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  • 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring  (2)
  • ANT-XIX/2; AWI; Caete_mangr; Carbon, organic, dissolved; CTD, Seabird; CTD-R; Date/Time of event; DEPTH, water; Equatorial West Atlantic; Event label; High temperature catalytic oxidation; Latitude of event; Longitude of event; Percentage; Polarstern; Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; PS61; PS61/024-1; PS61/027-1; PS61/031-1; Salinity; Sample type; SPP1158; Station label; Water sample; Weddell Sea; WS  (1)
  • 2005-2009  (3)
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Keywords
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Year
  • 1
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    Unknown
    (Table 1) Salinity and dissolved organic carbon concentration of marine water (ANT-XIX/2) and mangrove porewater (Brazil) (2005)
    PANGAEA
    In:  Supplement to: Koch, Boris P; Witt, Matthias; Engbrodt, Ralph; Dittmar, Thorsten; Kattner, Gerhard (2005): Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. Geochimica et Cosmochimica Acta, 69(13), 3299-3308, https://doi.org/10.1016/j.gca.2005.02.027
    Details
    Publication Date: 2023-10-28
    Description: The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.
    Keywords: ANT-XIX/2; AWI; Caete_mangr; Carbon, organic, dissolved; CTD, Seabird; CTD-R; Date/Time of event; DEPTH, water; Equatorial West Atlantic; Event label; High temperature catalytic oxidation; Latitude of event; Longitude of event; Percentage; Polarstern; Priority Programme 1158 Antarctic Research with Comparable Investigations in Arctic Sea Ice Areas; PS61; PS61/024-1; PS61/027-1; PS61/031-1; Salinity; Sample type; SPP1158; Station label; Water sample; Weddell Sea; WS
    Type: Dataset
    Format: text/tab-separated-values, 35 data points
    Location Call Number Expected Availability
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    DATA PANGAEA
  • 2
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    Unknown
    Real-time simultaneous detection of volcanic Hg and SO2 at La Fossa Crater Vulcano (Aeolian Islands, Sicily) (2007)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Measuring Hg/SO2 ratios in volcanic emissions is essential for better apportioning the volcanic contribution to the global Hg atmospheric cycle. Here, we report the first real-time simultaneous measurement Hg and SO2 in a volcanic plume, based on Lumex and MultiGAS techniques, respectively. We demonstrate that the use of these novel techniques allows the measurements of Hg/SO2 ratios with a far better time resolution than possible with more conventional methods. The Hg/SO2 ratios in the plume of F0 fumarole on La Fossa Crater, Vulcano Island spanned an order of magnitude over a 30 minute monitoring period, but was on average in qualitative agreement with the Hg/SO2 ratio directly measured in the fumarole (mean plume and fumarole ratios being 1.09 x 10-6 and 2.9 x 10-6, respectively). The factor 2 difference between plume and fumarole compositions provides evidence for fast Hg chemical processing the plume.
    Description: Published
    Description: L21307
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: partially_open
    Keywords: Mercury ; Fumarolic condensates ; Volcanic emissions ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Unknown
    Mercury and halogen emissions from Masaya and Telica volcanoes, Nicaragua (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: We report measurements of Hg, SO2, and halogens (HCl, HBr, HI) in volcanic gases from Masaya volcano, Nicaragua, and gaseous SO2 and halogens from Telica volcano, Nicaragua. Mercury measurements were made with a Lumex 915+ portable mercury vapor analyzer and gold traps, while halogens, CO2 and S species were monitored with a portable multi gas sensor and filter packs. Lumex Hg concentrations in the plume were consistently above background and ranged up to 350 ng/m3. Hg/SO2 mass ratios measured with the real-time instruments ranged from 1.1*10-7 to 3.5*10-5 (mean 2*10-5). Total gaseous mercury TGM)concentrations measured by gold trap ranged from 100 to 225 ng/m3. Reactive gaseous mercury accounted for 1% of TGM, while particulate mercury was 5% of the TGM. Field measurements of Masaya’s SO2 flux, combined with the Hg/SO2 ratio, indicate a Hg flux from Masaya of 7.2 Mg/a-1. At Masaya’s low temperature fumaroles, Hg/CO2 mass ratios were consistently around 2*10-8, lower than observed in the main vent (Hg/CO2 10-7). Low-temperature fumarole Hg fluxes from Masaya are insignificant (150 g a-1). Ratios of S, C and halogen species were also measured at Masaya and Telica volcanoes. CO2/SO2 ratios at Masaya ranged from 2.8 to 3.9, comparable to previously published values. At Masaya molar Br/SO2 was 3*10-4 and I/SO2 was 2*10-5, suggesting fluxes of 0.2–0.5 Mg HBr d-1 and 0.02–0.05 Mg HI d-1. At Telica the Br/SO2 ratio was also 3*10-4 and the I/SO2 ratio was 5.8*10-5, with corresponding fluxes of 0.2 Mg HBr d-1 and 0.06 Mg HI d-1. Gases at both volcanoes are enriched in I relative to Br and Cl, compared to gases from volcanoes elsewhere.
    Description: This work was funded by NERC grant NE/ C511180/1/.
    Description: Published
    Description: B06203
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Mercury ; Halogen ; Volcanic emissions ; Masaya volcano ; Telica volcano ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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