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  • Springer  (63)
  • American Meteorological Society (AMS)
  • Berlin: Deutsches Institut für Wirtschaftsforschung (DIW)
  • National Academy of Sciences
  • 1995-1999  (40)
  • 1965-1969  (25)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Glycoconjugate journal 14 (1997), S. 785-793 
    ISSN: 1573-4986
    Keywords: glycoprotein ; glycosylation ; gp120 ; HIV ; MALDI-TOF-MS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Neutral complex-type N-glycans of the envelope glycoprotein 120 of HIV-2, propagated in different host cells, display cell-type specific variations. In order to identify typical structural elements, glycans were analysed by gel filtration, by enzymic sequencing and, in part, by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The characteristic substituents of di- tri- and tetraantennary carbohydrate units thus observed include N-acetyllactosamine repeats, bisecting N-acetylglucosamine and fucose linked to the chitobiose core as well as to N-acetyllactosamine antennae. Each glycoprotein preparation displayed a characteristic set of glycoforms. Abbreviations: endo H, endo-β-N-acetylglucosaminidase H; E-PHA, Phaseolus vulgaris agglutinin E4; GlcNAcOH, N-acetyl-glucosaminitol; gp120/HUT78(MOLT4/Mφ/PBL/U937), external envelope glycoprotein 120 of HIV-2, strain D194, propagated in HUT78 (MOLT4, Mφ, PBL, U937) cells; gu, glucose units; HPAEC, high-pH anion-exchange chromatography; MALDI-TOF-MS, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry; Mφ, human monocytes/macrophages; PBL, human peripheral blood lymphocytes; PNGase F, peptide-N4-(N-acetyl-β-glucosaminyl)asparagine amidase F
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 47 (1999), S. 219-238 
    ISSN: 1573-515X
    Keywords: dissolved humic substances ; FTIR spectroscopy ; land use history ; peat ; synchronous fluorescence spectroscopy ; UV/VIS spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The elemental composition and spectroscopic properties of dissolved fulvic acids isolated from different sampling media (topsoil, ground and surface water) of a natural fen area (high portion of organic soils) were examined to reveal the effects of land use history. These effects need to be known if dissolved humic substances are to be a major factor in identifying the impact of present and future changes in land use. Dissolved fulvic acids (topsoil, groundwater) from highly degraded peatlands (due to a long-term agricultural use) exhibit lower C/N ratios, higher absorption in the UV spectra, and higher absorption at 1,620 cm−1 in the FTIR spectra compared with fulvic acids from relatively intact peatlands. These properties illustrate that long-term agricultural use with high inputs results in increased aromatic structures and a further humification of dissolved fulvic acids due to very strong peat decomposition compared with relatively intact peatlands. Synchronous fluorescence spectra also indicate the higher level of aromatic structures within fulvic acids isolated from sites with long-term agricultural use (high peat decomposition) compared with a land use history resulting in a lower peat decomposition. The different sources of fulvic acids in surface water (precipitation, runoff, interflow, groundwater) are the main reason for these effects not being detected in fulvic acids isolated from surface water. Short-term changes in land use characterized by a transition from crop farming to an unimproved grassland were found not to affect the spectroscopic properties of dissolved fulvic acids. A humification index deduced from the synchronous fluorescence spectra is proposed. We have strong evidence that dissolved humic substances indicate changes in the environmental conditions (both anthropogenic and natural) of wetlands with a high proportion of organic soils.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Biogeochemistry 47 (1999), S. 219-238 
    ISSN: 1573-515X
    Keywords: dissolved humic substances ; FTIR spectroscopy ; land use history ; peat ; synchronous fluorescence spectroscopy ; UV/VIS spectroscopy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The elemental composition and spectroscopic properties of dissolved fulvic acids isolated from different sampling media (topsoil, ground and surface water) of a natural fen area (high portion of organic soils) were examined to reveal the effects of land use history. These effects need to be known if dissolved humic substances are to be a major factor in identifying the impact of present and future changes in land use. Dissolved fulvic acids (topsoil, groundwater) from highly degraded peatlands (due to a long-term agricultural use) exhibit lower C/N ratios, higher absorption in the UV spectra, and higher absorption at 1,620 cm−1 in the FTIR spectra compared with fulvic acids from relatively intact peatlands. These properties illustrate that long-term agricultural use with high inputs results in increased aromatic structures and a further humification of dissolved fulvic acids due to very strong peat decomposition compared with relatively intact peatlands. Synchronous fluorescence spectra also indicate the higher level of aromatic structures within fulvic acids isolated from sites with long-term agricultural use (high peat decomposition) compared with a land use history resulting in a lower peat decomposition. The different sources of fulvic acids in surface water (precipitation, runoff, interflow, groundwater) are the main reason for these effects not being detected in fulvic acids isolated from surface water. Short-term changes in land use characterized by a transition from crop farming to an unimproved grassland were found not to affect the spectroscopic properties of dissolved fulvic acids. A humification index deduced from the synchronous fluorescence spectra is proposed. We have strong evidence that dissolved humic substances indicate changes in the environmental conditions (both anthropogenic and natural) of wetlands with a high proportion of organic soils.
