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  • Articles  (3)
  • pH  (3)
  • Springer  (3)
  • Oxford University Press
  • 2005-2009
  • 1990-1994  (2)
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  • 1975-1979
  • 1950-1954
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  • Articles  (3)
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  • Springer  (3)
  • Oxford University Press
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  • 2005-2009
  • 1990-1994  (2)
  • 1980-1984  (1)
  • 1975-1979
  • 1950-1954
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 12 (1994), S. 103-154 
    ISSN: 1573-0417
    Keywords: acidification ; alkalization ; pH ; alkalinity ; diatoms ; sediment chemistry ; New England ; catchment effects ; land use ; logging ; acidic deposition ; air pollutants
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Studies of sediment cores from 12 acidic lakes in granitic, forested and uninhabited catchments in northern New England, U.S.A. produced diatom-inferred pH (IpH) 5.2 to 5.8 and alkalinity (Ialk) −12 to 31 µeq l−1, with slowly declining values at some lakes, for one to four centuries prior to logging. Increases of IpH (Δ0.05 to 0.60) and Ialk (Δ5 to 40 µeq l−1) correlate with logging in the catchments in the early-1800s to early-1900s. Recovery to pre-logging IpH and Ialk correlates with forest succession toward conifers, and is completed in the late-1800s to mid-1900s. Beginning at 1915–1920 (4 lakes), 1930–1950 (4 lakes) and 1965–1970 (4 lakes), IpH and Ialk start decreasing below pre-logging values due to atmospheric acidic deposition, leading to respective total decreases of 0.10 to 0.45 (X=0.25) and 5 to 25 µeq l−1 (X=15). Inputs of anthropogenic Pb, Zn, V, polycyclic aromatic hydrocarbons, and soot from the atmosphere are first detectable in early- to late-1800s sediment, and Cu in late-1800s sediment, increase rapidly in the late-1800s to mid-1900s, and level off or decrease since the 1960s — partly due to emission controls. Decreasing Ca, Mn, and possibly Zn relative to other metals and normalized to organic content, and increasing flux of Fe to the lakes, indicate soil and water acidification after 1900.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 126 (1990), S. 237-246 
    ISSN: 1573-5036
    Keywords: Al3+ ; Ca2+ ; Mg2+ ; NH4 + ; NO3 − ; SO4 2− ; Al toxicity ; forest dieback ; Fagus sylvatica ; Nothofagus ; pH ; Picea abies ; soil solution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Concentrations of ions were measured in soil solutions from beech (Nothofagus) forests in remote areas of New Zealand and in solutions from beech (Fagus sylvatica) and Norway spruce (Picea abies) forests in North-East Bavaria, West Germany, to compare the chemistry of soil solutions which are unaffected by acid deposition (New Zealand) with those that are affected (West Germany). In New Zealand, soil solution SO4 2− concentrations ranged between 〈2 and 58 μmol L−1, and NO3 − concentrations ranged between 〈1 and 3 μmol L−1. In West Germany, SO4 2− concentrations ranged between 80 and 700 μmol L−1, and NO3 − concentrations at three of six sites ranged between 39 and 3750 μmol L−1, but was not detected at the remaining three sites. At all sites in New Zealand, and at sites where the soil base status was moderately high in West Germany, pH levels increased, and total Al (Alt) and inorganic monomeric Al (Ali) levels decreased rapidly with increasing soil depth. In contrast, at sites on soils of low base status in West Germany, pH levels increased only slightly, and Al levels did not decline with increasing soil depth. Under a high-elevation Norway spruce stand showing severe Mg deficiency and dieback symptoms in West Germany, soil solution Mg2+ levels ranged between 20 and 60 μmol L−, and were only half those under a healthy stand. Alt and Ali levels were substantially higher the healthy stand than under the unhealthy stand, indicating that Al toxicity was not the main cause of spruce decline.
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  • 3
    ISSN: 1573-5117
    Keywords: pH ; alkalinity ; indicators
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A series of laboratory and field studies were conducted to evaluate the reliability of colorimetric pH indicators in dilute, acidic surface waters in New England. Laboratory studies consisted of comparing colorimetric and electrometric pH results in synthetic solutions with a range of ionic strength and buffering capacity. Field studies involved simultaneous colorimetric and electrometric pH determinations in 52 New England lakes with differing water chemistry. Colorimetric indicators deviated from electrometric pH results at low alkalinities and near the end of their operating range. They agreed with electrometric values, within 0.2 unit, at alkalinities of 20 µeq 1-1 and greater, or near the center of their operating range. Changing ionic strength without changing buffering capacity did not affect results. When indicators were selected that bracketed sample pH, colorimetric determinations of pH in New England lakes agreed well with electrometric determinations.
    Type of Medium: Electronic Resource
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