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  • American Institute of Physics (AIP)  (4)
  • Wiley
  • 2000-2004  (4)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 3061-3063 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Epitaxial NiO hillocks on the {111} and {001} facets of truncated octahedral nanoparticles of Ni have been directly observed by high-resolution transmission electron microscopy. These nanometer hillocks form a rough shell enclosing the Ni nanoparticle. The epitaxial relationships of NiO on nanoparticles of Ni are the same as those of NiO on bulk Ni {111} and {001} surfaces. The formation of hillocks is related to the relaxation of the compressive stress in NiO arising from the very large lattice mismatch between NiO and Ni. The compressively stressed epitaxial NiO shell provides effective protection to the nanoparticles of Ni against further oxidation. © 2001 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 3072-3074 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A large magnetic entropy change has been observed in an intermetallic compound LaFe10.6Si2.4. The maximum −ΔSM(approximate)3.2 J/kg K was found at its Curie temperature, ∼242 K, upon a 2 T magnetic field change. Although the entropy change is slightly smaller than that of pure Gd metal, such Fe-rich compounds still appear to be very attractive candidates since (a) the raw materials are much cheaper than pure Gd metal; (b) the Curie temperature can be easily shifted by tuning the composition; (c) the materials are much more chemically stable than pure Gd metal. © 2000 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 3971-3973 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Remarkably oxidation-resistant nanoparticles of iron prepared at Tianjin University have been studied by electron diffraction and high-resolution transmission electron microscopy (HRTEM). HRTEM images clearly show the polyhedral epitaxy of γ-Fe2O3 layers on equivalent {100} facets of the {100} truncated {110} rhombic dodecahedral nanoparticles of iron. Oxide layers on {110} facets are formed by the lateral extension of the epitaxial {100} γ-Fe2O3 layers over adjacent {110} facets. The {110} oxide layers are bent and concave inward. The compressive γ-Fe2O3 layers which are about 4 nm thick give effective protection, according to the theory of Caberra–Mott, to the iron core from further oxidation. © 2000 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 1360-1362 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rare-earth intermetallic compounds (Tb1−xGdx)Al2, have been successfully fabricated and characterized. Large magnetic entropy change, ΔSM, was observed in these alloys. The maximum −ΔSM(=14.3 J/kg K) is achieved in the TbAl2 alloy at its Curie temperature, TC=105 K, with a 5 T magnetic field change. It is shown that the alloys are very soft magnetic alloys. The magnetic entropy change is thus completely reversible in the whole temperature range of 80–180 K. An interesting feature in (Tb1−xGdx)Al2 compounds is that the Curie temperature can be easily shifted by tuning the composition. These alloys, therefore, appear to be an attractive material candidate for realizing the active magnetic regenerator magnetic refrigerator consisting of eight stages, as suggested by K. A. Gschneidner, Jr. and V. K. Percharsky. [Rare Earth: Science, Technology, and Applications III, edited by R. G. Bautista, C. O. Bounds, T. W. Ellis, and B. T. Kilbourn (The Minerals, Metals and Materials Society, 1997), p. 209.] © 2000 American Institute of Physics.
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