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  • Inorganic Chemistry  (18)
  • Computational Chemistry and Molecular Modeling  (6)
  • Gas chromatography  (3)
  • Asymmetric synthesis  (2)
  • 42.75
  • Wiley-Blackwell  (29)
  • 1995-1999  (23)
  • 1960-1964  (6)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Zur Kenntnis der Farbstoffe der Roten Rübe, III (1960)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 1296-1304 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung der freien Farbsäuren des Betanins und Betanidins wird beschrieben, ihre Bruttoformeln werden erörtert. Beide Verbindungen sind optisch aktiv. Sie spalten mit starker Natronlauge in der Hitze etwa 1/3 ihres Stickstoffes als Ammoniak ab. Quantitative Decarboxylierungsversuche und potentiometrische Titration weisen für das Glucosid wie für das Aglykon auf drei Carboxylgruppen, von denen eine durch eine basische Gruppe neutralisiert zu sein scheint, und eine schwach saure (phenolische) Gruppe hin. Beim oxydativen Abbau des Betanidins wurde L-Asparaginsäure erhalten.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19600930609
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  • 2
    Electronic Resource
    Electronic Resource
    Über eine ungewöhnliche Spaltung von Diaryl-äthernHerrn Professor Dr. Richard Kuhn zum 60. Geburtstag gewidmet. O. Th. Schmidt. (1960)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 2761-2776 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dehydro-digallussäure (I) und Valoneasäure-dilacton (II) erleiden mit Alkalien eine Spaltung an der Diphenyläther-Brücke, die keine Hydrolyse ist. Anhand zahlreicher Modellsubstanzen wird festgestellt, daß diese neuartige Spaltung von Diphenyläthern offenbar an das Vorliegen von 3 vicinalen, freien Hydroxygruppen an einem der beiden Phenylreste gebunden ist. Die Spaltung ist eine innere Disproportionierung; als Mechanismus wird eine β-(oder vinyloge β-)Eliminierung diskutiert. - Sieben einseitig hydroxyl-substituierte Diphenyläther wurden neu dargestellt.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19600931203
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  • 3
    Electronic Resource
    Electronic Resource
    2.3.4.6-Tetrabenzyl-α-D-glucose (1960)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 93 (1960), S. 556-557 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19600930247
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  • 4
    Electronic Resource
    Electronic Resource
    Organmetallic Selenolates, IVPart III: Ref.[1].. Reactions of MSeW(CO)3cp (M=Li, Na) with Organodi- and -tetrahalides - X-ray Crystal Structures of C6H5CH2W(CO)3(η5-C5H 5), μ-[m-C6H4{CH2SeW(CO)3(η5-C5H5)}2], μ-[p-C6H4{CH2SeW(CO)3- (η5-C5H5)}2], and C6H5CH[SeW(CO)3(η5-C5H5)]2 (1996)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 129 (1996), S. 1275-1279 
    Details
    ISSN: 0009-2940
    Keywords: Organotungsten selenolates ; 77Se NMR ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Organotungsten-selenolato complexes were prepared in moderate yields by insertion of selenium into the alkali metaltungsten bonds of MSeW(CO)3cp (M = Li, Na) and subsequent reactions with the organohalides o-, m-, and p- C6H4(CH2Br)2, C6H5CHBr2, m-C6H4(CHBr2)2 and C6H5CCl3. The 77Se-NMR data of the new complexes are discussed and compared with those of related complexes derived from organomonohalides. Moreover, the X-ray crystal structures of C6H5CH2W(CO)3cp (1), μ-[m-C6H4{CH2SeW(CO)3cp}2] (3), μ-[p-C6H4{CH2SeW(CO)3cp}2] (4), and C6H5CH[SeW-(CO)3cp]2 (5) were determined. In complex (1), the W-CH2 bond length is 2.374 Å; the W-Se bond lengths in the complexes 3, 4 and 5 are all in the range 2.625-2.655 Å, corresponding to W-Se single bonds.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19961291021
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  • 5
    Electronic Resource
    Electronic Resource
