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  • Polymer and Materials Science  (1,119)
  • AERODYNAMICS  (448)
  • Chemical Engineering  (325)
  • Aircraft Stability and Control
  • GENERAL
  • Inorganic Chemistry
  • Organic Chemistry
  • 2000-2004  (24)
  • 1975-1979  (1,750)
  • 1955-1959  (453)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Structure and properties of copolymers of vinylcyclohexane and α-methylvinylcyclohexane with acrylonitrile (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 2989-2997 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study has been made of the structure and properties of alternating equimolar and random copolymers of vinylcyclohexanne and α-methylvinylcyclohexane with acrylonitrile using infrared and 1H-NMR spectroscopy methods, as well as x-ray diffraction and differential thermal analyses. The spectral methods allowed an estimation of the composition and distribution of comonomer units in the copolymer macrochains. The thermal stability of alternating copolymers was found to be higher than that of polyacrylonitrile. Alternating and random copolymers are amorphous products with various dimensions of crystallites. Information on the molecular motion intensity and temperatures of structural transitions in copolymer macrochains was obtained by the spin-probe technique.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070231017
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  • 2
    Electronic Resource
    Electronic Resource
    Preparation of Mikanecic EsterThe systematic name of mikanecic acid is 4-vinyl-cyclohex-1-ene-1,4-dicarboxylic acid; it is used in the experimental Part. and its precursor, 1,3-butadiene-2-carboxylic ester (1975)
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 58 (1975), S. 2061-2073 
    Details
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Eine thermische (a) und eine reduktive (b) Methode zur Herstellung von Mikanez-Estern wird beschrieben. Bei der ersten gelang der Nachweis des monomeren Vorläufers, 1,3-Butadien-2-carboxylester. (a)trans/cis-Gemische von Methyl resp. Äthyl 2-Brom-1-methylcyclopropancarboxylat (14/15 resp. 16/17), mit Tri-n-butylzinnhydrid aus den entsprechenden 2,2-Dibrom-1-methylcyclopropancarboxylaten 12 resp. 13 hergestellt, wurden bei 480°/1,7 Torr pyrolysiert. Die bei -78° daraus abgefangenen Kondensate bestanden aus den 1,3-Butadien-2-carboxylaten 5 und 6, im Falle des Äthylesters 6 durch seine 1H-NMR.-Signale charakterisiert und als Addukt (19) mit 4-Phenyl-1,2,4-triazolin-3,5-dion (18) abgefangen (55%). Beim Erwärmen der Kondensate dimerisierten die Dienester 5 resp. 6, so dass sich Dimethyl resp. Diäthyl Mikanezat (9 resp. 10) isolieren liess (67 resp. 100%).(b)Behandlung von Methyl 2(E)-2-Methyl-2-butenoat (20) mit 2 Äquivalenten N-Bromsuccinimid gab (25%) Methyl 2(Z)-4-Brom-2-brommethyl-2-butenoat (21). (Mit 3 Äquivalenten entstand ein Stereomerengemisch 2(Z)- und 2(E)-4,4-Dibrom-2-brommethyl-2-butenoat (22 und 23)). Reduktion des Dibromesters 21 mit Zink in Tetrahydrofuran, Methanol oder Eisessig ergab (50%) Dimethyl Mikanezat (9). Von einer Iodolaktonisierung der aus 9 durch Verseifung hergestellten Mikanezsäure (8) erhielt man 4-Iodo-7-oxo-1-vinyl-6-oxabicyclo[3.2.1]octan-4endo-carbonsäure (24), dessen Bildungsleichtigkeit und IR.-Bande bei 1780 cm eine unabhängige Bestätigung dafür liefert, dass Mikanezsäure (8) durch Kopf-zu-Kopf-Diels-Alder-Dimerisierung von 1,3-Butadien-2-carbonsäure (4) entsteht.Aus Methyl (E)-2-Methyl-2-pentenoat (25) wurde auf gleiche Weise, d.h. über Dibromierung zu 27 und Reduktion mit Zink in Äther, Dimethyl 3,2′-Dimethylmikanezat (29) gewonnen. Die Multiplizität des 1H-NMR.-Signals von H—C(3) in 29 bestätigt, wiederum unabhängig, dass die Dimerisierung des Dienesters (in diesem Fall 28) in Kopf-zu-Kopf-Diels-Alder-Weise stattfindet.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/hlca.19750580721
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  • 3
    Electronic Resource
    Electronic Resource
    Methods of calculating the physical acation of flame retardants (1976)
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 1 (1976), S. 85-89 
    Details
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The chemical mechanisms for the action of flame retardants are often mentioned in the literature but the physical modes of action are seldom. Discussed. This article presents one way to quantify their efficiency. The technique is based on literature data for the physical and thermal properties of flams retardants for temperatures from 25°C up to 1000°C. The prolongation of the time to ignition by heat absorption by the retardant and the amount of inert gas evolved by the retardant are calculated at a given radiation for a material flame-proofed with a given amount of the flame retardant. The ability to form an insulating surface layer is considered but not quantified. It is assumed that a medium density wood fibre building boards is treated with 2 kg of flame retardant per m2. The flame retardants included are borates, boric acid, phosphates and silicates. The board is assumed to be irradiated with an intensity of 15 k W m-2. Under these conditions an untreated board ignites after 6-7 min. The time to ignition is prolonged by 1-5 min through heat absorption by the different retardants, and the amount of inert gases evolved may be as high as 2.6 m3 per m2 board. The formation of an insulating surface layer is more difficult to quantify. The results confirm the importance of the physical modes of action of flame retardants and the technique could form the basis for evaluating materials in simulated fire situations.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/fam.810010302
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  • 4
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    Aerodynamic characteristics in ground proximity (1976)
    In:  CASI
    Details
    Publication Date: 2016-06-07
    Description: Results from recent investigations in the Langley V/STOL tunnel of an externally blown flap and an upper surface blown flap configuration in ground proximity are presented. Comparisons of longitudinal aerodynamic characteristics indicate that in ground proximity, drag is reduced for both configurations, but changes in lift are configuration dependent. Steady state analyses of the landing approach indicate an increase in flight path angle for both configurations in ground proximity because of the drag reduction. Dynamic analyses with a fixed-base simulator indicate that the resultant flight path during landing approach is dependent on the initial flight path angle and the control technique used.
