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  • Analytical Chemistry and Spectroscopy  (1)
  • Epoxidations  (1)
  • Wiley-Blackwell  (2)
  • 2000-2004  (1)
  • 1970-1974  (1)
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  • Wiley-Blackwell  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1387-1389 
    ISSN: 1434-193X
    Keywords: Natural products ; Epoxidations ; Asymmetric synthesis ; Fluorine ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---The synthesis of enantiomerically and diastereomerically pure (-)-(1R,2R,5R)- and (-)-(1R,2S,5R)-2-fluoro frontalin (7) starting from (+)-(1S)-menthyl-(R)-toluene-4-sulfinate, methylmagnesium bromide, methyl fluoroacetate, 4-pentenyl bromide and diazomethane is described. The absolute stereochemistry was unambiguously determined by X-ray analysis of (+)-(1S,2R,5S,RS)-5, an intermediate in the synthesis of the enantiomeric (+)-(1S,2R,5S)-2-fluoro frontalin (7).
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Various complexes (RnMO·BF3) of boron trifluoride with sulphoxides, aminoxides, phosphinoxides and arsinoxides have been prepared and investigated using proton, fluorine (at variable temperature) boron and phosphorus resonance. A comparison with similar adducts containing a co-ordinative O—B bond is presented.
    Notes: Les spectres de résonance magnétique nucléaire (1H, 11B, 19F et 31P) des complexes RnMO·BF3 formés par le trifluorure de bore et des sulfoxydes, aminoxydes, phosphinoxydes et arsinoxydes ont été obtenus. Les paramètres (déplacements et couplages) caractérisant ces spectres sont comparés à ceux de composés similaires renfermant également une liaison de coordination O·B.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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