of pores between the splats and around inclusions or unmelted particles, and are also in the form of cracks within the splats which may develop during cooling. The porous volume increases as the angle between the spray gun and the substrate (the “spray angle”) decreases. This study also indicates that the cracks are preferentially oriented, and that the crack orientation also depends on the spray angle. The interlamellar pores, however, are preferentially oriented parallel to the substrate surface, and the orientation of the pore is independent of the spray angle.
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  • 4
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Fluid Mechanics 31 (1999), S. 417-457 
    ISSN: 0066-4189
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We survey the newly developed Hilbert spectral analysis method and its applications to Stokes waves, nonlinear wave evolution processes, the spectral form of the random wave field, and turbulence. Our emphasis is on the inadequacy of presently available methods in nonlinear and nonstationary data analysis. Hilbert spectral analysis is here proposed as an alternative. This new method provides not only a more precise definition of particular events in time-frequency space than wavelet analysis, but also more physically meaningful interpretations of the underlying dynamic processes.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Chemistry of materials 7 (1995), S. 1325-1332 
    ISSN: 1520-5002
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bingley : Emerald
    International journal of clothing science & technology 11 (1999), S. 198-205 
    ISSN: 0955-6222
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The aim of this study is to investigate the water (moisture vapor and liquid) transfer properties of two-layer weft knitted fabric and some related factors. Some experimental fabrics with specific yarns and stitch densities were prepared. Water vapor permeability rate through the fabrics and liquid water transfer from inner to outer layers were measured. The results show that the permeability rate is closely related to the porosity within the fabric while the transfer depends mainly upon the water absorption properties of the fibers on the two layers and degree of their difference.
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  • 7
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Tetragonal BaTiO3 powders were prepared hydrothermally, using Ba(OH)2·8H2O and TiO2 (anatase), in the absence of anions such as chloride ions, at a temperature of 220°C for several days. Characterization via X-ray diffractometry, scanning electron microscopy, and differential scanning calorimetry confirmed that increasing the Ba:Ti molar ratios (from 1:1 to 4:1) and alkaline concentrations (from 1.0M to 3.0M) promotes the formation of tetragonal BaTiO3.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Alumina blanks were prepared via isostatic pressing and sintering at 1400°C for 2 h, whereas alumina-glass composites were prepared by infiltrating the molten glass into the partially sintered alumina compacts. The samples had a high bending strength (340 MPa) and high fracture toughness (3.91 MPa·m1/2) and were free of shrinkage. Concurrently, zirconia (5 wt%) was used as an additive to alumina to improve the mechanical properties of both partially sintered alumina and alumina-glass composites. Results show that zirconia notably improves the mechanical properties of the partially sintered alumina but increases that of the composites by no more than 10%.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Three-dimensional (3-D) computer simulations of ferroelectric domain formation and evolution were performed, using a computer simulation model based on the time-dependent Ginsburg-Landau equations. A cubic-to-tetragonal ferroelectric phase transition is considered. It is shown that the initial stage of the transition during the annealing of a quenched cubic paraelectric phase involves the nucleation and growth of the ferroelectric domains, followed by the domain coarsening leading to the formation of 90° and 180° domain structures. Part of the 3-D results reported here confirm our conclusions made earlier for the two-dimensional (2-D) case, namely, the nonlocal elastic interactions are critical to the formation of twin structure and the dipole-dipole interactions are responsible for the head-to-tail arrangements of dipoles at twin boundaries. In contrast to our previous work, and others; the effect of the depolarization energy was explicitly incorporated into the simulation model. It is found that when there are no surface charges to compensate the Lorentz field due to the polarization charges, and if the system is mechanically clamped, both 90° and 180° domains are thermodynamically stable.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of grain growth and Ostwald ripening in Al2O3-ZrO2 two-phase composites was systematically investigated using two-dimensional (2-D) computer simulations, based on a diffuse-interface field model. Using average values for the experimentally measured ratios of the grain boundary energies to the interphase boundary energy as the input, the predicted 2-D microstructural features and their evolution are in excellent qualitative agreement with experimental observations on 2-D cross sections of 3-D Al2O3-ZrO2 two-phase composite microstructures. It was found that the coupled grain growth in Al2O3-ZrO2 composites is controlled by long-range diffusion and the average size (Rt) as a function of time (t) follows the power-growth law, Rmt - Rm0=kt with m= 3, which is independent of the initial microstructures and volume fractions of the two phases. The predicted variation of the kinetic coefficient (k) on the volume fraction follows a trend similar to that experimentally measured through the entire range of volume fractions. The scaling of grain size distributions is observed at a given volume fraction, i.e., they are time-invariant in the steady state. However, the characteristics of size distributions vary with the initial microstructures and the volume fractions. The relationship between matrix grain size and second-phase grain size is discussed.
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