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  • 4
    Publication Date: 1999-11-01
    Print ISSN: 0168-2563
    Electronic ISSN: 1573-515X
    Topics: Chemistry and Pharmacology , Geosciences
    Published by Springer
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 98 (1967), S. 852-873 
    ISSN: 1434-4475
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract The formation of benzotropolone compounds from catechol and pyrogallol derivatives depends upon the type, size, and position of the substituents in the reactants. Electrophilic substituents can be installed only in the 5-position of pyrogallol without loosing the capability of forming benzotropolones. This behavior is explained by the symmetrical electronic structure of the anion acting as 1.3-dipole. Pyrogallols, substituted in the 4- and 6-position by either methyl-, ethyl- or phenyl-groups, yield benzotropolones with 3-methoxy-o-benzoquinone. Isopropyl- andtert. butyl-groups in the same positions hinder benzotropolone formation because of steric hindrance. It was attempted to clarify the effect of the factors on the reaction mechanism by analysis of mixtures of benzotropolones, formed by oxidative coupling of catechol derivatives with pyrogallol-derivatives. On account of deficient yields this could not be done.
    Notes: Zusammenfassung Die Benzotropolonbildung aus Brenzcatechin- und Pyrogallolderivaten hängt von Art, Größe und Stellung der Substituenten in den Reaktionspartnern ab. Nur in die 5-Stellung des Pyrogallols können elektrophile Substituenten eingebaut werden, ohne daß die Fähigkeit zur Benzotropolonbildung verlorengeht. Dieses Verhalten wird durch die Symmetrie der elektronischen Struktur des als 1,3-Dipol wirkenden Anions erklärt. In 4- und 6-Stellung durch Methyl-, Äthyl- und Phenylgruppen substituierte Pyrogallole liefern mit 3-Methoxy-o-benzochinon Benzotropolone; Isopropyl- undtert. Butylgruppen in den gleichen Positionen verhindern aus sterischen Gründen die Benzotropolonbildung. Es wird versucht, aus der Produktanalyse von Benzotropolongemischen, die durch oxydative Verknüpfung von Brenzcatechinderivaten mit Pyrogallolderivaten hervorgegangen sind, Einblick in die den Mechanismus bestimmenden Faktoren zu erhalten. Verbindliche Aussagen hierüber werden durch die mangelhaften Stoffbildungen unmöglich gemacht.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 52 (1965), S. 14-15 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Communications in mathematical physics 179 (1996), S. 215-234 
    ISSN: 1432-0916
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Physics
    Notes: Abstract We present a direct approach for the calculation of functional determinants of the Laplace operator on balls. Dirichlet and Robin boundary conditions are considered. Using this approach, formulas for any value of the dimension,D, of the ball, can be obtained quite easily. Explicit results are presented here for dimensionsD=2,3,4,5 and 6.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 56 (1967), S. 973-992 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract The facies development of the Jurassic in the subbetic realm of Spain shows many common features on the whole in spite of differences in detail. “Neritic limestone facies“ may be distinguished from “Nodular limestone facies“ and “Limestone-marl-facies“. This paper deals with the stratigraphie range of red nodular limestones and “Limonite Crusts“ as equivalents of the celtiberic “Boundary Oolites“. The occurrence ofNucleata, Pygope andPosidonia in the Subbetic is discussed. There are certain facies relations to the Jurassic of the adjacent celtiberic area and especially to the Jurassic of the Western and Southern Alps.
