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  • 1
    Publication Date: 2019-08-28
    Description: The electrical conductivity of high-purity, single-crystal alumina is determined parallel to and perpendicular to the c-axis. The mean conductivity of four samples of each orientation is a factor 3.3 higher parallel to the c-axis than perpendicular to it. The conductivity as a function of temperature is attributed to extrinsic electron conduction at temperatures from 400 to 900 C, and intrinsic semiconduction at temperatures from 900 to 1300 C. In the high-temperature regime, the slope on all eight specimens is 4.7 +/- 0.1 eV. Hence, the thermal bandgap at O K is 9.4 +/- 0.2 eV.
    Keywords: NONMETALLIC MATERIALS
    Type: American Ceramic Society, Journal (ISSN 0002-7820); 75; 10; p. 2790-2794.
    Format: text
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  • 2
    Publication Date: 2019-08-27
    Description: The fully guarded three-terminal technique was used to perform conductivity measurements on single-crystal alumina at temperatures of 400-1300 C. The conductivity was also determined as a function of time at various temperatures and applied fields. Further, the fractions of the current carried by Al and O ions (ionic transference numbers) were determined from long-term transference experiments in the temperature range 1100-1300 C. A mathematical model of the conduction mechanism is proposed, and model predictions are compared with experimental results.
    Keywords: NONMETALLIC MATERIALS
    Type: American Ceramic Society, Journal (ISSN 0002-7820); 75; 295-304
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