ISSN:
1572-8862
Keywords:
luminescent copper complex
;
one-dimensional polymer
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The synthesis and structure of a one-dimensional polymer of formula [Cu3(dpphp)2(MeCN)1.7(CH2Cl2)0.3](ClO4) n is reported (where dpphp=6-diphenylphosphino-2-pyridonate). There are three distinct copper(I) sites within the polymer. Two of these sites are four-coordinate, bound to one P- and two O-atoms and a solvate molecule; the third site is bound only to two N-atoms. The Cu*Cu distances within the polymer are around 2.8 Å. The compound is luminescent in the solid-state.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1009077118047
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