    Large volume sample introduction using temperature programmable injectors: Implications of liner diameter (1995)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 18 (1995), S. 19-27 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Large volume injection ; PTV injectors ; PTV splitless injection ; PTV solvent split injection ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Temperature programmable injectors with liner diameters ranging from 1 to 3.5 mm are evaluated and compared for solvent split injection of large volumes in capillary gas chromatography. The liner dimensions determine whether a large sample volume can be introduced rapidly or has to be introduced in a speed controlled manner. The effect of the injection technique used on the recovery of n-alkanes is evaluated. Furthermore the influence of the liner diameter on the occurrence of thermal degradation during splitless transfer to the analytical column is studied. Guidelines are given for the selection of the PTV liner internal diameter best suited for specific applications.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240180106
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  • 6
    Electronic Resource
    Electronic Resource
    Asymmetric Synthesis and Enantioselectivity of Binding of 1-Aryl-1,2,3,4-tetrahydroisoquinolines at the PCP Site of the NMDA Receptor Complex (1998)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 2019-2029 
    Details
    ISSN: 1434-193X
    Keywords: Asymmetric synthesis ; Nitrogen heterocycles ; N-Acyliminium ions ; PCP site ligands ; Pharmacological enantioselectivity ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new method for the asymmetric synthesis of 1-substituted tetrahydroisoquinolines is presented. It is based on stereoselective addition reactions of organometallic compounds to the intermediate N-acyliminium ion 6, which is provided with an N-acyl group as a chiral auxiliary. In addition reactions with organomagnesium and organozinc reagents diastereoselectivities from 70:30 to 95:5 (for 7/8) were observed with the zinc reagents in general leading to markedly improved stereoselectivities. By catalytic hydrogenation of 7 and 8 and after removal of the chiral auxiliary the target compounds 11 and 12 were obtained. The enantiomerically pure 11c-g and 12c-g (ee 〉 99 %), 1-aryl-tetrahydroisoquinolines, were evaluated for their affinity to the PCP [1-(1-phenylcyclohexyl)piperidine] binding site of the NMDA (N-methyl D-aspartate) receptor. In each case the enantiomers 11 exhibited a higher affinity than those of 12, with the potencies of the enantiomers differing by a factor of 4 (11/12g) to 27 (11/12c). The absolute configuration of the more potent enantiomers 11 is in accordance with the stereochemical requirement found for FR115427 (3) which is a close analogue.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Automated derivatization for on-line solid-phase extraction-gas chromatography; phenolic compounds (1997)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 20 (1997), S. 363-368 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Solid-phase extraction ; Automation ; Water samples ; Acetylation ; Chlorophenols ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An automated system for derivaatization was coupled on-line with solid-phase extraction-gas-chromatography (SPE-GC). The system was optimized for the determination of phenol and chlorinated phenols in aqueous samples. The test analytes were acetylated with acetic anhydride; proper buffering of the sample was a critical factor. Next, the phenol acetates were enriched on a SPE cartridge and transferred to a GC; two appraoaches were studied. In the first approach, the derivatives were enriched on disposable C18 cartridges (ASPEC type) and desorbed with methylacetate. Aan aliquot of the final eluate was injected on-line the GC by means of a loop-type interface. In the second approach, trace enrichment was performed on 10 × 2 mm i.d. LC-type precolumn packed with polystyrenedivinylbenzene copolymer (PLRP-S) this precolumn was dried with a mitrogen purge and the phenol acetates were desorbed with ethyl acetate which was injectedon-line into the retention gap of the GC under partially concurrent solvent evaporation (PCSE) conditions. The Derivatization-SPE-GC system which was based on the loop-type interface has the advantage of simplicity and easy operation, the main drawback is the impossibility to determine phenol acetates which elute prior to trichlorophenol acetates. With the derivatization-SPE-GC approach using PCSE-based desorption, even the most volatile analyte of the test series, phenol acetate, can be determined successfully. The entire procedure, including the derivatization step, was fully automated and integrated in one set-up. The precision data for the integrated on-line derivatization-SP-FID system were fully satisfactory, with RSD values of 1-12 % at the 1 μg/1 level. When a sample volume of 2.2 ml was analyzed, The detection limits for the chlorinated phenol acetates were in the 0.1-0.3 μg/1 range.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240200704
