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  • Inorganic Chemistry  (6)
  • Astronomy; Optics
  • Industrial Chemistry
  • 1995-1999  (7)
  • 1930-1934  (1)
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Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 206 (1932), S. 356-356 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 2
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 68 (1996), S. 1074-1075 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 1287-1289 
    ISSN: 0044-2313
    Keywords: Calcium hexahydroxodizincate dihydrate ; synthesis ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of CaZn2(OH)6 · 2 H2OThe electrochemical oxidation of zinc in a zinc/iron-pair leads in an aqueous NH3 solution of calciumhydroxide at room temperature to colourless crystals of CaZn2(OH)6 · 2 H2O. The X-ray structure determination was now successful including all hydrogen positions.P21/c, Z = 2, a = 6.372(1) Å, b = 10.940(2) Å, c = 5.749(2) Å, β = 101.94(2)° N(F2o ≥ 3σF2o) = 809, N(Var.) = 69, R/RW = 0.011/0.012The compound CaZn2(OH)6 · 2H2O contains Zn2+ in tetrahedral coordination by OH- and Ca2+ in octahedral coordination by four OH- and two H2O. The tetrahedra around Zn2+ form corner sharing chains, three-dimensionally linked by isolated polyhedra around Ca2+. Weak hydrogen bridge bonds result between H2O as donor and OH-.
    Notes: Die elektrochemische Oxidation von Zink in einem Zink/Eisen-Paar führt in einer wäßrigen NH3-Lösung von Calciumhydroxid bei Raumtemperatur zu farblosen Kristallen von CaZn2(OH)6 · 2 H2O. An ihnen wurde röntgenographisch die Struktur jetzt einschließlich aller H-Lagen bestimmt.P21/c, Z = 2, a = 6,372(1) Å, b = 10,940(2) Å, c = 5,749(2) Å, β = 101,94(2)° Z(F2o ≥ 3σF2o) = 809, Z(Var.) = 69, R/RW = 0,011/0,012In CaZn2(OH)6 · 2 H2O ist Zn2+ tetraedrisch von OH- und Ca2+ oktaedrisch von vier OH- und zwei H2O umgeben. Die Tetraeder um Zn2+ bilden Ketten über gemeinsame Ecken, die durch voneinander isolierten Oktaedern um Ca2+ dreidimensional verknüpft werden. Es liegen schwache H-Brückenbindungen von H2O als Donator zu OH- vor.
    Additional Material: 2 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 1273-1276 
    ISSN: 0044-2313
    Keywords: Strontium tetrahydroxozincate monohydrate ; crystal structure refinement ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of SrZn(OH)4 · H2OColorless crystals of SrZn(OH)4 · H2O are obtained by electrochemical oxidation of Zn in a zinc/iron pair in an aqueous ammonia solution saturated with strontium hydroxide. The X-ray crystal structure determination was now successful including all hydrogen positions: P1, Z = 2, a = 6.244(1) Å, b = 6.3000(8) Å, c = 7.701(1) Å, α = 90.59(1)°, β = 112.56(2)°, γ = 108.66(2)°, N(F2o ≥ 3σF2o) = 1967, N(Var.) = 84, R/Rw = 0.020/0.024.In SrZn(OH)4 · H2O Zn2+ is tetrahedrally coordinated by four OH- -ions while Sr2+ has 6 OH- and one H2O as neighbours. The polyhedra around Sr2+ are connected to chains which are linked three-dimensionally by isolated tetrahedra [Zn(OH)4]. Hydrogen bonds between H2O as donor and OH- are characterized by raman spectroscopy.
