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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 320 (1978), S. 177-182 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of Hepten-(3) and Allyl Cyanide with CoO/MoO3/Al2O3 and WO3/SiO2 CatalystsThe influence of the β nitrilgroup in allylcyanid was determined by comparison of the activity of hepten-(3) and allylcyanid.Hepten-(3) give with CoO/MoO3/Al2O3 and WO3/SiO2 catalysts mainly methathesis which is never observed with allylcyanid. This product gives only isomerisation in crotonitril and finally dimerisation - trimerisation of this last.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Physical Organic Chemistry 4 (1991), S. 141-148 
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The influence of solvation on the Z - E isomerization process of three representative molecules of simple push-pull ethylenes [H2N(H)C1=C2(H)R = NO2, COH and CN] derived from aminoethylene was investigated by means of RHF-SCF ab initio calculations at the 3-21 + G level. Solute-solvent interactions were modelled by a cavity model. The shape of the cavity is based on electronic isodensity surfaces. By using an ellipsoidal cavity very close to the isodensity surface, the perturbation due to the solvent takes an analytical form which is incorporated into the Hartree-Fock equations and leads to efficient quantum chemical computations. The polarization of the solutes under the influence of the solvent is noticeable and was analysed in detail. Similarly, the barriers to internal rotations are substantially modified by the solvent: the barrier around the C=C double bond is appreciably decreased in the thermal mechanism whereas its lowering is less important in the anionic mechanism; in contrast, the barrier around the C-1—N bond is slightly increased. The variation of the barriers with the nature of the acceptor group is fairly well reproduced by the computations. The electronic structure of the push-pull ethylene molecules and the modifications of this structure under the influence of the solvent are analysed in detail.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1991 (1991), S. 1099-1100 
    ISSN: 0170-2041
    Keywords: Aminocyclopropanecarboxylic acids ; Amino acid, dehydro ; Diazomethane, addition of ; Oxazolone ; Cyclopropanecarboxylic acid ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new method is reported for the synthesis of rac-allocoronamic acid hydrochloride (5), from the readily available oxazolone 1 via the 1,3-dehydro amino acid derivative 2, diazomethane addition, photolysis and acid hydrolysis.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 320 (1978), S. 329-334 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of Pentene-(2), Hexene-(3) and Allyl Cyanide with WCl6-Catalysts
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0170-2041
    Keywords: Toxic oil syndrome ; Aniline ; Fatty acids, synthesis of ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The synthesis of anilides 2 from several saturated and unsaturated fatty acids 1 required for toxicological studies related to the Spanish Toxic Oil Syndrome is reported. In addition, a simple procedure for the microscale determination of the position of a carbon-carbon double bond of a fatty acid residue is described. This procedure involves epoxidation of the sample with 3,3-dimethyldioxirane followed by oxidative cleavage with periodic acid to yield the corresponding carbonyl derivatives which are easily identifiable by GC-MS analysis. Finally, the synthesis of anilino derivatives 5-8 formally derived from glycerol is also reported. For this purpose, a common precursor, i.e. 3-(phenylamino)propane-1,2-diol (4) is prepared, and convenient procedures for its chemoselective acylation at either the hydroxy or the amino group have been developed.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 7 (1993), S. 421-424 
    ISSN: 0268-2605
    Keywords: N, N′ -Dimethyl-2, 2′-bisimidazole ; diorganotin(IV) dihalides ; complexes ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Adducts of N, N′ -dimethyl-2, 2′-bisimidazole (DMBIm) with diethyl- and dibutyl-tin(IV) dihalides (Cl, Br) have been isolated and characterized. IR data for [SnR2X2(DMBIm)] compounds are in keeping with a six-coordinate tin atom with DMBIm acting as a bidentate ligand, whereas in [(SnR2X2)2(DMBIm)] the tin is five-coordinate and DMBIm acts as a bridging ligand. Measurements of conductivity in acetonitrile show the adducts to behave as non-ionogens in this solvent. NMR data show them to undergo dissociation in CDCl3.
    Additional Material: 3 Tab.
