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  • Analytical Chemistry and Spectroscopy  (11)
  • General Chemistry  (3)
  • Chemical Engineering  (2)
  • Constant volume Varigrad
  • Engineering
  • Wiley-Blackwell  (16)
  • 1995-1999  (7)
  • 1985-1989  (9)
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  • Wiley-Blackwell  (16)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 9 (1986), S. 345-349 
    ISSN: 0935-6304
    Keywords: Isothermal vs programmed indices ; Coefficient of index increase ; Equivalent isothermal temperature ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A systematic approach was utilized to deduce the relation between the programmed and isothermal retention indices in chromatography. The relation was given in the form of a chart from which the equivalent isothermal temperature Te is plotted vs ΔT′ with IP as the parameter. ΔT′ is a function of both the inlet and outlet temperatures during the temperature programmed run and Te is the temperature at which the isothermal index is equal to the programmed index IP.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 9 (1986), S. 242-247 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, LC ; Gradient elution ; Hydrostatic equilibrium ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Gradient elution under hydrostatic equilibrium is extended to the treatment of the case where the two liquids have different densities. Analytic expressions are derived only for the cases where both mixing chamber and reservoir have constant cross-sectional areas.As in the case where the densities of the liquids are equal, pressigned concentration gradients can be duplicated quite satisfactorily by combining a mixing chamber having a constant cross-sectional area and a reservoir having an area which changes linearly with reservoir height. A numerical example is given to illustrate the use of the derived equations.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 681-683 
    ISSN: 0935-6304
    Keywords: Theory ; Separation efficiency ; Unequal peaks ; Direct method ; Impirical equation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 12 (1989), S. 342-345 
    ISSN: 0935-6304
    Keywords: Retention relationships ; General equation ; Iterative procedure ; Logarithmic and linear indices ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Tab.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 592-594 
    ISSN: 0935-6304
    Keywords: Dimensionless volume ; Approximate functions ; Exact relationship ; Preparative chromatography ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 678-680 
    ISSN: 0935-6304
    Keywords: Programed time ; Initial and final slopes ; xm fit and log fit ; Equivalent temperature ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Microcolumn Separations 7 (1995), S. 199-206 
    ISSN: 1040-7685
    Keywords: micellar electrokinetic chromatography ; capillary electrophoresis ; bile salts ; metal-ligands ; chiral separations ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We have utilized micellar electrokinetic chromatography with sodium deoxycholate micelles to separate the enantiomers of bis(8-((pyridine-2-methylene)amino)quinoline)iron(II) hexafluorophosphate, Fe(PMAQ)2(PF6)2, bis(8-((pyridine-2-methylene)amino)lepidine iron(II) hexafluorophosphate, Fe(PMAL)2(PF6)2, and bis(1-(2-pyridinyl)ethylidine)-8-aminoquinoline iron(II) hexafluorophosphate, Fe(PEAQ)2(PF6)2. The influence of 13 water miscible organic additives on the resolution of each pair of enantiomers was investigated. Significant changes in resolution are seen depending upon the particular organic additive used in the separation buffer. In addition, the effects of acetone concentration on the resolution of these enantiomers in bile salt solution was investigated. Resolution for all three pairs of enantiomers is maximized in a buffer solution containing 15% acetone. © 1995 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 2146-2147 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 1815-1823 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite-element analysis of Taylor flow in a cylindrical capillary was performed using a commercial FEM program (FIDAP) to solve the fundamental fluid dynamics equations together with the capillary forces at the gas-liquid interface. A moving-surface formulation was used to calculate the bubble shape. The thickness of the liquid film surrounding the gas bubble, the degree of mixing in the liquid phase, and the slip velocity between the two phases were calculated. These parameters influence the performance of monolith reactors operating in the Taylor flow regime. On comparison with experimental results it was found that the FEM calculation generally predicts a thinner liquid film, which can possibly be explained in terms of a peripheral variation in surface tension. Moreover, the wavelength of the wiggles predicted in the liquid film near the tail end of the bubble was compared to those arising from a simplified mathematical analysis available in the literature. Good agreement was found for Ca 〈 0.005, while for higher Ca the FEM predicts significantly shorter wavelengths, indicating that the lubrication theory is not valid here.
    Additional Material: 10 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 904-906 
    ISSN: 0935-6304
    Keywords: Linear complementary index ; Logarithmic complementary index ; Kovat's index ; Experimental alpha (αE) ; Ideal alpha (αI) ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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