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  • Wiley-Blackwell  (73)
  • American Chemical Society (ACS)
  • 1995-1999  (13)
  • 1970-1974  (38)
  • 1965-1969  (22)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 6 (1973), S. 454-456 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 5 (1972), S. 91-101 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Relations form the theory of characteristics are used to connect boundary and interior points in the numerical analysis of multidimensional, unsteady gas dynamics.Since specification of all variables on the boundaries does not occur, it is necessary to employ at least some of the differential equations for boundary points. The objective is to avoid the use of non-central finite differences and the subsequent generation of a pseudo-boundary layer.Boundaries consisting of a moving shock wave, a solid wall and a surface in a supersonic, downstream region are considered. The numerical procedure for determining variables on boundaries is described in datail for the hypersonic, blunt body problem.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 277-287 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Studies have been made on the dynamic and steady-shear melt rheology of an ethylene-methacrylic acid copolymer and two of its salts obtained by partial neutralization with sodium and with calcium bases. Measurements were made with a Weissenberg rheogoniometer over a broad range of shear rates and frequency in the temperature interval mainly from 100 to 160°C. The temperature coefficients of dynamic and steady shear viscosity are evaluated at both constant shear rate and constant stress. Likewise, complex dynamic viscosities and apparent high steady-flow viscosities and intercompared at equivalent frequencies and shear rates. The un-ionized acid copolymer shows good correlation between the frequency dependence of the complex viscosity and the shear rate dependence of the apparent viscosity. This is not true for either the sodium salt or the calcium salt. These results are consistent with the two-phase structural model for these materials, i.e., a matrix of hydrocarbon in which are embedded ionic domains.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 335-340 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Gel permeation chromatography was used to follow changes in the molecular weight distribution of a polyisobutene, initial Mv = 466,000, during degradation induced by sonic irradiation. Seven samples taken at times of 200-163,500 sec. were studied. In general, a steady decrease in molecular weight was observed, although a bimodal distribution was present after 20,000 sec. irradiation. Various measures of inhomogeneity, Mw/Mn, U, etc., were examined. The function, σn/Mw, where σn is the standard deviation of the number distribution, is considered as a measure of the relative distribution. It is shown to be almost constant throughout the degradation.
    Additional Material: 4 Ill.
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  • 5
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A group of C14-tagged ethylene and propylene polymers consisting of physical mixtures of homopolymers, block copolymers made up of two homopolymer sequences, and block copolymers made up of several homopolymer segments has been studied by differential thermal analysis (DTA). The effect of randomness in copolymers has also been studied in this set of systems, which contains 0-51 wt.-% ethylene. Block copolymers and physical mixtures have been found to have thermograms with endothermal minima at approximately 138 and 163°C. The ratio of heights of the two minima has been found to be a function of the ethylene and propylene content for mixtures of homopolymers and for block copolymers without randomness. DTA thus provides an analysis for monomer ratios in physical mixtures and in block copolymers of ethylene and propylene. The cooling thermograms of block copolymers have been demonstrated to have two exotherms in all cases where the block ethylene content exceeded 10%; the propylene limit was not fixed. Mixed homopolymers do not exhibit two freezing exotherms. The total heat of fusion of the polymer has been found to be a usable measure of chain randomness and block nature. The conditions for observation of single and multiple transitions have been extended.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 2215-2226 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A general treatment is given of the methods to be used in other parts of this series for calculating the degree of chemical crosslinking in natural rubber vulcanizates from stress-strain measurements in extension and from equilibrium volume swelling measurements. Corrections are required for the presence in the vulcanizate of appreciable quantities of particulate solids or soluble diluents and for the introduction of foreign atoms into the rubber network. For this purpose distinction is made between the rubber vulcanizate, the rubber matrix, the rubber network, and the rubber hydrocarbon component of the network. Expressions are derived, in terms of these concepts, for the Money-Rivlin parameter, C1, measured on vulcanizates which have undergone various treatments.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 1805-1819 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Isoprene was polymerized in batch reactors by use of bottle polymerization techniques at 30°, 40°, and 50°C at concentrations from 1 to 5 molar. Butyllithium concentration was varied from 0.005 to 0.03 molar. Isoprene and n-butyllithium conversions and molecular weight distributions were determined for different reaction times. Rate equations for the initiation and propagation reactions are presented. The importance of the association reactions in obtaining a narrow molecular weight distribution is illustrated.
    Additional Material: 8 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 532-537 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Radiation absorption at the surface of catalytic particles is the initial step of photocatalytic oxidation reactions currently considered for their potential effectiveness in the treatment of polluted water with traces of highly toxic organics. Owing to the presence of catalyst particles within the fluid phase, the radiation field within a photocatalytic reactor results from the absorption and scattering within the participating medium. An annular reactor with a coaxial central lamp was considered, and the resulting 2-D radiation field was analyzed using a Monte Carlo technique to solve the radiative transfer equation. Results are discussed based on the relevant optical parameters, and a heuristic is derived for the design and rating of a photocatalytic reactor. To exploit the reaction volume effectively, the order of magnitude of the optical thickness should be close to unity, and for a given value of the absorption coefficient the catalyst with the lowest albedo should be selected; however, a precise evaluation of the phase function is not crucial to a relable representation of the radiation field.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 8 (1995), S. 243-248 
    ISSN: 0894-3370
    Keywords: Engineering ; Electrical and Electronics Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Two separate exercises on a similar theme are reported. In the first, the moment-method program NEC was extensively modified in order to optimize its performance on a four-processor Cray X-MP computer. In the second exercise, the MININEC moment-method program was completely rewritten into the occam programming language so that it could be executed directly by a transputer system. The NEC exercise exploited judicious use of vectorization and alternative parallelization techniques and achieved a reduction of run times by factors of about five or more. The MININEC exercise has so far achieved only a modest reduction in run-time but it has the potential for a much greater improvement if an optimum strategy for configuring the transputer network is implemented.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 536-541 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The processes of absorption and desorption with reversible reaction are compared theoretically for reactions of the type A ⇌ nB. With the same concentration difference between bulk and interface, it is found that in general, the rate of desorption is lower than that of absorption. Under certain conditions the difference may be as much as 35%.The analysis is based on the penetration theory. The numerical solution introduces a new transformation of the time and distance variables (based on the error function) which reduces the computing time required. An analytical examination of the penetration theory equations provides an explanation of the results of the numerical solution.
    Additional Material: 6 Ill.
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