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  • Springer  (58)
  • Institute of Physics  (9)
  • American Institute of Physics (AIP)  (5)
  • 1995-1999  (72)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 10 (1998), S. 437-456 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The structural features of turbulence at the free surface of a channel flow have been experimentally investigated. The experiments were conducted in a horizontal channel of large aspect ratio in the (depth based) Reynolds number range of 2800–8800. The results indicate that the persistent structures on the free surface can be classified as upwellings, downdrafts, and spiral eddies. Upwellings are shown to be related to the bursts originating in the sheared region at the channel bottom and the eddies are seen to be generated at the edges of the upwellings. The eddies often merge if rotating in the same direction, and form "pairs" if rotating in opposite directions—though there are occasional mergers of such counter-rotating ones. The spiral eddies decay slowly and are sometimes annihilated by fresh upwellings. The population densities and the persistence times of the various structures were measured for different flow conditions. The resulting data show that the physical parameters characterizing the structures at the interface, scale with a mix of inner (wall shear stress and viscosity) and outer variables. Measurement of the streamwise and spanwise velocities at the free-surface were made by particle imaging velocimetry (PIV) and the surface normal velocity near the free-surface estimated by continuity. The results indicate that the upwellings and spiral eddy regions would be expected to dominate scalar transport rates at high Prandtl/Schmidt numbers. The one-dimensional energy spectra of the flow field at the free-surface compare well with direct numerical simulations and show a region with −5/3 slope at low wave numbers. This experimentally confirms a previous result regarding the two-dimensionality of turbulence near the free surface, based on numerical simulations by Pan and Banerjee [Phys. Fluids 7, 1649 (1995)]. © 1998 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Physics of Fluids 10 (1998), S. 160-177 
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A method for particle image velocimetry (PIV) is presented which improves upon the accuracy, computational efficiency and dynamic range (i.e., the difference between the largest and smallest resolvable particle displacement vectors) of conventional PIV techniques. The technique is applied to free-surface turbulence to resolve energy spectra for motions with a wide dynamic range. The methodology—based on multi-grid image processing algorithms for rigid body motion analysis, estimates the displacement vectors at discrete particle locations. The essence of this technique is to estimate large scale motions from image intensity patterns of low spatial frequencies and small scale motions from intensity patterns of high spatial frequencies. Cross-correlation between a pair of time separated particle images is implemented by the hierarchical computational scheme of Burt ["Fast filter transforms for image processing," Int. J. Comput. Vision 16, 20 (1981)]. Each image is convolved with a series of band-pass filters and subsampled to obtain a set of images progressively decreasing in resolution and size. A coarse estimate of the displacement field obtained from pairs of lower resolution images are used to obtain more accurate estimates at the next (finer) level. Processing starts at the level of lowest resolution and stops at the highest resolution level, which contains the original image pair. Due to subsampling of low resolution images, the match template size can be kept constant for all stages of computation, thus eliminating the dependence of the largest resolvable displacement on the size of match template. In the present work, the search area at each level is kept constant at 3×3 pixels and the match template size at 5×5 pixels for all levels of computation. The algorithm has been implemented using simple thresholding based on the confidence level of an estimated displacement vector, as suggested by Anandan ["A computational framework and an algorithm for measurement of visual motion," Int. J. Comput. Vision, 2, 283, (1987)]. However, the confidence-level-based smoothing technique for rigid body motions (continuous velocity fields) could not be applied to displacement estimates obtained at discrete points i.e., the particle locations. Instead, smoothing was performed over the area covered by each particle. The algorithm has been tested against direct numerical simulations of turbulent flows when the flow field is known and particle images have been generated from these with the addition of noise. Both the accuracy of motion estimation and the computation time are seen to improve as compared to conventional PIV methods. Finally, video images taken of particle motion on the free-surface of a channel flow have been used to determine the capabilities of the technique in an experimental study. The resulting spectra show a quasi-two-dimensional character of the free-surface turbulent flow field, which corresponds well with the direct numerical simulations. © 1998 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 70 (1997), S. 1037-1039 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this letter, we present results of experiments in which nuclear magnetic resonance (NMR) signals were detected using an untuned pickup coil coupled to a high temperature superconductor (HTS) based superconducting quantum interference device (SQUID). We were able to operate