    Keywords: AERODYNAMICS
    Type: Powered-Lift Aerodyn. and Acoustics; p 145-158
    Format: application/pdf
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  • 5
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    Multidisciplinary Techniques and Novel Aircraft Control Systems (2000)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: The Aircraft Morphing Program at NASA Langley Research Center explores opportunities to improve airframe designs with smart technologies. Two elements of this basic research program are multidisciplinary design optimization (MDO) and advanced flow control. This paper describes examples where MDO techniques such as sensitivity analysis, automatic differentiation, and genetic algorithms contribute to the design of novel control systems. In the test case, the design and use of distributed shape-change devices to provide low-rate maneuvering capability for a tailless aircraft is considered. The ability of MDO to add value to control system development is illustrated using results from several years of research funded by the Aircraft Morphing Program.
    Keywords: Aircraft Stability and Control
    Type: AIAA Paper 2000-4848 , Multidisciplinary Analysis and Optimization; Sep 06, 2000 - Sep 08, 2000; Long Beach, CA; United States
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  • 6
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    Steady and unsteady transonic flow (1978)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: An investigation of the transonic flow over a circular arc airfoil was conducted to obtain basic information for turbulence modeling of shock-induced separated flows and to verify numerical computer codes which are being developed to simulate such flows. The investigation included the employment of a laser velocimeter to obtain data concerning the mean velocity, the shear stress, and the turbulent kinetic energy profiles in the flowfield downstream of the airfoil midchord where the flow features are more complex. Depending on the free-stream Mach number, the flowfield developed was either steady with shock-wave-induced separation extending from the foot of the shock wave to beyond the trailing edge or unsteady with a periodic motion also undergoing shock-induced separation. The experimental data were compared with the results of numerical simulations in which a computer code was employed that solved the time-dependent Reynolds' averaged compressible Navier-Stokes equations.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 78-160 , Aerospace Sciences Meeting; Jan 16, 1978 - Jan 18, 1978; Huntsville, AL
    Format: text
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  • 7
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    An experimental and computational investigation of the flow field about a transonic airfoil in supercritical flow with turbulent boundary-layer separation (1976)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: A combined experimental and computational research program for testing and guiding turbulence modeling within regions of separation induced by shock waves incident on turbulent boundary layers is described. Specifically, studies are made of the separated flow over the rear portion of an 18%-thick circular-arc airfoil at zero angle of attack in high Reynolds number supercritical flow. The measurements include distributions of surface static pressure and local skin friction. The instruments employed include high-frequency response pressure cells and a large array of surface hot-wire skin-friction gages. Computations at the experimental flow conditions are made using time-dependent solutions of ensemble-averaged Navier-Stokes equations, plus additional equations for the turbulence modeling.
    Keywords: AERODYNAMICS
    Type: ICAS PAPER 76-15 , Congress; Oct 03, 1976 - Oct 08, 1976; Ottawa; Canada
    Format: text
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  • 8
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    Multidisciplinary Techniques and Novel Aircraft Control Systems (2000)
    In:  CASI
    Details
    Publication Date: 2019-08-13
    Description: The Aircraft Morphing Program at NASA Langley Research Center explores opportunities to improve airframe designs with smart technologies. Two elements of this basic research program are multidisciplinary design optimization (MDO) and advanced flow control. This paper describes examples where MDO techniques such as sensitivity analysis, automatic differentiation, and genetic algorithms contribute to the design of novel control systems. In the test case, the design and use of distributed shapechange devices to provide low-rate maneuvering capability for a tailless aircraft is considered. The ability of MDO to add value to control system development is illustrated using results from several years of research funded by the Aircraft Morphing Program.
    Keywords: Aircraft Stability and Control
    Type: AIAA Paper 2000-4848 , Multidisciplinary Analysis and Optimization; Sep 06, 2000 - Sep 08, 2000; Long Beach, CA; United States
    Format: application/pdf
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  • 9
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    Aerodynamic drag reduction tests on a full-scale tractor-trailer combination and a representative box-shaped ground vehicle (1975)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Keywords: AERODYNAMICS
    Type: SAE PAPER 750703 , West Coast Meeting; Aug 11, 1975 - Aug 14, 1975; Seattle, WA
    Format: text
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  • 10
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    On turbulence modeling for unsteady transonic flows (1979)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: A detailed examination of the turbulent field in an unsteady transonic flow undergoing shock-induced separation is conducted. Ensemble-averaged mean and fluctuating velocities, obtained from conditionally sampled laser velocimeter data, are described and analyzed to assess the applicability of modeling concepts usually employed in steady-flow problems. Some comparisons with computations employing the Reynolds averaged Navier-Stokes equations with a mixing length turbulence model are then presented to illustrate the status of current predictive capabilities. The results appear to imply that turbulence models developed for steady flows apply and that the model need not reflect all the fine details of the turbulent structure but rather account in an approximate way for the production and destruction of the turbulence.
    Keywords: AERODYNAMICS
    Type: AIAA PAPER 79-0071 , American Institute of Aeronautics and Astronautics, Aerospace Sciences Meeting; Jan 15, 1979 - Jan 17, 1979; New Orleans, LA
    Format: text
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