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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 43 (1987), S. 197-201 
    ISSN: 1432-0649
    Keywords: 81.60 ; 82.65
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract X-ray photoemission spectroscopy (XPS) has been used to study the surface reaction of Zn3P2 single crystals. The spectra of crystals exposed to H2, O2, CO2, O2+H2O or CO2+H2O during a four week period were compared to the spectra of as-grown or in UHV scraped samples. For samples contaminated with the wet gases O2+H2O and CO2+H2O additional phosphorus core levels together with a shift of the zinc core levels were observed. For crystals exposed to atmosphere during several months no phosphorus could be detected on the gasgrown surface, whereas the stochiometry of Zn3P2 was maintained within the bulk. Crystals with scraped surfaces showed no moisture sensitivity. No surface contamination was also detected for Zn3P2 crystals deposited with up to 1000 L H2O or exposed to atmosphere during 30 min.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 73.40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The work function of 13 polycrystalline transition metal suicides was measured by photoemission in uhv. Their values are discussed in relationship to their Schottky barrier heights on n-Si. While there appears to be a weak correlation for a certain group of transition metal suicides, the values of the 5d-noble metal suicides including some of the lattice matched Ni suicides appear to be completely uncorrelated. Experimental values of work functions are compared to the values proposed previously by Freeouf.
    Type of Medium: Electronic Resource
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