ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
A method has been developed to quantitatively measure the surface plasticizer levels present on test plaques made from a plasticized PVC compound. The plaque fabrication conditions have been chosen so that the plaque closely models an extruded flexible PVC profile. The analysis method utilized sorption of the surface plasticizer on fumed silica, followed by methanol extraction and liquid chromatographic identification and quantitation of the plasticizer. Typical results are presented for a model compound plasticized with either di-2-ethylhexyl phthalate (DOP) or a mixture containing predominantly linear C7, C9, and C11 dialkyl phthalates (DHNUP). The effect of compound work level, as measured by Banbury drop temperature and final processing temperature, has also been studied. These results show that, for the model compound studied, the average surface level of DHNUP is always greater than that of DOP. The DOP levels are essentially independent of compound work level. The DHNUP levels generally increase with increasing mold temperatures. Finally, this data has been correlated with a study of the lifetime of a Neoprene-based adhesive bond to DOP-and DHNUP-plasticized flexible PVC in a 100°C oven. These studies clearly show that a one-to-one substitution of DOP for DHNUP will increase the time to adhesive bond failure by a factor of at least 10 with this particular adhesive system and model compound.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1984.070290136
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