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  • Articles  (125)
  • Springer  (59)
  • Wiley  (52)
  • Copernicus  (14)
  • Molecular Diversity Preservation International
  • 2000-2004  (59)
  • 1995-1999  (66)
  • 1935-1939
  • Geosciences  (125)
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  • Articles  (125)
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Year
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    GPS solutions 3 (1999), S. 32-41 
    ISSN: 1521-1886
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: The hybridization of GPS with GLONASS has formed a first stage in GNSS development. We examine the performance of the hybrid system in the position domain for both code and carrier phase cases. Several major differences exist between GPS and GLONASS; most significant is GLONASS's signal frequency diversity, which can lead to measurement bias, particularly so when a pair of receivers are operating at different temperatures. Unless signal frequency diversity is addressed either on-receiver or at the data processing stage, positioning errors can occur at the centimeter level. We outline the difficulties of combining observations from the two systems and discuss how these may be overcome. © 1999 John Wiley & Sons, Inc.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 29 (1999), S. 809-812 
    ISSN: 1572-8854
    Keywords: tungsten(II) ; dibromo ; carbonyl ; diphenylcyclohexylphosphine ; but-2-yne ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract [WBr2(Co)(PPh2Cy)2(η2-MeC2Me)]·CH2Cl2 (Cy = cyclohexyl) crystallizes in the monoclinic space group, P21/n, with a = 10.606(12), b = 23.11(3), c = 18.19(2) Å, β = 106.070(10) Dcalc = 1.610g cm−3 for Z = 4. The tungsten coordination geometry can best be considered as a distorted octahedron, with the but-2-yne ligand occupying one coordination site, which has a trans-Br(2) group. The equatorial plane is made up of trans-PPh2Cy groups, with the bromo and carbonyl ligands occupying the other two sites.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 29 (1999), S. 907-911 
    ISSN: 1572-8854
    Keywords: tungsten(II) ; Iodo ; carbonyl ; cis-bis(diphenylphosphino)ethene ; but-2-yne ; cationic ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The complex [WI(CO)(cis-dppen)(η2-MeC2Me)2]I·CH2Cl2(1) is prepared as a by-product from the reaction of equimolar quantities of [WI2(CO)(NCMe)(η2-MeC2Me)2] and cisdppen {dppen = bis(diphenylphosphino)ethene}. Complex 1, [WI(CO)(cis-dppen)(η2-MeC2Me)2]I·CH2Cl2 crystallizes in the triclinic space group $${\text{P}}\bar 1$$ with a = 11.189(13), b = 12.331(14), c = 15.395(17) Å, α = 83.61(1), β = 86.06(1), γ = 64.48(1)°, U = 1904 Å3, and Z = 2. The metal environment in the cation can best be considered as a distorted octahedron with the two but-2-yne groups taking up individual sites trans to phosphorus atoms of the dppen ligand. The coordination sphere is completed by mutually trans-carbonyl and iodide groups.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 28 (1998), S. 839-841 
    ISSN: 1572-8854
    Keywords: π-allyl ; carbonyl ; nitrile ; chloro ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound crystallizes in the monoclinic spacegroup P21/m with a = 6.796(9), b = 12.145(14), c = 7.749(8)Å, β = 101.86(1)°, and Z = 2. The crystal structure consists of molecules of [MoCl(CO)2(NCMe)2(η3-C3H4Me-2)] with crystallographically imposed Cs symmetry and has a pseudo-octahedral geometry, with the π-allyl group trans- to the chloro group and the two cis-carbonyl and acetonitrile groups occupying the equatorial plane.
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 26 (1996), S. 661-665 
    ISSN: 1572-8854
    Keywords: N,N′-bis(2-hydroxyphenyl)butanediamide ; crystal structure ; hydrolysis product
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of N,N′-bis(2-hydroxyphenyl)butanediamide has been determined. The molecule consists of two 2-hydroxyphenyl moieties which are attached (at the 2 position) to the two nitrogens of the butanediamide. The compound C16H16N2O4 crystallizes in the monoclinic space group P21/c witha=5.576(1),b=4.8853(6),c=25.397(6) Å and β=90.58(1)°.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 28 (1998), S. 639-643 
    ISSN: 1572-8854
    Keywords: Tungsten(II) ; diiodo ; carbonyl ; trimethylphosphite ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract [WI2(CO)3{P(OMe)3}2]crystallizes in the orthorhombic space group Pca21, with a = 26.924(5), b = 10.726(2), c = 14.136(3) Å, and Z = 8. There are two molecules in the asymmetric unit, the metal atoms in each case being seven-coordinate with a capped fac-(CO)3 octahedral geometry. The molecular dimensions in the two molecules are nearly identical. The W–P distance to the capping atom 2.397 Å (average) is significantly shorter than the other W–P distance, 2.525 Å (average).
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 30 (2000), S. 181-184 
    ISSN: 1572-8854
    Keywords: tungsten(II) ; diiodo ; dicarbonyl ; triisopropylphosphite ; 3-hexyne ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract [WI2(CO)2{P(OiPr)3}(η2-EtC2Et)] crystallizes in the monoclinic space group P21/n, with a = 11.101(12), b = 16.272(18), c = 14.892(17) Å, β = 93.27(1), Z = 4. The geometry can be considered to be pseudo-octahedral, with the 3-hexyne ligand occupying one site, with two iodo-groups, and the P(OiPr)3 ligand completing the equational plane of ligands, with two trans-carbonyl groups occupying the axial sites.
