Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
113 (2000), S. 561-566
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We present high resolution zero kinetic energy photoelectron spectra of the allyl radical through various intermediate vibronic states. The spectra yield an ionization energy of 65 762 cm−1, corresponding to 8.153 eV, as well as frequencies for a number of cationic vibrational states. The spectrum from the B 000 state shows activity in modes corresponding to out-of-plane motion of the terminal −CH2 groups. This confirms the nonplanar geometry of this state suggested previously, and thus provides additional insight into the vibronic couplings in the intermediate states. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.481831
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