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Indirect Catalysis, Caused by Hydrogen Spillover Through the Gas Phase. Activation by Hydrogen Oxygen Reaction (2000)

Baumgarten, E. ; Meyer, G.

Springer

Reaction kinetics and catalysis letters 71 (2000), S. 335-341

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ISSN: 1588-2837

Keywords: Indirect catalysis ; spillover through the gas phase ; hydrogen spillover

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Earlier investigations revealed that glass surfaces may get catalytic properties by hydrogen spillover. Occasional activations by oxyhydrogen reaction, observed there, were executed systematically now and revealed high and stable degrees of activity of glass activated in this way. The activation energies for the hydrogenation of cyclohexene on the glass 'catalyst' are 18.1 kJ mol-1 (T 〉 367 K) 33.6 kJ mol-1 (T 〉 367 K)

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1023/A:1010339512972

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