    Notes: Die elektrochemische Oxidation von Zink in einem Zink/Eisen Paar führt in einer wäßrigen ammoniakalischen Lösung von Strontiumhydroxid zu farblosen Kristallen von SrZn(OH)4 · H2O. An ihnen wurde röntgenographisch die Struktur jetzt einschließlich aller H-Lagen bestimmt: P1, Z = 2, a = 6,244(1) Å, b = 6,3000(8) Å, c = 7,701(1) Å, α = 90,59(1)°, β = 112,56(2)°, γ = 108,66(2)°, Z(F2o ≥ 3σF2o) = 1967, Z(Var.) = 84, R/Rw = 0,020/0,024.In SrZn(OH)4 · H2O ist Zn2+ tetraedrisch von OH- und Sr2+ von 6 OH- und einem H2O umgeben. Die Polyeder um Sr2+ bilden Ketten. Sie sind über isolierte Tetraeder [Zn(OH)4] dreidimensional verknüpft. Wasserstoffbrückenbindungen von H2O als Donator zu OH- sind durch Ramanspektroskopische Daten belegt.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 1035-1036 
    ISSN: 0044-2313
    Keywords: Titanium compound ; Phosphorane iminato derivatives ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetrakis(triphenylphosphoraneiminato)titanium, [Ti(NPPh3)4]The title compound has been prepared by the reaction of [TiCl2(NPPh3)2] with methyllithium and cyclopentadienyllithium, respectively, in hexane solution. [Ti(NPPh3)4] · 3 C7H8 crystallizes from toluene solution to form colourless, only slightly moisture sensitive crystals which were characterized by a crystal structure determination. Space group I41/a, Z = 8, lattice dimensions at -80°C: a = b = 2160.7(2), c = 3334.2(3) pm, merohedral (110) twin, R = 0.077. The compound forms monomeric molecules with tetrahedrally coordinate titanium atoms and bonding parameters of TiN = 187.3 pm, PN = 155.1 pm, TiNP 150.4° in average.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 423-428 
    ISSN: 0044-2313
    Keywords: Barium hexahydroxodizincate pentahydrate ; synthesis ; crystal structure ; hydroxozincate ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Crystal Structure of BaZn2(OH)6 · 5 H2OThe electrochemical corrosion of zinc in a zinc/iron pair leads in an ammonia containing solution of barium hydroxide at room temperature to colourless platelets of crystals of BaZn2(OH)6 · 5H2O. The X-ray structure determination on these crystals was successful including all hydrogen positions: P21/c, Z = 4, a = 6.181(2) Å, b = 16.126(3) Å, c = 11.121(2) Å, β = 99.69(2)° Z(Fo2 ≥ 3 σ Fo2) = 3281, Z(Var.) = 178, R/Rw = 0.020/0.021 BaZn2(OH)6 · 5 H2O crystallizes in a layer structure. The layers contain Zn2+ in tetrahedral coordination by OH- and Ba2+ in an onefold capped tetragonal antiprism of 6 H2O and 3 OH-. Hydrogen bridge bonds of a further H2O molecule between the layers to OH- and H2O connect these three-dimensionally.
    Notes: Die elektrochemische Korrosion von Zink in einem Zink/Eisen-Paar führt in einer ammoniakalischen wäßrigen Lösung von Bariumhydroxid bei Raumtemperatur zu plättchenförmigen farblosen Kristallen von BaZn2(OH)6 · 5H2O. An ihnen wurde röntgenographisch die Struktur einschließlich aller H-Lagen bestimmt: P21/c, Z = 4, a = 6,181(2) Å, b = 16,126(3) Å, c = 11,121(2) Å, β = 99,69(2)° Z(Fo2 ≥ 3 σ Fo2) = 3281, Z(Var.) = 178, R/Rw = 0,020/0,021 BaZn2(OH)6 · 5H2O kristallisiert in einer Schichtstruktur. Innerhalb der Schichten ist Zn2+ tetraedrisch von OH- und Ba2+ einfach überkappt tetragonal antiprismatisch von 6H2O und 3OH- umgeben. Über Wasserstoffbrückenbindungen eines weiteren Moleküls H2Q zu OH- und H2O sind die Schichten dreidimensional verknüpft.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 623 (1997), S. 1855-1856 
    ISSN: 0044-2313
    Keywords: Zirconium compound ; phosphorane iminato complex ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: [Zr2Cl4(NPMe3)4(HNPMe3)] · CH3CN, a Phosphorane Iminato Complex with Zr=N Double BondsThe title compound has been prepared from a molten mixture of ZrCl4 with Me3SiNPMe3 in the presence of potassium fluoride and subsequent extraction with acetonitrile. According to the crystal structure determination the zirconium atoms are linked by three μ2-N atoms of two NPMe3- groups and by the HNPMe3 molecule. Two terminal bounded chlorine atoms and a terminally coordinated NPMe3- ligand complete the distorted octahedral surrounding of the zirconium atoms thus forming an edge sharing double octahedron. The ZrN bond lengths of the terminal NPMe3- groups of 194.6 pm correspond with double bonds.
    Additional Material: 1 Ill.
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