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  • 7
    Publication Date: 2021-05-19
    Description: Ichthyoplankton was sampled in 9 exploratory cruises in the sea off Buenos Aires province (Argentina), Uruguay and Brazil, during the spawning peak of the anchovy in spring-early summer and mid-autumn. The most abundant speices in the ichthyoplankton was Engraulis anchoita, representing 88. of the eggs and 76. of the larvae collected in all the cruises. These percentages vary boath regionally and seasonally; as regards eggs, the lowest percentage (10. ) was found in January. The distribution of anchovy eggs and larvae, covered almost entirely the surveyed area, with the exception of hte region influenced by the River Plate estuary. Minimum salinity tolerance for the species eggs was 23.5o/oo. The eastern limit of the distribution of anchovy eggs, extends in spring-early summer to the 200 m isobath in the northern part of the study area, whereas in the south rarely extends beyond the 50 m isobath. Anchovy larvae showed a wider distribution, penetrating in November and December in the brackish waters of the Samborombón bay, extending over more off-shore waters in January. As the spawning season progressed a southwards movement of intensive reproduction nuclei was observed. The average daily egg production during spring-early summer was estimated at 260 anchovy eggs/m2/day; in autumn, a ten-fold reduction of this production was observed. On the basis of the seasonal egg production for spring-early summer, calculated at 3.5238 E15 eggs and the larvae census carried out in mid-January a 98.2. mortality during the imbryonic and larval stages of the anchovy could be assumed. The spawning biomass of the anchovy during this period was calculated at 2,514,970 t. Preliminary results on the vertical distribution of anchovy eggs and larvae show that their distribution is generally restricted to the upper 50 m water layer, with higher concentrations at 10 to 25 m depths.
    Description: Publisher permission
    Description: Published
    Description: Clupeiformes, Engraulidae, evaluación de efectivos, huevos de peces, distribución vertical, poblaciones desovantes
    Keywords: Vertical distribution ; Fish eggs ; Spawning populations
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 8
    Publication Date: 2021-05-19
    Description: A bongo sampler fifted with nets of two different mesh sizes, 330 and 505 u. was used to collected 137 ichthyoplankton samples in the coastal areas off Buenos Aires Province in October, 1981. The efficiency of the two meshes for catching anchovy eggs and larvae and total ichthyoplankton was examined. The statistical analysis of the samples shows that there are no significant differences between the numbers of anchovy and total eggs collected by the different meshes. As regards anchovy and total larvae the finer mesh showed as significantly higher catching efficiency. The results of this partial estimate do not suggest that a major revision of the total assessment of the complete stock is necessary.
    Description: Publisher permission
    Description: Published
    Description: Clupeiformes, Engraulidae, Engraulis anchoita, evaluación de efectivos, huevos de peces
    Keywords: Stock assessment ; Stock assessment ; Fish eggs
    Repository Name: AquaDocs
    Type: Journal Contribution
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  • 9
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    Unknown
    Mar del Plata: Instituto Nacional de Investigación y Desarrollo Pesquero (INIDEP)
    Publication Date: 2021-05-19
    Description: Fecundity and spawning frequency were estimated in the northern(off Buenos Aires Province)and southern (patagonian)argentine anchovy Engraulis anchoita populations in 1993, during the peak of the spawning season. Relative fecundity, expressed as eggs per ovary-free weight was 574±21 (CI 95. ) and 605±49 (CI 95. ) in the northern and southern populations. The difference was not statistically significant between stocks (P0.13). Relative fecundity was higher in anchovies larger than 130 mm. The mean batch fecundity for the northern and southern populations was 13675±856 (CI 95. ) and21677±2.753 (CI 95. ) respectively. Batch fecundity (F)expressed as alinear function of ovary-free weight (W)was: F=-1310+649 * W(northern), F=-5935+786 * W (southern). The daily spawning incidence was estimated in 12,6. ±3.3 (CI 95. ) for the northern population and 15,5. ±8.5 (CI 95. ) for the southern. The females spawned about every 7.9 and 6.5 days respectively. A low incidence of alpha and bethastages atresia in ovaries was founded in both populations (less than 2. yolked oocytes affected). Relative egg production for anchovies ages 1-2 and ages 2-3 were estimated to contribute 74. and 64. to egg production in the northern and southern stocks during the peak of the spawning season. It was observed a direct relationship between collections with male-dominated schools and females with hidrated and recent post-ovulattory follicles.
    Description: Publisher permission
    Description: Published
    Description: Engraulidae, Engraulis anchoita, anchoíta, ovarios, fecundidad, estaciones de desove, huevos de peces, poblaciones desovantes
    Keywords: Ovaries ; Fecundity ; Ovaries ; Fecundity ; Spawning populations ; Fish eggs ; Spawning seasons
    Repository Name: AquaDocs
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  • 10
    Publication Date: 2021-05-19
    Description: Ichthyoplankton samples were collected during an exploratory cruise carried out by the RV Dr.Holmberg during the spring spawning peak of 1981 in the sea-shelf off Buenos Aires province (Argentina). The cruise was designed to carry out population studies in a restricted area of intense reproduction activity, in order to gather information on the time-space patterns of distribution of the eggs and larvae of the species.
    Description: Publisher permission
    Description: Published
    Description: Clupeiformes, Engraulidae, larvas de peces, huevos de peces, curvas de crecimiento, condiciones controladas, mortalidad
    Keywords: Fish larvae ; Mortality ; Fish larvae ; Mortality ; Growth curves ; Controlled conditions ; Fish eggs
    Repository Name: AquaDocs
    Type: Journal Contribution
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