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  • Articles  (6)
  • Sulfoxides  (4)
  • Interplanetary shocks  (2)
  • 1995-1999  (6)
  • 1970-1974
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Astrophysics and space science 243 (1996), S. 123-127 
    ISSN: 1572-946X
    Keywords: Solar activity ; CMEs ; Interplanetary shocks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A scenario is presented whereby CMEs and interplanetary shocks are consequences of a large scale rearrangement of the coronal magnetic field induced by the disconnection of field lines from the solar surface due to the emergence of flux with opposite polarity. In this scenario the CME is the mass released from the previously closed structure and the interplanetary shock is formed by the injection of faster solar wind from an extended or newly created coronal hole which results from the opening of the field lines. Here CMEs and interplanetary shocks are associated events, but not cause-effect related. Observational and computational evidence supporting this view is provided.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Annales geophysicae 16 (1998), S. 359-369 
    ISSN: 0992-7689
    Keywords: Interplanetary physics ; Interplanetary shocks ; Solar wind plasma ; Solar physics ; Flares and mass ejections
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Interplanetary transients with particular signatures different from the normal solar wind have been observed behind interplanetary shocks and also without shocks. In this paper we have selected four well-known transient interplanetary signatures, namely: magnetic clouds, helium enhancements and bidirectional electron and ion fluxes, found in the solar wind behind shocks, and undertaken a correlative study between them and the corresponding solar observations. We found that although commonly different signatures appear in a single interplanetary transient event, they are not necessarily simultaneous, that is, they may belong to different plasma regions within the ejecta, which suggests that they may be generated by complex processes involving the ejection of plasma from different solar regions. We also found that more than 90% of these signatures correspond to cases when an Hα flare and the eruption of a filament occurred near solar central meridian between 1 and 4 days before the observation of the disturbance at 1 AU, the highest association being with flares taking place between 2 and 3 days before. The majority of the Hα flares were also accompanied by soft X-ray events. We also studied the longitudinal distribution of the associated solar events and found that between 80% and 90% of the interplanetary ejecta were associated with solar events within a longitudinal band of ±30° from the solar central meridian. An east-west asymmetry in the associated solar events seems to exist for some of the signatures. We also look for coronal holes adjacent to the site of the explosive event and find that they were present almost in every case.
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  • 3
    ISSN: 1434-193X
    Keywords: Fluorine ; Lactones ; Annulation ; Ketene ; Sulfoxides ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Enantiomerically pure α,α-dichloro β-fluoroalkyl γ-p-tolylthio γ-butyrolactones trans-6a-c have been obtained with excellent stereocontrol (〉 98:2) and enantiomeric purity (〉 98:2) by sulfoxide-directed lactonization (Marino's annu-lation reaction) of β-fluoroalkyl vinyl sulfoxides (R)-(E)-5a-c with dichloroketene. Highly chemoselective dechlorination and desulfurization reactions performed on trans-6c efficiently provided the β-chlorodifluoromethyl γ-butyrolactone (S)-8c, the absolute stereochemistry of which was determined by X-ray diffraction analysis of its γ-p-tolylthio precursor (2R,3S)-7c.
    Additional Material: 1 Ill.
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  • 4
    ISSN: 1434-193X
    Keywords: Fluorine ; Pheromones ; Sulfoxides ; Sulcatol ; Asymmetric synthesis ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -The pheromone (R)-(-)-sulcatol (10a) and three of its enantiomeric mono-, di-, and trifluoro analogues 10b-d have been synthesized, in six steps and with good overall yields, starting from chiral (R)-2-methyl-5-[(4-methylphenyl)sulfinyl]pent-2-ene (1) and commercially available fluorinated or non-fluorinated acetates.Supporting information for this article is available on the WWW under http://www.wileY-Vch.de/contents/jc_2046/1999/98375_s.pdf or from the author.
    Additional Material: 2 Tab.
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  • 5
    ISSN: 1434-193X
    Keywords: Fluorine ; Cycloadditions ; Nitrones ; Asymmetric induction ; Sulfoxides ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 3-(Fluoroalkyl)isoxazolidines 6 and -2,3-dihydroisoxazoles 8 have been obtained in enantiomerically pure form with good diastereoselectivity by 1,3-dipolar cycloaddition of diethyl fumarate and dimethylacetylene dicarboxylate, respectively, to the chiral fluorinated nitrone (R)-5. The latter has been prepared from the β-fluoromethyl-β-oxo sulfoxide (RS)-1, by a synthetic sequence where the chiral and enantiomerically pure sulfinyl function acts as a removable source of chirality. Reductive opening of isoxazolidines 6 then afforded amino fluoromethyl diols 7 in good yields.
    Additional Material: 1 Ill.
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  • 6
    ISSN: 1434-193X
    Keywords: Fluorine ; Sulfoxides ; Nucleotide analogues ; Asymmetric synthesis ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: D- and L-(diethoxyphosphoryl)difluoromethyl nucleoside analogues 10 have been synthesized using the building block approach, starting from chiral fluorinated molecules. The key steps of the synthetic sequence were condensation of 2-methyl-5-(4-methylphenylsulfinyl)pent-2-ene (1) and ethyl 2-(diethoxyphosphoryl)-2,2-difluoroacetate (2), reduction of the thus formed ketones 3 to alcohols 4, reductive removal of the sulfur moiety to give hydroxy phosphonates 6, and oxidative cyclization to give furanose derivatives 8.
    Additional Material: 3 Tab.
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