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  • 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology  (3)
  • American Geophysical Union  (2)
  • MINERALOGICAL SOC AMER  (1)
  • American Chemical Society
  • Blackwell Publishing Ltd
  • 2005-2009  (3)
  • 1985-1989
  • 1945-1949
  • 1
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    Shallow slab fluid release across and along the Mariana arc-basin system: Insights from geochemistry of serpentinized peridotites from the Mariana fore arc (2007)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Shallow slab devolatilization is not only witnessed through fluid expulsion at accretionary prisms, but is also evidenced by active serpentinite seamounts in the shallow fore-arc region of the Mariana convergent margin. Ocean Drilling Program (ODP) Leg 195 recovered serpentinized peridotites that present a unique opportunity to study the products of shallow level exchanges between the upper mantle and slab-derived fluids. Similar to samples recovered during ODP Leg 125, the protoliths of these fore-arc serpentinized peridotites are mantle harzburgites that have suffered large volume melt extraction (up to 25%) prior to interactions with fluids released from the downgoing Pacific Plate. Samples recovered from both ODP legs 125 and 195 show U-shaped rare earth element (REE) patterns and very low REE abundances (0.001–0.1 chondrites). Relative to global depleted mantle values these rocks typically have 1–2 orders of magnitude lower high field strength elements, REE, Th, and U contents. Interestingly, all fore-arc rocks thus far examined show extreme enrichments of fluid mobile elements (FME: B, As, Cs, Sb, Li). Because the elemental and B, Li, and Sr isotope systematics in these fore-arc serpentinites point to nonseawater-related processes, studies of elemental excesses and anomalous isotopic signatures allow assessment of how much of the subducted inventory is lost during the initial subduction process between 10 and 40 km. On the basis of similar but substantial enrichments of FME in the Mariana fore-arc samples recovered at ODP legs 125 and 195, we report large slab inventory depletions of B ( 75%), Cs ( 25%), As ( 15%), Li ( 15%), and Sb ( 8%); surprisingly low (generally less than 2%) depletions of Rb, Ba, Pb, U, Sr; and no depletions in REE and the high field strength elements (HFSE). Such slab-metasomatized mantle wedge materials may be dragged to depths of arc magma generation, as proposed by Tatsumi (1986) and Straub and Layne (2002) and thus represent an unexplored class of mantle material, different in its origins, physical properties and geochemical fingerprint from mantle rocks traditionally used in modeling a wide range of subduction zone processes.
    Description: Published
    Description: B09205
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Shallow slab fluid ; Mariana arc-basin ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Oxidation state of iron in hydrous phono-tephritic melts (2008)
    MINERALOGICAL SOC AMER
    Details
    Publication Date: 2017-04-04
    Description: The oxidation state of iron in hydrous ultrapotassic (phono-tephritic) melts coexisting with mixed H2O-CO2 fluids was experimentally studied at 1200 and 1250{degree sign}C and pressures from 50 to 500 MPa. The oxygen fugacity (fO2) varied from NNO-2.9 to NNO+2.6 in logfO2, relative to the Ni-NiO oxygen buffer (NNO), as imposed by external redox conditions in experimental vessels and internal variations in water activity from 0.05 to 1 inside the capsules. The iron redox state of the quenched melts was determined by colorimetric wet-chemical analysis. This analytical method was optimized to measure the Fe2+/ΣFe ratio of mg-sized samples within ±0.03 (2σ). The accuracy and precision was tested with international reference materials and with standards analyzed by other methods. The Fe2+/ΣFe ratio of the experimental glasses covered a range of 0.41 to 0.85. A small negative effect of dissolved water on Fe2+/ΣFe at given fO2 was found, consistent with the thermodynamic model of Moretti (2005). No effect of pressure and temperature on the redox state of iron was resolvable in the investigated P-T range. Compared to hydrous ferrobasaltic melts that were studied previously under similar conditions, systematically lower Fe2+/ΣFe ratios were found for the phono-tephritic melts, in particular at low oxygen fugacities. This effect is attributed to the much higher K2O contents of the phono-tephrite (7.5 compared to 0.3 wt%), but the difference in ΣFeO (7.8 wt% in the phono-tephrite and 12.9 wt% in the ferrobasalt) may have an influence as well. Comparison of the experimentally obtained relationship between logfO2 and Fe3+/Fe2+ for the studied hydrous ultrapotassic melts with commonly used empirical and thermodynamic models suggest that these models can be successfully applied to phono-tephritc melts, although such compositions were not implemented in the model calibrations. Furthermore, the new data can be used to improve the models with respect to the effects of compositional variables, such as H2O or K2O, on the redox state of iron in silicate melts.
    Description: Published
    Description: 1493-1504
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: open
    Keywords: iron oxidation state, ferrous iron determination, oxygen fugacity, phono-tephrite, ultrapotassic hydrous silicate melt, Alban Hills, water activity ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Geochemistry of serpentinized peridotites from the Mariana Forearc Conical Seamount, ODP Leg 125: Implications for the elemental recycling at subduction zones (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20–30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These serpentinites have U-shaped rare earth element (REE) patterns, resembling those of boninites. U, Th, and the high field strength elements (HFSE) are highly depleted and vary in concentration by up to 2 orders of magnitude. The low U contents and positive Eu anomalies indicate that fluids from the subducting Pacific slab were probably reducing in nature. On the basis of substantial enrichments of fluid-mobile elements in serpentinized peridotites, we calculated very large slab inventory depletions of B (79%), Cs (32%), Li (18%), As (17%), and Sb (12%). Such highly enriched serpentinized peridotites dragged down to depths of arc magma generation may represent an unexplored reservoir that could help balance the input-output deficit of these elements as observed by Plank and Langmuir (1993, 1998) and others. Surprisingly, many species thought to be mobile in fluids, such as U, Ba, Rb, and to a lesser extent Sr and Pb, are not enriched in the rocks relative to the depleted mantle peridotites, and we estimate that only 1–2% of these elements leave the subducting slabs at depths of 10 to 40 km. Enrichments of these elements in volcanic front and behind-the-front arc lavas point to changes in slab fluid composition at greater depths.
    Description: Published
    Description: 1-24
    Description: partially_open
    Keywords: Serpentinite ; Ocean Drilling Program ; Forearc ; Mantle ; Marianas ; Subduction ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Format: 462 bytes
    Format: 2257702 bytes
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    Format: application/pdf
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