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  • Electrophilic additions  (1)
  • aerobic  (1)
  • Wiley-Blackwell  (2)
  • American Institute of Physics (AIP)
  • Amsterdam : Elsevier
  • Geological Society of America (GSA)
  • 2000-2004
  • 1995-1999  (2)
Collection
Publisher
  • Wiley-Blackwell  (2)
  • American Institute of Physics (AIP)
  • Amsterdam : Elsevier
  • Geological Society of America (GSA)
Years
  • 2000-2004
  • 1995-1999  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 49 (1996), S. 601-610 
    ISSN: 0006-3592
    Keywords: aerobic ; anaerobic ; biomass separation ; bioreactor ; bubbleless ; oxygen mass transfer ; extraction of organic pollutants ; membrane ; wastewaters ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Combining membrane technology with biological reactors for the treatment of municipal and industrial wastewaters has led to the development of three generic membrane processes within bioreactors: for separation and recycle of solids; for bubbleless aeration of the bioreactor; and for extraction of priority organic pollutants from hostile industrial wastewaters. Commercial aerobic and anaerobic membrane separation bioreactors already provide a small footprint alternative to conventional biological treatment methods, producing a high-quality effluent at high organic loading rates. Both the bubbleless aeration and extractive membrane bioreactors are in the development stages. The former uses gas-permeable membranes to improve the mass transfer of oxygen to the bioreactor by providing bubbleless oxygen. By using a silicone membrane process, extractive membrane bioreactors transfer organic pollutants from chemically hostile wastewaters to a nutrient medium for subsequent biodegradation. All three membrane bioreactor (MBR) processes are comparatively and critically reviewed. © 1996 John Wiley & Sons, Inc.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-193X
    Keywords: Strained molecules ; 1-Vinyltricyclo[4.1.0.02,7]heptanes ; Electrophilic additions ; Rearrangements ; Cyclic ketene imine ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of 1-vinyltricyclo[4.1.0.02,7]heptanes 4 has been obtained by Ni0-catalyzed cross-coupling reactions of the corresponding Grignard reagent with vinyl halides or via reaction of 4b with various electrophiles. Selected model compounds 4 were treated with tetracyanoethylene (TCNE), N-phenyl-1,2,4-triazoline-3,5-dione (PTAD), and dimethyl acetylenedicarboxylate (DMAD). Product studies revealed that TCNE and PTAD attacked the CC double bond forming a zwitterion, which in most cases underwent several carbenium ion rearrangements until internal bond formation of the ionic centers took place. The main reaction path of DMAD and 4 led via attack at the bicyclo[1.1.0]butane bridgehead to a biradical of type 38, which after H abstraction and CC bond formation gave rise to the tricyclic system 37.
    Type of Medium: Electronic Resource
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