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  • 8
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract An under-recognized and economically important class of intrusion-related gold deposits, which occur within magmatic provinces best known for tungsten and/or tin mineralization, is described with reference to seven major deposits (Fort Knox, Mokrsko, Salave, Vasilkovskoe, Timbarra, Kidston and Kori Kollo). These gold deposits contain a metal suite that includes some combination of bismuth, tungsten, arsenic, tin, molybdenum, tellurium and antimony, and contrasts with that found in the more widely-developed gold-rich porphyry copper and related deposits. The gold deposits associated with tungsten and/or tin provinces are located in cratonic margins, in a landward or back-arc position relative to continental margin arcs (where recognized), or within continental collisional settings. The deposits are related genetically to felsic domes, stocks or plutons of intermediate oxidation state, both magnetite- and ilmenite-series magmas are represented. The intrusion-hosted gold deposits are most commonly of sheeted vein/veinlet type, although greisen-like, disseminated and breccia deposits are also described. Gold may also be concentrated more distally (1–3 km) with respect to the intrusions, where deposits may be of skarn, disseminated replacement or vein types. K-feldspar, albite and/or sericitic alteration assemblages, commonly including carbonate, accompany the gold mineralization. In sheeted vein deposits, alteration is normally restricted to narrow envelopes around veins, whereas more pervasive alteration occurs in greisen-like, disseminated and shallow (〈3 km) deposits. The gold mineralization is commonly present with low total sulphide contents (〈3%), mainly pyrite and lesser arsenopyrite. In several deposits, bismuth minerals are closely associated with gold, and bismuth-gold and tellurium-gold correlations exist. Most deposits contain tungsten, tin, molybdenum and antimony, although generally these do not correlate with gold; tungsten and molybdenum concentrations may increase with depth or may occur in separate zones. Base metals generally are present in minor amounts (e.g. 〈100 ppm Cu). The distinct spatial association with felsic intrusions, combined with the consistent metal signature, suggests a magmatic-hydrothermal origin. Fluid inclusions studies indicate the presence of high-salinity fluids in some deposits, and low-salinity and carbonic fluids in most deposits, similar to the composition of fluids in intrusion-related tungsten deposits. Variations in mineralization style largely reflect depth of formation and location relative to the intrusive centre. Several deposits in this class contain 〉100 tonnes (3 million oz) of gold, thereby highlighting the gold potential of intrusion-related deposits beyond the more traditionally explored gold and copper provinces in arc terranes.
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  • 9
    ISSN: 1432-0789
    Keywords: Key words Methane oxidation ; Nitrogen ; Fertilizer ; Soils ; Isotopic dilution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  The short-term effects of N addition on CH4 oxidation were studied in two soils. Both sites are unfertilized, one has been under long-term arable rotation, the other is a grassland that has been cut for hay for the past 125 years. The sites showed clear differences in their capacity to oxidise CH4, the arable soil oxidised CH4 at a rate of 0.013 μg CH4 kg–1 h–1 and the grassland soil approximately an order of magnitude quicker. In both sites the addition of (NH4)2SO4 caused an immediate reduction in the rate of atmospheric CH4 oxidation approximately in inverse proportion to the amount of NH4 + added. The addition of KNO3 caused no change in the rate of CH4 oxidation in the arable soil, but in the grassland soil after 9 days the rate of CH4 oxidation had decreased from 0.22 μg CH4 kg–1 h–1 to 0.13 μg CH4 kg–1 h–1 in soil treated with the equivalent of 192 kg N ha–1. A 15N isotopic dilution technique was used to investigate the role of nitrifiers in regulating CH4 oxidation. The arable soil showed a low rate of gross N mineralisation (0.67 mg N kg–1 day–1), but a relatively high proportion of the mineralised N was nitrified. The grassland soil had a high rate of gross N mineralisation (18.28 mg N kg–1 day–1), but negligible nitrification activity. It is hypothesised that since there was virtually no nitrification in the grassland soil then CH4 oxidation at this site must be methanotroph mediated.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 27 (1998), S. 279-283 
    ISSN: 1432-0789
    Keywords: Key words Peats ; Methane ; Nitrogen ; Land use ; Agriculture
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  Rates of methane uptake were measured in incubation studies with intact cores from adjacent fenland peats that have been under arable management and woodland management for at least the past 30 years. On two separate occasions the woodland peat showed greater rates of uptake than the arable peat. These rates ranged from 23.1 to 223.3 μg CH4 m–2 day–1 for the woodland peat and from 29.6 to 157.6 μg CH4 m–2 day–1 for the arable peat. When the peats were artificially flooded there was a decrease in the rate of methane oxidation, but neither site showed any net efflux of methane. 15N isotopic dilution was used to characterise nitrogen cycling within the two peats. Both showed similar rates of gross nitrogen mineralisation (3.58 mg N kg–1 day–1, arable peat; 3.54 N kg–1 day–1, woodland peat) and ammonium consumption (4.19 arable peat and 4.70 mg N kg–1 day–1 woodland peat). There were significant differences in their inorganic ammonium and nitrate pool sizes, and the rate of gross nitrification was significantly higher in the woodland peat (4.90 mg N kg–1 day–1) compared to the arable peat (1.90 mg N kg–1 day–1). These results are discussed in the light of high atmospheric nitrogen deposition.
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