ALBERT

Description: In high latitudes, recent research has demonstrated that both thermo-erosion and temperature dependence influence sediment release into fluvial systems. An analysis of proglacial suspended sediment concentration (SSC) dynamics is presented for three glacierized basins: cold-based Austre Brøggerbreen (Svalbard), polythermal Midre Lovénbreen (Svalbard) and polythermal Glacier B28 (Bylot Island). The temporal variation in processes dominating SSC patterns is assessed using stepwise multivariate regression following the subdivision of the time series. Partitioning of the time series is achieved through principal components and change point analyses. The regression models use discharge and surrogate predictor variables to model SSC, while improvements are made by using air temperature and radiation terms as independent variables. Comparisons are drawn between two sets of models with contrasting subseasonal division. By interpretation of the regression model characteristics, temporal changes in physical processes are implied over the course of the time periods. Numerical analyses suggest there is a trend for changes between fluvial, glacial and periglacial factors forcing responses in SSC. Therefore, it is conjectured that glaciofluvial sediment transfer at high latitudes is influenced by periglacial processes and conditions. This has implications for the predictions of fluvial sediment loads in a changing environment, and the use of sedimentary records for environmental reconstruction.

Description: The interaction between thrust and strike slip fault systems is well detailed in Pakistan where the Chaman transform zone connects the Makran and Himalayan convergence zones and contains an internal convergence zone in the Zhob district. The transform zone contains numerous strike slip faults of which the Chaman fault proper is the westernmost. We can demonstrate at least 200 km of left lateral displacement along the Chaman fault alone. In the Zhob belt N-S shortening by folds and a major thrust fault amounts to several dozen kilometres. The 400 km wide Makran convergence zone is now being shortened by E-W oriented folds, thrust faults, and reverse faults. As these faults in the Makran zone approach the transform zone, their traces bend to the N and motion on each of them becomes oblique, combining reverse and left lateral slip. They merge continuously with the strike slip faults of the Chaman transform zone. The Makran thrust system and the Chaman transform zone first became active in the late Oligocene or early Miocene. Later (Pliocene?), a component of left lateral shear occurred across the entire Makran Zone in association with the opening of the newly identified Haman-i-Mashkel fault trough S of the Chagai Hills and W of the Ras Koh. The total displacement and displacement rate across the Chaman transform zone varies in response to the rates of convergence in the plates E and W of the zone.

Description: The widespread occurrence of organic-carbon-rich strata (‘black shales’) in certain portions of Jurassic, Cretaceous and Cenozoic sequences has been well-documented from Deep Sea Drilling Project sites in the Atlantic and Pacific Oceans and from sequences, now exposed on land, originally deposited in the Tethyan ocean. These ancient black shales usually have been explained by analogy with examples of modern deep-sea sediments in which organic matter locally is preserved by (1) increasing the supply of organic matter, (2) increasing the rate of sedimentation, and/or (3) decreasing the oxygen content of the bottom water. However, detailed examination of many black shales reveals characteristics that cannot be explained by simple local models, including: their approximate coincidence in time globally; their occurrence in a variety of different environments, including open oxygenated oceans, restricted basins, deep and shallow water; their interbedding with organic-carbonpoor strata which often dominate a so-called black shale sequence; their deposition by pelagic, hemipelagic, turbiditic and other processes; and the variations in type and amount of organic matter that occur even within the same sequence. A more complex model for the origin of black shales therefore appears most appropriate, in which the cyclic preservation of organic matter depends on the interplay of the three main variables, namely supply of organic matter, sedimentation rate, and deep-water oxygenation, each of which varies independently to some extent. The variation and relative importance of these parameters in individual basins and widespread black shale deposition in general are linked globally and temporally by changes in global sea-level, climate and related changes in oceanic circulation. An important and often overlooked factor for the supply of organic matter to deep-basin sediments is the frequency and magnitude of redepositional processes. The interplay of these variables is discussed in relation to the middle Cretaceous and Cenozoic organic-carbon-rich strata, in particular, which show marked differences in the relative importance of the different variables.

