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  • Polymer and Materials Science  (2,371)
  • Occupational Health and Environmental Toxicology  (84)
  • Wiley-Blackwell  (2,455)
  • 1995-1999  (1,209)
  • 1980-1984  (1,246)
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  • Wiley-Blackwell  (2,455)
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Year
  • 11
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 1819-1833 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multiblock copolymers offer the possibility to combine the properties of different polymers. Thus, new materials with tailor-made unique properties are available by coupling of different suitable polymeric segments. The goal of the work discussed in this paper was to combine advantageous properties of liquid-crystalline polymers (LCP) with those of polysulfone (PSU). Therefore, liquid crystalline poly(ethylene terephthalate-co-1,4-oxybenzoates) were connected with PSU oligomers. Chemically homogeneous multiblock copolymers with high molecular weight were obtained by a melt transesterification procedure. It was demonstrated by wide angle x-ray scattering (WAXS), polarizing microscopy, transmission electron microscopy (TEM), and differential scanning calorimetry (DSC) that the properties of the multiblock copolymers (solid phase structure, phase behavior, morphology, glass transition, and melting behavior) can be balanced by the segment length of the incorporated blocks. The investigations clearly reveal the existence of a two-phase structure. However, a change of properties compared to the corresponding homopolymers refers to certain interactions between the phase due to the chemical connection of the LCP and PSU segments. © 1996 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1151-1155 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyurethanes were synthesized by the reaction of hydroxyterminated polybutadiene (HTPB) and diisocyanates such as toluene diisocyanate (TDI), diphenylmethane diisocyanate (MDI), hexamethylene diisocyanate (HMDI), and isophoron diisocyanate (IPDI). A number of fillers such as carbon black, kaolin, and antimony trioxide (Sb2O3) were used in these formulations. Mechanical and thermal stability of these polyurethanes were studied. Based on its properties, HTPB-MDI derived filled polyurethane was selected and evaluated as an inhibitor for a composite propellant. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 26 (1981), S. 509-519 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The deterioration of polyolefin, poly(ethylene terephthalate), and polyamide films under soil burial conditions extending up to 32 months has been investigated. Based on changes in their elongation at break, the films can be ranked in order of increasing sensitivity to degradation: Polyester ≃ polypropylene 〈 low-density polyethylene ≃ high-density polyethylene 〈 nylon 6.6. The degraded nylon 6.6 and polyethylene films were characterized by infrared and luminescence spectroscopy and scanning electron microscopy, as well as by wet analysis for hydroperoxides. From a comparison with the well-known oxidative sensitivity of nylon 6.6 in oxygenated water at slightly elevated temperatures, the rapid deterioration of nylon 6.6 film during soil burial was also concluded to be an oxidative process. The somewhat smaller, but significant, embrittlement of the polyethylenes studied could not be simply explained by thermal oxidation (with only trace oxidation products detectable) or microbiological attack (deterioration being unaffected by surface activation to enhance wettability).
    Additional Material: 5 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 17 (1983), S. 59-70 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Porous high-density polyethylene specimens were implanted in the femurs of mongrel canines. At the end of the residency period (3 or 6 months), the animals were sacrificed and the implants were retrieved. The work-of-fracture of the implant specimens was then determined using the technique of Tattersall and Tappin. The work required to fracture a specimen in three-point bending by controlled crack propagation through a triangular cross section was obtained directly from the load-deflection curve. The area of the resulting fracture surface was measured by macro-photographic techniques, and the work-of-fracture was calculated as work per unit area. The implants were subsequently sectioned and examined microradiographically to determine the extent of bone ingrowth. Bone specimens adjacent to the implants and porous high-density polyethylene controls (no ingrowth) were also tested to determine their work-of-fracture. The results showed that bone adjacent to the implant specimens had a higher work-of-fracture than normal medial, canine femoral bone and was not appreciably different from the composite. The work-of-fracture of porous high-density polyethylene was not significantly increased by an increase in bone infiltration, and this anomalous behavior was attributed to a degradation of the polyethylene during implant residence. Control studies supported this hypothesis.
    Additional Material: 7 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 16 (1982), S. 381-398 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Numerous hypotheses exist to explain observed blood-materials interactions. It is the purpose of this article to test two popular hypotheses, namely, the minimum interfacial free energy hypothesis and the optimum polar/apolar ratio hypothesis. Methacrylate polymers and copolymers were characterized using the captive bubble underwater contact angle method; bulk water content was determined by gravimetric methods; streaming potential measurements were made; and surface roughness and possible particulate contamination were evaluated by reflected light microscopy. In vitro blood tests include whole blood clotting time measurements on polymer-coated tubes; centrifugal force platelet adhesion on polymer-coated coverslips; and a measure of the partial thromboplastin time, Russell's viper venom time (Stypven time), and the prothrombin time of native whole blood exposed to polymer-coated microscope slides. Results suggest that platelet adhesion correlates in the opposite direction of whole blood clotting time and partial thromboplastin time, emphasizing the need for a multiparameter approach to blood-materials testing. Based on these tests the minimum interfacial free energy hypothesis is not supported. In fact, the data suggest the opposite to be true. It is apparent that platelet adhesion can be a misleading indicator of blood compatibility. Neither hypotheses can explain the apparent conflict between the platelet adhesion data and the coagulation time data.