    Abstract: Résumé Les faciès dans le Jurassique subbétique montrent, malgré des différences dans les détails beaucoup de traits communs. Il faut cependant distinguer entre le « faciès des calcaires néritiques», le « faciès des calcaires noduleux» et le « faciès des marnes et calcaires». La distribution stratigraphique des calcaires noduleux rouges et des « croutes de limonite», qui représentent les équivalents des «oolites limitrophes» celtibériques, est discuté. On commente alors l'existence deNucleata, Pygope etPosidonia dans le Subbétique. On peut constater des relations plus ou moins nettes non seulement avec le Jurassique celtibérique, mais aussi, avant tout, avec le Jurassique alpin occidental et méridional.
    Notes: Zusammenfassung Die fazielle Entwicklung des subbetischen Juras weist trotz Differenzierung im einzelnen viele gemeinsame Züge auf. Grundsätzlich ist aber zwischen einer „Neritischen Kalk-Fazies“ einer „Knollenkalk-Fazies“ und einer „Kalk-MergelFazies“ zu unterscheiden. Auf die stratigraphische Verbreitung der Roten Knollenkalke und die „Limonitkrusten“ als Äquivalente der keltiberischen „Grenzoolithe“ wird näher eingegangen, das Auftreten vonNucleata, Pygope undPosidonia im subbetisehen Jura besprochen. Sowohl zum benachbarten keltiberischen Jura als auch zum west- und südalpinen Jura sind mehr oder weniger deutliche Beziehungen vorhanden.
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  • 9
    ISSN: 1436-5073
    Keywords: Keywords. Ti-stabilized steels; soft-X-ray spectrometry; LEEIXS ; XRF ; SEM.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract  Various kinds of precipitates can influence the mechanical properties of Ti-stabilized steels. The qualitative composition of the Ti inclusions can be characterized microscopically, whereas for quantitative information to be obtained time-consuming selective dissolution must be used. The present study aims at chemical speciation of the isolated precipitates as a solid phase with the help of soft-X-ray spectrometry. Whether the method is capable of giving both qualitative and quantitative information on the composition of Ti-mixtures is discussed. The precipitates in Ti-stabilized steels are investigated after chemical dissolution of the steel matrix with a bromine/methanol mixture (1:10). By combination of soft-X-ray spectrometry with X-ray fluorescence (XRF) and scanning electron microscopy (SEM) both qualitative and quantitative characterization of the precipitates can be performed. They were found to consist mainly of TiC and TiN.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of insect conservation 1 (1997), S. 125-130 
    ISSN: 1572-9753
    Keywords: grazing ; mowing ; fens ; hay-meadows ; conservation.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Nature of Science, Research, Systems of Higher Education, Museum Science
    Notes: Abstract Traditional hay-meadows in the Alps and fens at the edge of the Alps are habitats for many rare and endangered butterfly species. Conservation efforts aim at preserving these species, but the biotopes depend on regular mowing, which in turn requires intensive financial support. The feasibility of substituting mowing of these sites by grazing is discussed and considered as a more cost effective management type which produces agriculturally valuable goods as well. In this study the butterfly fauna of mown and grazed sites were compared. Species composition, species number, and the occurrence of rare species under the two management types were in most cases rather similar for both grassland ecosystems. Nevertheless, there are hints that for single rare species this might not be true. Additionally, at one site, grazing intensity on a former hay-meadow was too high to preserve the species-rich community. Overall the results are encouraging: grazing does not have to be as detrimental as formerly thought, although details (compartments of pastures, intensity) still have to be confirmed. Experimental grazing management of aban-doned grasslands of the studied types should be started.
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