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  • 1,2,4-trimethylbenzene hydroxylation  (1)
  • 1995-1999  (1)
  • 1945-1949
  • 1
    Electronic Resource
    Electronic Resource
    Oxidation of trimethylbenzene by the heteropoly vanadomolybdate-hydrogen peroxide system (1998)
    Springer
    Reaction kinetics and catalysis letters 64 (1998), S. 193-197 
    Details
    ISSN: 1588-2837
    Keywords: Trimethylbenzene oxidation ; heteropoly vanadomolybdate ; 1,2,4-trimethylbenzene hydroxylation ; hydroxylation by hydrogen peroxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Oxidation of 1,3,5- and 1,2,4-trimethylbenzenes using heteropoly vanadomolybdate as catalyst in the presence of hydrogen peroxide under homogeneous conditions has been investigated. Phenol formation in the case of 1,2,4-trimethylbenzene and only side chain oxidation in the case 1,3,5-trimethylbenzene were observed. This behavior is explained in terms of the charge densities on different centers of both substrate molecules calculated by the MNDO method.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02475388
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