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  • Springer  (1,899)
  • 1995-1999  (1,008)
  • 1965-1969  (830)
  • 1945-1949  (61)
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  • 1
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 53 (1966), S. 537-537 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Contributions to mineralogy and petrology 129 (1997), S. 385-403 
    ISSN: 1432-0967
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The andesitic early Oligocene Taveyanne metagreywacke of the Helvetic nappes of western Switzerland shows an increase of metamorphic grade from zeolite facies through lower greenschist facies. Electron microprobe analysis, fluid inclusion thermometry, stable isotope analysis, coal rank, illite and chlorite crystallinity and thermodynamic calculations were carried out to determine metamorphic conditions. Evaluation of all techniques used in this study suggest that only combinations of different parameters yield reliable information to constrain very low-grade metamorphic conditions. Electron microprobe analyses are presented for actinolite, chlorite, epidote, phengite, laumontite, prehnite, pumpellyite, and titanite. With increasing metamorphic grade, chlorite is enriched in tetrahedral Al, pumpellyite becomes poorer in Fetot and more homogeneous in chemical composition, and titanite tends to incorporate Ti at the expense of Al and Fe3+. Metamorphic P-T conditions were determined by a combination of fluid inclusion microthermobarometry, stable isotope thermometry on quartz-calcite veins, chlorite “geothermometry” and thermodynamic calculations. Peak temperatures range from 210–250 °C for zeolite facies to 270–300 °C for prehnite-pumpellyite facies to 300–360 °C for pumpellyite-actinolite facies. An evaluation of 289 chlorite analyses indicates that the tetrahedral Al content is negatively correlated with the saponite component. Temperatures derived from chlorite “geothermometry” match maximum temperature conditions mentioned above. Illite crystallinity data for shales and slates intercalated with the Taveyanne metagreywacke indicate that the diagenetic zone correlates with the zeolite facies, the upper anchizone with the prehnite-pumpellyite facies, and the lower epizone with the pumpellyite-actinolite facies. A comparison of coal rank and illite crystallinity data (n=12,r=0.91) yielded R max values of 2.9 and 5.5% for the lower and upper boundary of the anchizone, respectively.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 46 (1996), S. 353-359 
    ISSN: 1572-8943
    Keywords: aqueous solutions ; calcium carbonate polymorphs ; dissolution reactions ; phase transitions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Thermodynamic quantities of the aragonite → calcite transition, were evaluated using results of calorimetric investigations. (1) Dissolution enthalpies of the CaCO3 polymorphs aragonite and calcite measured near room temperature with different calorimeter, (2) the enthalpy of the spontaneous phase transformation obtained by differential scanning calorimetry, (3) heat capacities and heat capacity differences determined with a heat flux calorimeter as well as previously determined, (4)e.m.f. data on Gibbs-energies of the phase transition were processed simultaneously with an optimization routine developed recently. The optimized data set (25°C) given below corresponds reasonably with CODATA recommendations, however, the precision has markedly improved.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Boundary layer meteorology 93 (1999), S. 29-45 
    ISSN: 1573-1472
    Keywords: Blowing snow ; Charge-to-mass ; Drifting snow ; Electrostatic charge ; Electric field ; Saltation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Separation of electrostatic charge during the transport of particles by wind adds a force to the gravitational and fluid forces that determine trajectories of particles moving by saltation. Evaluating this electrostatic force requires the electric field strength very near the saltation surface, and charge-to-mass ratios for the moving particles. Field mill readings 4 cm above the surface in a moderate blizzard showed electric field strength as high as +30 kV m-1. Another experiment gave charge-to-mass ratios of individual saltation particles in low-level drifting that ranged between +72 μC kg-1 and -208 μC kg-1. From these measurements, we estimated electrostatic forces as large as the gravitational force on some saltating particles. Including forces of this magnitude in the equations of motion significantly alters predicted saltation trajectories from those for uncharged particles. Predictions appear reasonable that for some saltating particles, the electrostatic force prevents new surface impacts. These results should help improve models of energy transfer in the planetary boundary layer during blizzards and sandstorms.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1435-1528
