ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Various methods of hydrogenating ring opening metathesis polymerization (ROMP) polymers were investigated as part of an effort to improve their stability and increase their usefulness as matrix materials for nanocluster synthesis. Hydrogenation with Pd/BaSO4 catalyst in high-pressure hydrogen gas was only partly successful and limited to unfunctionalized polymers such as polymethyltetracyclododecene. Block copolymers containing phosphine or carboxylic acid functionalities were successfully hydrogenated by diimide generated in situ from p toluenesulfonylhydrazide. © 1995 John Wiley & Sons, Inc.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1995.070580610
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