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  • Springer  (27)
  • Elsevier  (24)
  • American Chemical Society  (20)
  • Macmillan Magazines Ltd.  (2)
  • 2005-2009  (30)
  • 1995-1999  (30)
  • 1970-1974  (13)
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Year
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 38 (1973), S. 4192-4196 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1520-4804
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillan Magazines Ltd.
    Nature 394 (1998), S. 415-416 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] ...As a result of the reduction of their nuclear arsenals following the end of the Cold War, the United States and Russia have each declared almost half of the plutonium they produced for weapons. The United States has started a $2 billion programme to dispose of 50 tonnes of this excess plutonium, ...
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillan Magazines Ltd.
    Nature 392 (1998), S. 347-348 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] We propose a new method for computing the ratio of the isotopes carbon-14 to carbon-12 in deep water from the past, and for testing the results derived from the normal method of age difference between benthic and planktic foraminifera in deep-sea sediments. Our method involves measuring ...
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  • 6
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Nanosize poly(methyl methacrylate) (PMMA) microlatexes with high PMMA/surfactant ratio have been successfully prepared by a modified microemulsion polymerization, i.e., continuous and slow addition of monomer (MMA) to the polymerizing MMA microemulsion with mild stirring. Number-average diameters of 33–46 nm with narrow polydispersity (Dv/Dn= 1.1) and polymer content of 6–24 wt% were achieved using low levels of surfactant (dodecyltrimethylammonium bromide, DTAB) — less than 1 wt% of the reaction mixture. Particle diameter depended on polymerization temperature, MMA content, and concentrations of initiator and surfactant. Larger particles wereformed when temperature was too high, initiator concentration was too high, or surfactant concentration was too low.
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  • 7
    ISSN: 1437-3262
    Keywords: Manganese nodules ; Thorium dating ; Uranium isotopes ; Peru basin ; TIMS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution230Thexcess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (230Th), 0.43–1.40 ppm (232Th), 0.09–0.49 ppb (234U) and 1.66–8.24 ppm (238U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the230Thexcess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant230Thexcess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 22 (1972), S. 276-296 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The application of the fast-Fourier-transform (FFT) algorithm to calculating one-dimensional and bi-dimensional (temporal and spatial), power and cross-power (coherence and phase) spectra is examined for solar photospheric fluctuations. Alternative methods for smoothing raw spectra, direct averaging (employing various weights) and indirect truncation of the correlation function, are compared, and indirect smoothing is compared with spectra calculated by mean-lagged-product (MLP) methods. Besides providing the raw spectrum, FFT techniques easily allow computing a series of spectra with varying amounts of smoothing. From these spectra a range of satisfactory compromise between resolution and stability can be determined which helps in the interpretation of spectral trends, and in identifying more clearly the existence and significance of spectral features. For bi-dimensional spectra presented as contour plots, this range of satisfactory smoothing can be restricted, particularly when spectral trends must be represented by small-scale contours. Equivalent spectra (i.e. comparable equivalent degrees of freedom) computed or smoothed by different methods have minor, but not negligible, differences. Examination of these differences favors computing of FFT spectra smoothed by averaging for photospheric fluctuations.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 25 (1972), S. 44-70 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Fluctuations measured from a time sequence of high-resolution, high-dispersion Sacramento Peak Observatory spectrograms and previously analyzed by computing one-dimensional temporal and spatial spectra (Edmonds et al., 1965), are re-analyzed using bi-dimensional (temporal and spatial) power, coherence and phase spectra computed by fast-Fourier-transform techniques. The fluctuations measured are radial velocity for the FeI 5049.83, CrI 5051.91 and CI 5052.16 spectral lines, continuum brightness, and equivalent width and central intensity of the CI line. The bidimensional spectra, particularly those of coherence and phase, allow isolating different components of the fluctuations to a degree not possible in the one-dimensional analyses. Six components of the fluctuations have been isolated (Section 5 and Figure 11); the first three components are well-known but the nature of the remaining three is less certain: (1) Supergranulation which exists only in radial-velocity fluctuations and increases in power with depth. (2) Five-minute oscillations that dominate long-wavelength radial-velocity fluctuations, which may contribute of the order of one percent to continuum brightness and equivalent width fluctuations, and are waves which can propagate across the Sun's surface and possibly travel upwards at less than 70 km s−1. (3) A long-period, convective component which extends over all but very long wavelengths, is characterized by strong correlation between the radial velocity and photometric fluctuations, and involves low power levels for the radial velocity fluctuations. Seemingly, the radial velocity fluctuations lead those of continuum brightness by roughly 20 s. (4) Low and moderate wavenumber fluctuations which seemingly extend over frequencies ≲ 6 × 10−3 Hz and are characterized by low power levels for all types of fluctuations. It is difficult to deny the physical reality and distinctness from other components of these fluctuations, but whether they constitute a single component is uncertain. The radial velocity fluctuations seem to have the same phase relations with respect to each other as the five-minute oscillations. The continuum brightness fluctuations seem to lag the equivalent width fluctuations by roughly 17 s, lead the central intensity fluctuations by roughly 10 s, and lead the radial velocity fluctuations by roughly 15 to 20 s. (5) Possible line-formation (as distinct from continuum formation) brightness fluctuations at the center of the CI 5052.16 line, which seemingly are of low frequency and long wavelength and are poorly correlated with continuum brightness and radial velocity fluctuations. (6) A low-correlation, primarily photometric component restricted to long-periods and to wavelengths only slightly less than those of super-granulation. Its existence is suggested by a phase anomaly indicating that the radial velocity fluctuations lead the photometric fluctuations by roughly 4 min.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 38 (1974), S. 33-41 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The fractional convective flux πF c (x c /πF) is computed for the effective level x c = logτ c = 0.125, using bi-dimensional co-spectra for relative continuum-brightness fluctuations ΔI and radial velocity fluctuations ΔV measured for the C i 5052.16 spectral line. A more uncertain flux for x Fe ≈ - 0.9 is obtained for the Fe i 5049.83 line. Since the results (Figure 1) incorporate current uncertainties in RMS ΔI , RMS ΔV and RMS ΔT (x), where ΔT are photospheric temperature fluctuations, they must be considered qualitative until these uncertainties are appreciably reduced. The requirement that the fractional convective flux 〈 1, places restrictions on these uncertainties which suggest that current RMS ΔT (x)'s are too large. The results confirm the importance of overshoot at the top of the solar hydrogen convection zone and suggest a non-negligible fractional convective flux throughout the lower photosphere. Qualitatively, they do not agree with the predictions of the generally-used, local, mixing-length theory or those of Parsons' (1969) modified mixing-length theory. However, qualitative agreement with the predictions of the non-local, generalized mixing-length theory of Spiegel (1963) and with the non-local theory of Ulrich (1970) cannot be considered as observational confirmation of these theories.
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