    Keywords: Key words Hexagonal ; Lamellar ; Vesicle ; Shear orientation ; Polymeric surfactant
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The shear orientation of hexagonal and lamellar liquid crystalline phases of polymeric surfactants was investigated by rheo-optical techniques (flow birefringence (Δn), small-angle light scattering) as well as by nuclear magnetic resonance and optical microscopy. The evolution of birefringence in the hexagonal phase is discussed for simple and oscillatory shear, and an alignment of rodlike micelles along the flow direction was found. A shear induced formation of vesicles (“onions”) is observed with the lamellar phase. They displayed a characteristic four-lobe pattern in depolarized light scattering. Above a critical shear stress vesicles were degraded and perpendicularly aligned lamellae (i.e. with their normal along the vorticity direction) were obtained. A comparison of experiments performed at constant stress and constant rate revealed that the vesicle to planar lamellae transition occurred above a critical shear stress. The behavior of the polysoap lyotropic mesophases under shear, i.e. the strain dependent alignment in the hexagonal phase, the shear induced formation of vesicles, and a transition to planar lamellae in the lamellar phase, is very similar to the behavior of lyotropic mesophases formed by low molar mass surfactants or amphiphilic block copolymers. The geometrical constraints that are introduced when amphiphilic side groups are fixed to a polymer backbone do not significantly alter the response of the mesophase to a shear deformation.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1572-9540
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper presents the design of the internal gas-jet target, CRYJET, which is being constructed for investigations of, e.g., fast ion--atom collisions in the heavy-ion storage and cooler ring CRYRING at the Manne Siegbahn Laboratory, Stockholm University. The goal for the design work was to create an ultra-cold He target (〈 = 10 mK in the longitudinal direction and 0.5 mK transverse temperature) with a density of ∼ 1012 atoms/cm3. Care was taken in order to minimize the influence from the jet on the very low background pressure in the storage ring (∼ 10-11 mbar). The low temperature is essential for the resolution in the experiments. The high density will enable us to get sufficient luminosities for investigations of processes with cross sections down to the 10-27 cm2 range. The gas-jet target will be equipped with two recoil-ion-momentum spectrometers in order to extract detailed information about the collision dynamics.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 243 (1968), S. 398-414 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Nach Darlegung der praktischen Schwierigkeiten, zu optimalen Meß-bedingungen für Enzymaktivitäten im Serum zu gelangen, werden Verbesserungen der Methodik für die Bestimmung von Glutamat-Oxalat-Transaminase (EC 2.6.1.1), Glutamat-Pyruvat-Transaminase (EC 2.6.1.2) und Kreatin-Phosphokinase (EC 2.7.3.2) im Serum und die mit dieser Methodik ermittelten Normalbereiche, Temperaturfaktoren und für die Transaminasen Umrechnungsfaktoren vom konventionellen zum verbesserten Test angegeben, sowie der Effekt des Pyridoxal-5-phosphatzusatzes gezeigt. Die befriedigende in vitro-Stabilität aller drei Enzymaktivitäten wird beschrieben. Schließlich werden an Beispielen die Konsequenzen der Verbesserung der Meßbedingungen für die Enzymdiagnostik diskutiert und die günstige Gelegenheit, eine methodische Änderung dieser Routinemethoden mit einer Standardisierung zu verbinden, hervorgehoben.
    Notes: Abstract After discussion of the practical difficulties in establishing optimum conditions for the determination of enzyme activities in serum, improved methods are described for the assay of glutamic oxalacetic transaminase (EC 2.6.1.1), glutamic pyruvic transaminase (EC 2.6.1.2) and creatine phosphokinase (EC 2.7.3.2) in serum and the normal ranges of the 3 enzymes in serum of adults with these methods are presented. For both transaminases the ratios of improved assay to conventional assay methods and data on the effect of temperature and the addition of pyridoxal-5-phosphate are given. The satisfying in-vitro stability of the 3 enzymes is shown. Finally, the consequences of the improved conditions of assay for diagnostic use are discussed. The opportunity of combining an impending variation of methods with their standardization is. stressed.
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