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  • Mineralogical Society of Great Britain and Ireland  (2)
  • Blackwell Publishing Ltd  (1)
  • 1995-1999  (3)
  • 1
    Publication Date: 1995-03-01
    Description: Hydrogen in H-feldspar obtained by ion-exchange was studied in the spectral range 1000–5500 cm−1 by single crystal IR microspectroscopy. Spectra were almost identical for H-feldspars prepared either from sanidine or from adularia. Two bands in the middle-infrared were identified by D/H exchange as OH vibration modes. One broad band with a maximum at 3000 cm−1 and shoulders at 2800, 3200 and 3500 cm−1 confirms previous work. An additional OH absorption band with a maximum at 2485 cm−1 was observed for the first time in feldspars. The pleochroism of the OH absorption bands suggests that the H-feldspar is composed of two phases, an amorphous phase and a feldspathic phase. The proportion of the amorphous phase is increased by heating, producing a shift of the maximum of the band at 3000 cm−1 towards higher wavenumber and a decrease of the intensity of the band at 2485 cm−1. Near-infrared spectroscopy showed that hydrogen is present as hydroxyl groups bound to tetrahedral cations in both phases. Molecular water was not detected. The experimental results imply that hydrogen is incorporated in the H-feldspars as protons attached to bridging oxygen as well as to non-bridging oxygen. The complex structure of the IR spectra implies that the protons are distributed over a large number of sites in the cation cavity of the feldspars.
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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  • 2
    Publication Date: 1999-04-01
    Description: End-members and species defined with permissible ranges of composition are presented for the true micas, the brittle micas, and the interlayer-deficient micas. The determination of the crystallochemical formula for different available chemical data is outlined, and a system of modifiers and suffixes is given to allow the expression of unusual chemical substitutions or polytypic stacking arrangements. Tables of mica synonyms, varieties, ill-defined materials, and a list of names formerly or erroneously used for micas are presented. The Mica Subcommittee was appointed by the Commission on New Minerals and Mineral Names of the International Mineralogical Association. The definitions and recommendations presented were approved by the Commission.
    Print ISSN: 0026-461X
    Electronic ISSN: 1471-8022
    Topics: Geosciences
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Geophysical journal international 124 (1996), S. 0 
    ISSN: 1365-246X
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Plane-wave ray tracing has been performed through 2-D random media with Gaussian and exponential autocorrelation functions of the slowness perturbations. The standard deviation is ɛ, correlation length a and propagation distance L; computations have been performed for ɛ= 1 and 3 per cent and for L/a= 2.5 to 60. Up to L/a= 5 or 10, regular focusing and defocusing of the rays is observed. Then, irregular behaviour develops, apparently without foci, but with increasing deviations q from the straight rays of a homogeneous medium. Two neighbouring rays at the top of a rectangular cross-section usually arrive far from each other at the bottom, and rays can even turn. The standard deviation σ of q, normalized by L, is approximately σ/L=ɛ(L/a)1/2.From the traveltimes of the rays at the bottom of the cross-section, the first arrivals were determined and compared with the first arrivals according to the Huygens method of Podvin & Lecomte (1991). Both ray tracing and the Huygens method are high-frequency methods, but their traveltimes do not always agree. The reason is that the Huygens method gives first arrivals including diffractions around the slow parts of the structure, whereas ray tracing, in the sense of initial-value ray tracing, gives only transmitted rays. As a consequence, traveltimes calculated by ray tracing are systematically late with respect to the Huygens-method traveltimes. The difference becomes significant for L/a greater than 10 to 20, it increases with ɛ, and it is more pronounced for exponential than for Gaussian media. For instance, the velocity shift (with respect to the inverse of the volume average of the slowness) for an exponential medium, L/a= 60 and ɛ= 3 per cent, is –0.5 per cent according to ray tracing, whereas it is + 1.3 per cent according to the Huygens method. For ɛ= 1 per cent the corresponding numbers are 0 and +0.3 per cent, i.e. the difference between ray tracing and the Huygens method is still significant.A conclusion from our calculations is that, even in the mildly laterally heterogeneous earth models of seismic tomography, ray tracing may give traveltimes that are significantly biased, i.e. overestimated. Another result is that, in random media, ray-tracing first-arrival traveltimes often have much stronger short-scale spatial variations than Huygens-method traveltimes which include wavefront healing due to diffractions. Both effects, traveltime bias and short-scale variations, limit the applicability of ray tracing already for weak random media.
    Type of Medium: Electronic Resource
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