ISSN:
0947-3440
Schlagwort(e):
Furans
;
Thiophens
;
Palladium catalysis
;
Coupling reactions
;
Heterocycles
;
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The regiospecific synthesis of 3,4-disubstituted furans and thiophenes is reviewed. Our initial approach used 3,4-bis(tri-n-butylstannyl)furan as a building block, which led to many structurally diverse 3,4-disubstituted furans. Another avenue was explored by using 3,4-bis(trimethylsilyl)furan and 3,4-bis(trimethylsilyl)thiophene as precursors. A variety of unsymmetrically 3,4-disubstituted furans and thiophenes were prepared in this way. The advantages of our strategy lie in its stepwise manner as well as its prospect of yielding 3,4-disubstituted furans and thiophenes with rather different substitution pattern.
Zusätzliches Material:
5 Tab.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/jlac.199719970304
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