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  • Polymer and Materials Science  (3)
  • 31.30.Gs
  • 31.50.+w
  • 32.10.Tb
  • EARTH RESOURCES AND REMOTE SENSING
  • Geomagnetics
  • 1995-1999  (3)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 1735-1744 
    ISSN: 0887-624X
    Keywords: luminescence ; temperature ; tris(β-diketone) chelates ; europium ; vinyl ether ; cationic photopolymerization ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The temperature-dependent luminescence of tris (β-diketone) chelates of europium was used for in situ temperature measurements during cationic photopolymerizations of vinyl ethers. These molecular-level luminescent probes provided a real-time, noninvasive method for monitoring temperature during these high-speed polymerizations. Two specific probes, tris (benzoyl-1, 1, 1-trifluoroacetone) europium and tris (1,1,1,5,5,5,-hexafluoroacetylacetone) europium, met several stringent spectral and performance requirements for application in our system. The luminescence from these probes exhibits a reproducible temperature dependence over a wide temperature range and is not sensitive to changes in viscosity. In situ temperature profiles obtained using this novel technique verified the importance of thermal effects during these highly exothermic photopolymerizations. These studies have demonstrated the utility of the tris(β-diketone) europium chelates for characterizing the temperature during high-speed photopolymerizations that cannot be monitored using conventional techniques. © 1995 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 32 (1996), S. 447-457 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: The surface characteristics of sixteen “monobloc” titanium-6% aluminum-4% vanadium (Ti6Al4V) femoral components (two of the 6-Ti-28 type and 14 of the 6-Ti-32 type) retrieved after periods of 78-131 months following loosening of the femoral component, as well as two unimplanted controls, were studied. The femoral heads were examined by a combination of noncontact light profilometry, scanning electron microscopy, and energy-dispersive X-ray analysis. No consistent correlations were found between classical surface roughness parameters (average, root mean square, peak-to-valley roughness, and radius of curvature) and any clinical parameter studied (patient gender, weight, and height; primary diagnosis; implantation time; or calculated force applied on the hip joint). This extensive quantitative topographic analysis suggests that wear mechanisms in vivo are complex and that wear of titanium alloy femoral heads is partly attributed to a combination of an imperfect nature of the surface before implantation, removal of the oxide layer causing abrasion of the alloy, subsequent deformation of the bearing surface including polishing, and, to a very small degree, patient parameters. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 23 (1995), S. 712-716 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A new, time-saving method to determine the diffusion coefficient of caesium in sodium borosilicate glass is presented. With low-energy ion scattering (LEIS) the diffusion coefficient of caesium in this glass, where the main components are the same as those in nuclear waste glass, is determined in a wide temperature range (723-849 K). Compared to the conventional concentration couple method where the diffusion has to be studied over large distances (105 nm), it is shown that by using LEIS accurate measurements can be performed when diffusion takes place over distances of the order of 10 nm. Diffusion coefficients for caesium as low as 2.6 × 10-22 m2 s-1 are extracted from the measurements. This is a factor of 106 smaller than that measured with the concentration couple method for the same system and more than a factor of 10 smaller than diffusion coefficients for caesium determined in nuclear waste glasses by other techniques. At high temperatures the results of the different methods are in absolute agreement.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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