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Reliable detection of runaway reaction precursors in liquid phase reactions (1988)

Spence, John P. ; Noronha, John A.

New York, NY : Wiley-Blackwell

Plant/Operations Progress 7 (1988), S. 231-235

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ISSN: 0278-4513

Keywords: Chemistry ; Chemical Engineering

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology

Notes: A theoretical approach for early on-line detection of runaway reactions based on temperature derivative estimates is described and shown to be feasible in the laboratory. On-line process measurements were processed to yield smoothed derivative estimates and confidence intervals. These estimates were then compared to characteristics of potentially hazardous situations. If a match was sensed, preventive or emergency measures could be initiated. The problem lies in the tradeoff between earliest possible detection and false alarm avoidance.

Additional Material: 12 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/prsb.720070407

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