ISSN:
1434-1948
Keywords:
Diene complexes
;
Metallacycles
;
Palladium
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The complexes rac-5 and rac-6 of the trans-5-palladatricyclo[4.1.0.02,4]heptane rac-2a with norbornadiene and 1,5-cyclooctadiene were prepared and investigated by X-ray structure determination. With open-chained, unsaturated substrates, e.g. 7 and 8, no complexes could be isolated. In all cases no insertion of the olefin into the metal-carbon bond of the palladacycloalkane was observed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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