ISSN:
1572-9001
Schlagwort(e):
Titanium(IV) chelates
;
tridentate diacidic ligands
;
donor set ONO(S)
;
13C-CP/MAS-NMR spectra
;
crystal structure of bis[benzoylacetone thiobenzoylhydrazonato(2-)]titanium(IV)
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract A series of tridentate diacidic ligands having the donor set ONO(S) as well as the corresponding titanium(IV) chelates were studied by13C-CP/MAS-NMR spectroscopy. Structural changes caused by the complex formation are discussed. The crystal structure of bis[benzoylacetone thiobenzo-ylhydrazonato(2-)]titanium(IV) was determined by X-ray analysis as to be distorted trigonal prismatic. Orthorhombic space group Pca2l,Z=4, 3304 observed independent reflections, unit-cell parameters at 298 K:a=22,808(2) å,b=13,073(4) å,c=10,450(4) å.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF02263509
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