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  • De Gruyter  (2)
  • American Chemical Society (ACS)
  • 2005-2009  (2)
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  • 1
    Publication Date: 2006-01-01
    Description: A Note on the Chemical Composition of Nuffieldite Solid-Solution From Sulphide Mineralizations in the Western Carpathians, SlovakiaThe chemistry of the rare sulphosalt nuffieldite from three localities in Slovakia is examined. Nuffieldite is a part of a complex association of Bi sulphosalts accompanying tetrahedrite mineralization in some sulphide deposits in the Western Carpathians. Cu + Pb = (Bi, Sb) + vac. substitution in nuffieldite and the general formula Cu1+xPb2Bi2(PbxSbyBi1-x-y)S7where 0 〈 x 〈 0.34; and 0.32 〈 y 〈 0.45 are confirmed. Decreasing Sb content with increasing copper content indicates a predominant substitution of Bi by Sb in nuffieldite.
    Print ISSN: 1899-8291
    Electronic ISSN: 1899-8526
    Topics: Geosciences
    Published by De Gruyter
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  • 2
    Publication Date: 2007-01-01
    Description: Mineralogy and Geochemistry of the Nižná Boca Sb-Au Hydrothermal Ore Deposit (Western Carpathians, Slovakia)Samples from hydrothermal Sb-Au mineralization in the area SE of Nižná Boca village in the N&iAzke Tatry Mountains were investigated using a variety of geochemical and mineralogical methods. Ore minerals typically occur in N-S striking quartz-carbonate veins hosted by an I-type biotite granodiorite to tonalite of Variscan Age (the Ďumbier Type). Paragenetic associations in the deposit are comparable to other mineralizations of the same type in the Ďumbierske Nízke Tatry Mountains. A quartz-arsenopyrite, pyrite stage of mineralization is the oldest with a calculated temperature of formation of about 445°C. It is followed by a quartz-carbonate-stibnite, zinkenite stage and, in turn, a quartz-carbonate-sphalerite-galena, boulangerite-gold stage. The gold typically contains between 9-18 wt.% Ag regardless of mineral association. No evidence for further generations of gold was found although it is possible that some gold was remobilized from the structure of the auriferous arsenopyrite. The Au and Ag content of the bulk ore ranges from 0.53 g.t-1to 20.2 g.t-1and from 0.9 g.t-1to 31.2 g.t-1, respectively. A tetrahedrite-chalcopyrite stage is followed by a barite-hematite stage - the youngest assemblage in the deposit. Fluid inclusions from the first mineralization stage are usually less than 3 μm in size and contain less than 3.6 wt.% CO2; salinity, density and homogenization temperature range from 2.7-16.3 wt.% NaCl(eq), 0.85-1.03 g.cm-1and 128-280°C, respectively.
    Print ISSN: 1899-8291
    Electronic ISSN: 1899-8526
    Topics: Geosciences
    Published by De Gruyter
    Location Call Number Expected Availability
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