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  • Polymer and Materials Science  (4)
  • Three dimensional  (1)
  • Wiley-Blackwell  (5)
  • Elsevier
  • 1995-1999
  • 1980-1984  (5)
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 183 (1982), S. 1093-1099 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: N-Vinylcarbazole (NVC) is polymerised in the presence of pyridine at 60°C by using azodiisobutyronitrile (AIBN) and benzoyl peroxide (Bz2O2) as initiators and the results are compared with those obtained when benzene is used as the solvent. In the AIBN-initiated system using pyridine as the solvent the rates of polymerisation follow an usual linear relationship with respect to monomer concentration and a square root dependence with respect to the initiator concentration. In the Bz2O2-initiated system, however, deviations from these ideal behaviours are observed when benzene and pyridine, respectively, are used as the solvent. Initiation occurs through the complexation of the monomer with Bz2O2 and degradative transfer is thought to be mainly responsible for this unusual kinetic behaviour.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 23 (1984), S. 1565-1594 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The observed Raman and ir spectra of Ca-poly(L-glutamate) in the β conformation have been analyzed by means of a normal mode calculation. The force field for the main chain was transferred without refinement from β-poly(L-alanine), yet it provides a good prediction of the observed bands and, in particular, explains subtle differences in the spectra of these two β-sheet structures. Main- and side-chain modes are well characterized, and the dependence of the amide III frequency on side-chain composition is again demonstrated.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 1 (1981), S. 145-169 
    ISSN: 0271-2091
    Keywords: Numerical Model ; Estuary ; Open Boundary Condition ; Three dimensional ; Hydrothermal Biscayne Bay ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A three-dimensional time dependent free-surface model has been used to simulate the velocity and temperature distributions in Biscayne Bay, an estuarine basin in South Florida. Comparisons with tide gauge data and airborne infrared temperature data have been made. Analyses of three-dimensional velocity structure, phase relationships of velocity with depth and horizontal location have been conducted.One of the major concerns with three-dimensional models is the specification of conditions at open-boundaries, since it is rare that complete time dependent variations of variables at these boundaries are available. Two sets of approximate boundary conditions at the Biscayne Bay-Atlantic Ocean interface have been used for computations. It was found that specification of averaged surface height variation at open boundaries yield significantly better results than specification of estimated values of velocity.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 5 (1984), S. 295-299 
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 5 (1984), S. 441-446 
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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