ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On the RbNiCrF6 Type. III. New Fluorides of the Type CsZnMF6 (M = Al, Ga, In, Tl, Sc, Ti, V, Mn, Cu, Rh)Cubic compounds are CsZnGaF6 [3] (colourless, a = 10.29 Å); CsZnInF6 (colourless, a = 10.58 Å); CsZnTlF6 (colourless, a = 10.62 Å); CsZnScF6 (colourless, a = 10.58 Å); CsZnTiF6 (lightblue, a = 10.50 Å); CsZnVF6 (lightgreen, a = 10.43 Å); CsZnMnF6 (redbrown, a = 10.40 Å); CsZnCuF6 (light brown, a = 10.24 Å); CsZnRhF6 (redbrown, a = 10.41 Å), all RbNiCrF6 type of structure, in addition non cubic: CsZnAlF6 (colourless).The Madelung part of lattice energy, MAPLE, is calculated and discussed.
Notes:
Kubisch kristallisieren CsZnGaF6 [3] (farblos, a = 10,29 Å); CsZnInF6 (farblos, a = 10,58 Å); CsZnTlF6 (farblos, a = 10,62 Å), CsZnScF6 (farblos, a = 10,58 Å); CsZnTiF6 (hellblau, a = 10,50 Å); CsZnVF6 [3] (hellgrau, a = 10,43 Å); CsZnMnF6 (rotbraun, a = 10,40 Å); CsZnCuF6 (ocker, a = 10,24 Å); CsZnRhF6 (rotbraun, a = 10,41 Å), alle RbNiCrF6-Typ; jedoch nicht kubisch: CsZnAlF6 (farblos). Der Madelunganteil der Gitterenergie, MAPLE, wird berechnet und diskutiert.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19774280110
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