    Additional Material: 9 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 2 (1980), S. 5-10 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Mean free paths for inelastic scattering (λ) of low energy electrons in poly(methylmethacrylate) (PMMA) have been determined by measuring Al Kα excited C 1s and Si 2s photoelectron signal intensities as a function of ellipsometrically determined thicknesses of PMMA overlayers on silicon substrates. The λ values obtained are 29 ± 4 Å for 1196 eV electrons and 33 ± 5 Å for 1328 eV electrons. These data are necessary for the quantitative analysis of the surface region of PMMA and similar polymers by X-ray photoelectron spectroscopy (XPS). The magnitude of the λ values determined indicates that XPS measurements can provide chemical information about the surface region of polymers, such as PMMA, in the depth range of ∼6 to 100 Å. The results of this study are compared and discussed with respect to λ values determined for other organic compounds.
    Additional Material: 7 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 26 (1998), S. 461-470 
    ISSN: 0142-2421
    Keywords: W/TiN/Ti/Si contact structure ; MULSAM ; TEM ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The W/TiN/Ti/Si contact structures needed for ultra-large-scale integrated circuits have been studied using cross-sectional transmission electron microscopy (TEM) and multi-spectral Auger electron microscopy. Access to the Ti/Si interface for chemical characterization using SEM, Auger and electron energy-loss imaging and spectroscopy has been achieved by using a novel method of bevelled polishing of the silicon substrate material. Cross-sectional TEM was used to calibrate the depth scale in the MULSAM image sets, so allowing measurements of the thicknesses of various interfacial layers and the penetration of the ohmic contacts into the silicon. The TiN layer, providing adhesion of the tungsten as well as acting as a diffusion barrier, appears to have a domed shape, which penetrates the tungsten overlayer to a greater extent in the contact centres. The results of this work, combined with earlier, related, studies, enable a three-dimensional characterization of the bottom and sidewall structures in these contacts. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
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  • 18
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 204-210 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Atomic force microscopy (AFM) shows that PTFE-on-silicon wafer tribological transfer films consist of narrow ribbons of PTFE, 〈1 μm wide and 〈10 nm high, aligned with the film draw direction. Within the ribbons the PTFE molecular chains are also aligned with the draw direction. Such materials are of interest as substrates for the epitaxial crystallization of polymers and small molecules. X-ray photoelectron spectroscopy demonstrates that the amount of PTFE put down increases with deposition temperature and pressure. The XPS azimuthal angle dependence at low electron take-off angle is consistent with the aligned ribbon morphology. Azimuthal and polar angle dependence and charging studies show that hydrocarbon contamination observed in the XPS spectrum is located on top of the silicon wafer substrate, in the channels between the PTFE ribbons. Imaging XPS confirms the pressure dependence of PTFE coverage, and at low deposition pressure reveals tracks of PTFE ∽100 μm wide, aligned with the film draw direction. Together with the AFM data this leads to a description of PTFE transfer films as fractal materials.
    Additional Material: 6 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 2817-2834 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal degradation behavior of poly(1,3-phenylene isophthalamide) and poly(chloro-2,4-phenylene isophthalamide) was investigated with the aid of some appropriate model compounds. The pyrolysis products of these materials were identified by gas chromatography (GC), gas chromatography/Fourier transform infrared spectroscopy (GC/FT-IR), and gas chromatography/mass spectrometry (GC/MS). The residual chars were characterized by IR spectroscopy. Thermogravimetric analysis (TGA) was applied to study the effect of end-group concentration on the degradation characteristics of the two polyamides. Kinetic parameters that describe the thermal degradation of the polyamides were also evaluated by TGA. The results of this investigation suggest that the thermal decomposition of these aromatic polyamides involves homolytic as well as hydrolytic cleavages of the amide units.
    Additional Material: 13 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 79-88 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: There are two major fire processes, an understanding of which is essential for effective fire safety design: (1) the conditions under which a combustible material may become involved in flaming combustion, and (2) the rate at which such a material, once involved, will provide an output of heat, smoke, toxic gases, etc., which can endanger people and property. The first process may be regarded as covering both ignition and spread of fire on materials; its complement is the way in which fire may become extinguished. It is necessary for such processes to bring in a characteristic of the basic combustion reaction which, directly or indirectly, expresses the reactivity of the combustion process. Thus pilot ignition is usually associated with an approximate surface fuel temperature. More basically, it is associated with a critical flow rate of volatiles and a critical heat loss from the flame, the latter being influenced by ambient oxygen and temperatures conditions as well as heat lost and gained by the fuel itself. The most important factor governing the production of dangerous product is the rate at which volatiles first (fuel controlled fires) and later air (air controlled fires) are fed into the flames. The reactivity is of less importance, although it may be one of the factors which control combustion efficiency. In general, the more efficient is the combustion the more heat is produced, but the less smoke and toxic gases are produced. Some of the main advances in the above areas are reviewed in this paper.
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