ISSN:
1434-1948
Keywords:
Phthalocyanines
;
Nitrides
;
Oxo complexes
;
Rhenium
;
Molybdenum
;
Tungsten
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis of new nitrido(phthalocyaninato)molybdenum (1-4) and -tungsten complexes (5-7) starting from the corresponding phthalonitriles and MNCl3 (M = Mo, W) is reported. In addition, the reaction of (tBu4Pc)WN (6) with PPh3 leading, after several steps, to the diamagnetic compound (tBu4Pc)WO (7) is described. The reaction of (tBu4Pc)ReN (9) with PPh3 leads to [(tBu4Pc)ReO]2 (12), and of [(C5H11)8Pc]ReN (10) with PPh3 leads, under different conditions, to {[(C5H11)8Pc]ReO}2O (11).
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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