the HTS SQUID in the presence of static fields of up to 500 Gauss and radio frequency fields of up to 6 Gauss. The ability of a HTS SQUID to detect NMR signals opens up the possibility of using a sensitive detector for practical applications involving NMR that require a broad detection bandwidth. © 1997 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 10315-10324 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Monte Carlo calculations have been performed on two nominally athermal polymer/solvent mixtures to test molecular theories of mixing properties for these systems. We first used the incremental chemical potential concept to derive an equation of state in the spirit of the generalized Flory dimer theory, without resorting to the concept of excluded volume. The resulting generalized Flory dimer-like theory and a related model, statistical associating fluid theory, were tested against simulation results for the excess volume, excess Gibbs free energy and component activity coefficients. Good agreement was obtained between the statistical associating fluid theory and computer simulations for all properties studied. The generalized Flory dimer theory, when applied self-consistently, was also able to provide quantitative predictions for the thermodynamic properties of these mixtures. An important result that emerges from our calculations is that these polymer solutions behave ideally when examined on the basis of a "Flory-like'' reference state augmented by density effects. This asserts that the effects of molecular size disparity on system thermodynamics are properly captured by this approach. By contrast, the incompressible Flory approach fails to capture the dependence of activity coefficients on composition. © 1995 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 6634-6645 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Stimulated by the experimentally observed low vibrational inelasticity and the somewhat stronger rotational inelasticity in the H+–N2 collisions, we present here a quantum dynamics study of the scattering process in the framework of vibrational close-coupling rotational infinite-order sudden approximation. We have employed the recently obtained ground-state potential-energy surface of the system from which both rotational and vibrational coupling potentials can be obtained. The various computed dynamical attributes such as differential and integral cross sections, and average vibrational as well as rotational energy transfers, are analyzed in detail and compared successfully with the available experimental results. © 1997 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 28 (1998), S. 931-933 
    ISSN: 1572-8854
    Keywords: Flavone ; hydrate ; hydrogen bonding ; X-ray crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The X-ray crystal structure of 7-hydroxyflavone monohydrate, C14H10O3 · H2O, is determined. The compound crystallizes in the monoclinic space group, P21/n with a = 3.801(3), b = 19.665(4), c = 16. 039(6), β = 93.69(3)°, and μ = 0.68 mm−1 for Z = 4. The phenyl ring of the flavone moiety is rotated 18.6(1)° out of the penzopyran plane, which is a typical value for flavones. In the crystal lattice, there are wide channels which are lined mainly by C–H groups. The water molecules enclosed in these channels are severely disordered.
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  • 7
    ISSN: 1572-8854
    Keywords: Hexadiyne ; C–H···N hydrogen bonding ; X-ray crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The X-ray crystal structure of 1,6-bis(N-cyano-p-methoxy-anilino)-2,4-hexadiyne, C22H18N4O2, is determined. The crystal packing is dominated by phenyl stacking interactions. Weak C–H···N hydrogen bonds help align the molecules. C–H···π hydrogen bonding is not apparent.
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  • 8
    ISSN: 1572-8854
    Keywords: Cyclohexane ; alkyne ; hydrogen bonding ; X-ray crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The X-ray crystal structure of the title compound, C18H28O3, is determined. The hydrogen bond scheme does not follow considerations based on hierarchies of donor and acceptor strengths. The hydroxyl group of the molecule accepts only very weak C–H···O interactions.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 29 (1999), S. 99-102 
    ISSN: 1572-8854
    Keywords: Isoflavone ; natural compound ; Dalbergia spinosa ; X-ray crystal structure ; hydrogen bonding
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The X-ray crystal structure of the plant isoflavone dalspinin from Dalbergia spinosa is determined. The compound, C17H12O7, is monoclinic in P21/n with a = 3.970(1), b = 23.607(5), c = 14.633(3) Å, β = 94.46(3)°, V = 1367.2(5) Å3, D calc = 1.595 g cm−1 and Z = 4. The molecular structure is characterized by a short intramolecular O–H···O=C hydrogen bond, and a large tilt angle of the two rigid ring systems with respect to each other. The intermolecular interactions in the crystal are discussed.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 62 (1996), S. 309-311 
    ISSN: 1432-0649
    Keywords: 52.40 ; 42.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The effects of the development of the three-wave phase on the amplitude of the pumping laser light, the scattered light, and the electron plasma wave are studied. Analytical solutions are obtained to describe a pumping laser light decreasing with time and the development of the electron plasma wave and scattered wave from an initial increasing state to saturation and finally to a decaying state which is closely related to the three-wave phase.
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