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  • 2000-2004  (87)
  • 1995-1999  (94)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 90 (2001), S. 2737-2743 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The optical and electronic properties of TiCxNy(x+y∼1,0〈y〈1) thin films have been investigated by spectroscopic ellipsometry in the 1.5–4.5 eV energy range and by valence band x-ray photoemission spectroscopy as a function of the composition. The dielectric functions measured in the energy range of intraband transitions are analyzed in terms of a Drude-like approximation. Both the free plasma energy and the damping constant are observed to depend on the nitrogen content of the samples, suggesting a certain tunability of the optical and electronic properties of these films. Analysis of the valence band reveals that the C 2p band shifts toward higher binding energies upon an increase of the nitrogen content, in good agreement with the shift observed in the minimum of the optical reflectivity associated with the threshold of the interband transitions. The enhancement of the metallic character of the films as the nitrogen content increases is also evidenced by x-ray photoemission spectroscopy as a continuous intensity growth of the conduction band at the Fermi level. © 2001 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    European journal of soil science 47 (1996), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The analysis of free lipids in 12 soils from three representative types of Mediterranean forest has been carried out in an attempt to describe diagnostic molecules reflecting differences between the ecosystems and the intensity of the soil organic matter turnover. The study centred on the analysis by gas chromatography–mass spectrometry of the soil compounds extracted with petroleum ether from soils in central Spain, developed under monospecific formations of stone pine (Pinus pined), evergreen oak (Quercus rotundifolia) and Spanish juniper (Juniperus thurifera), the lipid extracts from their leaves also being analysed as reference material.The comparison between the distribution patterns of alkanes and fatty acids in plant lipids and the corresponding soil lipids was used to assess the extent to which the former accumulate in soil or are substituted by other biogenic or diagenetic homologues. In general, the alkane patterns showed the greatest variation in soils under oak, and the differences between lipid patterns in plant and soil were greatest in the juniper forests. As indicators of the vegetation type, the soil fatty acids had little value.Up to 60 major cyclic compounds were identified, including mainly di- and sesquiterpenes, in addition to some monoterpenes and nonterpenic naphthalenes and decalins. Of these major constituents, 33 compounds were found in soil but were not present in plant extracts, and 18 compounds were identified in plants but were not in the soils. The results suggest an arrangement of the soil samples based on the composition of the signature lipid assemblages.
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 69 (1996), S. 764-766 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Carbon nitride thin films obtained by dual ion beam sputtering have been investigated by electron energy-loss spectroscopy (EELS), transmission electron microscopy, and Fourier transform infrared spectroscopy. The nitrogen content in the films depends on deposition conditions. A maximum value of N/C=0.8 has been achieved. A new peak at 286.7 eV energy loss in the C K-edge EELS spectra has been assigned to C=N bonds with C in the sp2 hybridization state. In addition, experimental evidences are presented of the formation of β-C3N4 crystallites embedded in a layer of a polymer like CNx amorphous phase. An evaluation of the experimental parameters that lead to the highest N content in the films is also included. © 1996 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 99 (1995), S. 4655-4660 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Plant breeding 123 (2004), S. 0 
    ISSN: 1439-0523
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: To enlarge the number of microsatellite loci of Phaseolus vulgaris (L.) (common bean), a set of primer pairs has been obtained from public databases, to amplify DNA regions including simple sequence repeats (SSR), and they have been assayed in several P. vulgaris genotypes. Publically available DNA sequence data of P. vulgaris were searched for SSR motifs. Twenty sequences containing microsatellites were identified and primer pairs were designed to amplify those microsatellites. Primers were evaluated for their ability to detect polymorphisms within a set of P. vulgaris accessions, local landraces and hybrids and in addition, two accessions of the closely related species P. coccineus. Eighteen polymorphic SSR loci were identified. Polymorphisms were found at both levels of accessions and Phaseolus species.
