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  • 1
    Electronic Resource
    Electronic Resource
    The Transition Metal-Nitrogen Multiple BondDedicated to Professor Josef Goubeau on the occasion of his 80th birthday (1981)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 20 (1981), S. 413-426 
    Details
    ISSN: 0570-0833
    Keywords: Multiple bonds ; Bond theory ; Nitrido ligand ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Numerous nitrido complexes of transition metals show very short metal-nitrogen bond lengths, suggesting M≡N-triple bonds. At present, compounds of this type are being intensively investigated. In particular the molybdenum complexes are considered as model substances for the study of at least an intermediate step of N2-assimilation. This article contains a review of the structure and bonding, as well as syntheses and reactions of these complexes.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.198104133
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  • 2
    Electronic Resource
    Electronic Resource
    Osmium-Nitridtrichlorid, OsNCl3 (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1205-1208 
    Details
    ISSN: 0044-2313
    Keywords: Osmium Nitridotrichloride ; synthesis ; IR spectrum ; magnetic susceptibility ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Osmium Nitridotrichloride, OsNCl3OsNCl3 was prepared by the reaction of (NH4)2[OsNCl5] with chlorine at 300°C, forming a black, X-ray amorphous moisture sensitive, paramagnetic powder which was characterized by IR spectroscopy and measurement of the magnetic susceptibility in the range of 5-300 K.
    Notes: OsNCl3 wird als schwarzes, röntgenamorphes, feuchtigkeitsempfindliches paramagnetisches Pulver durch Reaktion von (NH4)2[OsNCl5] mit Chlor bei 330°C hergestellt und IR-spektroskopisch sowie durch magnetische Suszeptibilitätsmessungen im Bereich von 5-300 K charakterisiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19966220717
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