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  • 8
    Electronic Resource
    Electronic Resource
    Asymmetrische Elektrophile α-Amidoalkylierung, 11Part 10: Ref.. Neue chirale Hilfsgruppen aus (+)-CamphersäureHerrn Professor Eberhard Reimann mit den besten Wünschen zum 60. Geburtstag gewidmet. (1996)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1996 (1996), S. 1941-1948 
    Details
    ISSN: 0947-3440
    Keywords: Asymmetric synthesis ; N-Acyliminium ions ; Camphor-derived chiral auxiliaries ; 2-Substituted piperidines ; Enamides ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Asymmetric Electrophilic α-Amidoalkylation, 11. - New Chiral Auxiliaries from (+)-Camphoric AcidHerrn Professor Eberhard Reimann mit den besten Wünschen zum 60. Geburtstag gewidmet.The chiral bicyclic carboxylic acids 3b-e have been prepared in a few steps from camphoric acid. They were designed as new chiral auxiliaries for asymmetric synthesis with chiral N-acyliminium ions featuring precomplexation as a mechanism for asymmetric induction. Their asymmetric induction was evaluated in alkylation reactions with the enamides 5b-e being performed by addition of HCl and subsequent treatment of the resulting α-chloro amide with AlEt3. The carboxylic acid 3e turned out to be well suited as a chiral auxiliary providing high asymmetric induction (e.g. 92.9/7.1 with ZnEt2) and moderate chemical yields (66% 12e + 13e) and being easily removed by acid hydrolysis without destruction.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.199619961130
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  • 9
    Electronic Resource
    Electronic Resource
    On-line solid-phase extraction-thermal desorption-gas chromatography with ion trap detection tandem mass spectrometry for the analysis of microcontaminants in water (1996)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 19 (1996), S. 679-685 
    Details
    ISSN: 0935-6304
    Keywords: Solid-phase extraction-thermal desorption ; Gas chromatography ; Ion trap detection ; Tandem mass spectrometry ; Water samples ; Microcontaminants ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An improved set-up for solid-phase extraction with thermal desorption coupled on-line to gas chromatography (SPETD-GC) is presented. It includes a newly designed liner for a programmable temperature vaporizer (PTV) and an improved water elimination system. The SPETD procedure now includes a washing step with HPLC-grade water to prevent degradation of analytes due to interaction with remaining sample constituents. The system was used to analyze surface and tap water samples over a 4-month period. No decrease of chromatographic or trace-enrichment performance was observed, and a liner packed with Tenax GR could be used for at least 150 analyses. The SPETD module was coupled to GC with ion-trap detection for mass spectrometric (MS) and MS/MS detection. The linearity and repeatability of the procedure for several pesticides which were tested in the 0.5-10 μg/1 range were fully satisfactory (1 μg/1, RSD range 5-11%; n = 5). When using sample volumes of 0.1 ml only, detection limits were as low as 0. 1-0.2 μg/1. As an example, the confirmation and quantification of a suspected pesticide in a real-life sample using electron impact and positive chemical ionization in both the MS and MS/MS mode is shown.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240191205
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  • 10
    Electronic Resource
    Electronic Resource
    Implementation of reaction field methods in quantum chemistry computer codes (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 16 (1995), S. 1445-1446 
    Details
    ISSN: 0192-8651
    Keywords: Computational Chemistry and Molecular Modeling ; Biochemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcc.540161113
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