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    European journal of soil science 49 (1998), S. 0 
    ISSN: 1365-2389
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Frequent applications of chicken manure to a volcanic-ash soil resulted in an increased crop yield several years after the applications ceased. Improved nutrient cycling through the soil organic matter (SOM) was thought be the cause of this. An area that for several years had been under either unimproved fallow or continuous bean-maize intercropping (with chicken manure application) was planted with maize intercropped with the legume Arachis pintoi. Soil samples were fractionated into several sizes of aggregates and incubated for 6 weeks in intact form and after crushing the aggregates. Between 1.2 and 3.1% of the C in any aggregate size class exited in easily decomposable (i.e. not physically or chemically protected) form. Less than 0.8% of the macroaggregate C was physically protected by the aggregate structure. More than 97% of the C in any aggregate size class can be considered resistant. The large-or small-macroaggregate-protected SOM (i.e. in aggregates 〉 2000 μm and 250–2000 μm, respectively). once made available, was more easily decomposed than the unprotected SOM. The large SOM content (45.8–57.3 g C kg−1) but yet limited mineralizability indicates that mechanisms other than soil macroaggregation are important for protecting SOM in this soil. Binding of organic molecules onto allophane minerals is likely to be such a mechanism.The larger yield and nutrient uptake by the maize in the former bean-maize plots compared with the former fallow plots could not be explained by differences in SOM decomposition. We think that the frequent application of chicken manure to the former bean-maize plots increased the available phosphorus in these strongly P-sorbing soils by increasing the cycling of organic-P or by blocking some of the P-reactive sites. This, however, needs to be further investigated.
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  • 7
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 982-988 
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The crystal structure of Pb(O3PC6H5) has been solved from X-ray powder diffraction data. Crystal data: triclinic, a = 13.6907 (5), b = 9.3327 (4), c = 7.0432 Å, α = 106.188 (3), β = 94.927, γ = 96.977°, V = 851.04 (8) Å3, space group P{\bar 1} and Z = 4. Initial positional parameters for Pb atoms were obtained from direct methods using 556 structure factors in the 2θ range 9–63°. All remaining non-H atoms were located from successive difference-Fourier maps. The final agreement factors were Rwp = 0.055, Rp = 0.042 and RF = 0.017. There are 22 atoms in the asymmetric part of the unit cell and 66 positional parameters have been refined with the help of soft constraints. The lead coordination environment is irregular due to a marked inert pair effect. The three-dimensional structure of this organic inorganic compound is layered with inorganic layers built up from CPO3 tetrahedra and PbO6 units. 31P MAS and CP-MAS (cross-polarization magic angle spinning) NMR studies have been carried out to confirm the triclinic symmetry with two independent structural units. In optimum conditions two 31P resonance signals are observed, indicating that there are two crystallographically independent P atoms with closely similar environments. The thermal behavior of this material has been studied and the thermal decomposition products identified.
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 376 (1995), S. 473-473 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] FISHER ETAL. REPLY - The comments by Davidson et al. about the rainforests and the wooded communities of the cerrados are not relevant to our paper1, which was about the 35 million hectares (MHa) of treeless grasslands in Colombia and Venezuela and the 50 MHa (24%) of the cerrados of ...
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  • 9
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 376 (1995), S. 731-732 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SIR - Beach deposits of the Arenisca de Aren Formation1 (southern Pyrenees, Maastrichtian, Upper Cretaceous) are rich in dinosaur eggs and bones, distributed over an area of about 15 km2 along the northern flank of the Tremp syncline (Fig. 1). At one locality (Bastus, Lleida) ...
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  • 10
    ISSN: 1572-9729
    Keywords: biodegradation ; biofiltration ; hydrogen sulfide ; malodorous compounds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A laboratory scale bioreactor has been designed and set up in order to degrade hydrogen sulfide from an air stream. The reactor is a vertical column of 7 litre capacity and 1 meter in height. It is divided into three modules and each module is filled with pellets of agricultural residues as packing bed material. The gas stream fed into the reactor through the upper inlet consists of a mixture of hydrogen sulfide and humidified air. The hydrogen sulfide content in the inlet gas stream was increased in stages until the degradation efficiency was below 90%. The parameters to be controlled in order to reach continuous and stable operation were temperature, moisture content and the percentage of the compound to be degraded at the inlet and outlet gas streams (removal or elimination efficiency). When the H2S mass loading rate was between 10 and 40 g m-3h-1, the removal efficiency was greater than 90%. The support material had a good physical performance throughout operation time, which is evidence that this material is suitable for biofiltration purposes.
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