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  • American Institute of Physics (AIP)  (2)
  • 2000-2004  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 785-788 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Throughout a complete electron spin resonance (ESR) and magnetization study of La0.5Ca0.5MnO3, we discuss about the nature of the complex phase-segregated state established in this compound below T∼210 K. Between TN≤T≤TC, the ESR spectra shows two lines characteristic of two different magnetic phases. From the resonance field (Hr) derived for each line, we argue that the incommensurate-charge-ordering phase (ICO) which coexists with ferromagnetic–metallic (FMM) clusters in this temperature interval, is mainly paramagnetic and not antiferromagnetic. The FMM/ICO ratio can be tuned with a relatively small field, which suggests that the internal energy associated with those phases is very similar. Below TN, there is an appreciable ferromagnetic (FM) contribution to the magnetization and the ESR spectra indicates the presence of FM clusters in an antiferromagnetic matrix (canted). Our results show that ESR could be a very useful tool to investigate the nature of the phase-separated state now believed to play a fundamental role in the physics of mixed valent manganites. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 112 (2000), S. 8495-8501 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report a computer simulation study of diffusion influenced reactions in a disorder medium constituting by immobile spherical obstacles when the concentration of reagents is smaller than the concentration of obstacles. We found that the compartmentalization of the embedding medium leads to a strong decrease of the rate of the first collision between reagents and a strong increase of the rate of recollision after a no-reactive encounter. The behavior of the full rate of reaction depends on the probability that a collision leads to reaction (value of the activation energy) and on the relationship between the decrease of the rate of collision and the increase of the rate of recollision. Thus, totally diffusion controlled reactions are always unfavored in these mediums, while partially diffusion controlled reactions with very high activation energy are more favored in mediums with a bigger degree of compartmentalization. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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