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  • Engineering General
  • Organic Chemistry
  • 1995-1999  (7)
  • 1980-1984  (11)
  • 1945-1949  (4)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 65 (1982), S. 2422-2430 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The water relaxation rates of several flavoproteins in the semiquinone state have been investigated by the spin echo technique. The results indicate a rather unspecific interaction between water and the protein-bound flavosemiquinones. An average interaction distance of 0.3-0.5 nm has been estimated. From the temperature dependence of the rate constants the free energy of activation for proton exchange is calculated to be about 17 kJ/mol. The rate of proton exchange is around 1011 s-1 for the flavosemiquinones investigated are accessible to water regardless of their ionic state.The large difference in relaxation rates of water protons between D- and L- amino-acid oxidases is noticeable. Oxynitrilase exhibits the highest whereas Azotobacter vinelandii flavodoxin shows the lowest water relaxation rate of the flavoproteins studied. The results are discussed in relation to the visible-light absorption properties of the flavoproteins.
    Additional Material: 1 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 63 (1980), S. 1296-1303 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Flavinium salts dissolved in an ethanolic glass exhibit blue fluorescence and orange-red phosphorescence upon excitation with a UV. line from an argon ion laser equipped with UV. optics. This arrangement enables the wavelength distribution and the time-dependence of the phosphorescence to be measured in a relatively short time. Four cationic flavins were investigated. In spite of the small difference in the chemical structure of the compounds studied, large differences in the spectral shapes and in the ratio of quantum efficiencies of phosphorescence and fluorescence became apparent. The phosphorescence lifetimes were of the same order of magnitude, which indicated a similar rate of depletion of the lowest excited triplet state for all four cations. However, the efficiency of triplet formation (intersystem crossing) is affected by slight structural modifications in the pyrimidine subnucleus of the flavinium salt. The results point to a possible role of vibronic spin-orbit coupling in the intersystem crossing.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 17 (1981), S. 1740-1742 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 30 (1947), S. 1782-1783 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 20 (1995), S. 671-693 
    ISSN: 0271-2091
    Keywords: airfoil ; artificial viscosity ; upwinding ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The numerical solution of the compressible Euler and Navier-Stokes equations in primitive variables form requires the use of artificial viscosity or upwinding. Methods that are first-order-accurate are too dissipative and reduce the effective Reynolds number substantially unless a very fine grid is used. A first-order finite element method for the solution of the Euler and Navier-Stokes equations can be constructed by adding Laplacians of the primitive variables to the governing equations. Second-order schemes may require a fourth-order dissipation and higher-order elements. A finite element approach is proposed in which the fourth-order dissipation is recast as the difference of two Laplacian operators, allowing the use of bilinear elements. The Laplacians of the primitive variables of the first-order scheme are thus balanced by additional terms obtained from the governing equations themselves, tensor identities or other forms of nodal averaging. To demonstrate formally the accuracy of this scheme, an exact solution is introduced which satisfies the continuity equation identically and the momentum equations through forcing functions. The solutions of several transonic and supersonic inviscid and laminar viscous test cases are also presented and compared to other available numerical data.
    Additional Material: 17 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 22 (1996), S. 603-618 
    ISSN: 0271-2091
    Keywords: shallow water equations ; wave continuity equation ; boundary conditions ; finite elements ; generalized functions ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Finite element solution of the shallow water wave equations has found increasing use by researchers and practitioners in the modelling of oceans and coastal areas. Wave equation models, most of which use equal-orderC0 interpolants for both the velocity and the surface elevation, do not introduce spurious oscillation modes, hence avoiding the need for artificial or numerical damping. An important question for both primitive equation and wave equation models is the interpretation of boundary conditions. Analysis of the characteristics of the governing equations shows that for most geophysical flows a single condition at each boundary is sufficient, yet there is not a consensus in the literature as to what that boundary condition must be or how it should be implemented in a finite element code. Traditionally (partly because of limited data), surface elevation is specified at open ocean boundaries while the normal flux is specified as zero at land boundaries. In most finite element wave equation models both of these boundary conditions are implemented as essential conditions. Our recent work focuses on alternative ways to numerically implement normal flow boundary conditions with an eye towards improving the mass-conserving properties of wave equation models. A unique finite element formulation using generalized functions demonstrates that boundary conditions should be implemented by treating normal fluxes as natural conditions with the flux interpreted as external to the computational domain. Results from extensive numerical experiments show that the scheme does conserve mass for all parameter values. Furthermore, convergence studies demonstrate that the algorithm is consistent, as residual errors at the boundary diminish as the grid is refined.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 23 (1996), S. 673-690 
    ISSN: 0271-2091
    Keywords: Euler equations ; directionally adaptive meshes ; edge-based error estimate ; structured grids ; mesh movement ; finite element method ; high-speed flows ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The present paper describes a directionally adaptive finite element method for high-speed flows, using an edge-based error estimate on quadrilateral grids. The error of the numerical solution is estimated through its second derivatives and the resulting Hessian tensor is used to define a Riemannian metric. An improved mesh movement strategy, based on a spring analogy, but with no orthogonality constraints, is introduced to equidistribute the lengths of the edges of the elements in the defined metric. The grid adaptation procedure is validated on an analytical test case and the efficiency of the overall methodology is investigated on supersonic and hypersonic benchmarks.
    Additional Material: 21 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 7 (1983), S. 385-393 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 2 (1982), S. 317-330 
    ISSN: 0271-2091
    Keywords: Transonic flow ; Turbomachines ; Finite elements ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this work a study of the application of the finite element method to transonic flows in axial turbomachines is undertaken.Solution techniques capable of accurately predicting flows from the incompressible regime up to the establishment of shocks in the transonic regime are presented. In the subsonic and shockless transonic regimes a local linearization method capable of very rapid convergence is used. In the full transonic regime the artificial compressibility method is employed to exclude downstream influences in the supersonic regions. The two approaches can be combined in a unified package and appropriate switches introduced to select the relevant method in any flow regime.
    Additional Material: 14 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 3 (1983), S. 1-21 
    ISSN: 0271-2091
    Keywords: Turbomachines ; Finite Elements ; Transonic Flows ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A numerical approximation is taken to the solution of the complex flows existing in gas turbine engines with transonic blading. The quasi-3D approach decouples the problem into through-flow and blade-to-blade solutions. An industrially practical finite element through-flow solution is developed and for blade-to-blade solutions a transonic finite areas method is utilized. The finite element code developed is capable of operating in an analysis or a design mode. In both modes a dynamic relaxation factor is employed and considerable reduction in solution time can be achieved. Comparisons to streamline curvature methods are carried out for simple analytical and complex industrial problems.
    Additional Material: 21 Ill.
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