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  • Solid-state13C NMR  (1)
  • 1995-1999  (1)
  • 1975-1979
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  • 1995-1999  (1)
  • 1975-1979
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Structural chemistry 6 (1995), S. 161-165 
    ISSN: 1572-9001
    Keywords: Solid-state13C NMR ; 13C NMR ; fluorescein ; quinone ; zwitterion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The structures of colorless, red, and yellow-orange fluorescein have been investigated by a combination of solution and solid state13C NMR. It is demonstrated that the three forms have lactonic, zwitterionic, and quinoid structures, respectively. Conflicting X-ray, NMR, and IR structural evidence is discussed for samples of red fluorescein which cannot readily be obtained in definite crystalline form. It is concluded that solid-state13C NMR spectroscopy is superior by revealing primarily the molecular structure but being fairly insensitive toward lattice variations.
    Type of Medium: Electronic Resource
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