Description: The crustal structure of the Mesozoic deep Galicia margin and adjacent ocean-continent boundary (OCB) was investigated by seismic reflection (including pre-stack depth migration and attenuation of seismic waves with time). The seismic data were calibrated using numerous geological samples recovered by drilling and/or by diving with submersible. The N-S trending margin and OCB are divided in two distinct segments by NE-SW synrift transverse faults locally reactivated and inverted by Cenozoic tectonics. The transverse faulting and OCB segmentation result from crustal stretching probably in a NE-SW direction during the rifting stage of the margin in early Cretaceous times. The Cenozoic tectonics are related to Iberia-Eurasia convergence in Palaeogene times (Pyrenean event). In both segments of the deep margin, the seismic crust is made of four horizontal layers: (1) two sedimentary layers corresponding to post- and syn-rift sequences, where velocity ranges from 1.9 to 3.5 km s−1, and where the Q factor is low, the two sedimentary layers being separated by a strong reflector marking the break-up unconformity; (2) a faulted layer, where velocity ranges from 4.0 to 5.2 km s−1, and where the Q factor is high. This layer corresponds to the margin tilted blocks, where continental basement and lithified pre-rift sediments were sampled; (3) the lower seismic crust, where the velocity (7 km s−1 and more) and the Q factor are the highest. This layer, probably made of partly serpentinized peridotite, is roofed by a strong S-S’ seismic reflector, and resting on a scattering, poorly reflective Moho. A composite model, based both on analogue modelling of lithosphere stretching and on available structural data, accounts for the present structure of the margin and OCB. Stretching and thinning of the lithosphere are accommodated by boudinage of the brittle levels (upper crust and uppermost mantle) and by simple shear in the ductile levels (lower crust and upper lithospheric mantle). Two main conjugate shear zones may account for the observations and seismic data: one (SZ1), located in the lower ductile continental crust, is synthetic to the tilting sense of the margin crustal blocks; another (SZ2), located in the ductile mantle, accounts for the deformation of mantle terranes and their final unroofing and exposure at the continental rift axis (now the OCB). The S-S′ reflector is interpreted as the seismic signature of the tectonic contact between crustal terranes and mantle rocks partly transformed into serpentinite by syn-rift hydrothermal activity. It is probably related to both shear zones SZ1 and SZ2. The seismic Moho is lower within the lithosphere, at the fresh-serpentinized peridotite boundary.

Description: Six new labdane diterpenoids, leopersin C (1), 15-epi-leopersin C (2), leopersin D (3), leopersin E (4), leopersin F (5), and 7-epi-leopersin F (6) were isolated from the aerial parts of Leonurus persicus. Their structures were elucidated by extensive use of 1D and 2D homonuclear and heteronuclear shift-correlated 1H−13C-NMR spectroscopic methods. Leopersin C (1) and 15-epi-leopersin C (2) were obtained as a C-15 epimeric mixture, and their structures were elucidated on this basis.

Description: An automated method for on-site monitoring of uranium(VI) in raffinate streams originating from nuclear fuel reprocessing plants is described. An in-line stripping procedure (based on liquid/liquid extraction) was developed to extract U(VI) from this stream, a solvent mixture of 20% tributyl phosphate and nitric acid in kerosene, into an aqueous sodium sulfate solution, Degradation products in the solvent mixture, especially dibutyl phosphate, give rise to very strong complexes and are responsible for moderate but constant U(VI) recoveries (similar to 50%), Optimal conditions for in-line stripping comprise a mixing ratio of extractant (0.5 M sodium sulfate in water)/solvent mixture of similar to 3 and a pumping rate of similar to 0.4 mL min(-1) of the solvent mixture. The determination of U(VI) was by on-line cathodic stripping voltammmetry (CSV), preceded by adsorptive collection of the U(VL) as an oxine complex onto a hanging mercury drop electrode, Quantities of 1-2 mL of the aqueous extract were pumped into the voltammmetric cell and diluted (1/5 to 1/10) with a background electrolyte containing 0.1 M PIPES buffer, 2 x 10(-4) M oxine, 10(-4) M EDTA, and 0.2 M hydrazine hydrate (pH 9.0), The CSV peak for U(VI) was obtained at -0.68 V with a detection limit of 20 nM in the raffinate stream using an adsorption time of 120 s, Both the inline stripping procedure and the on-line measurement were fully automated, with a relative standard deviation in the measurements of 〈 5%.

Description: Cretaceous and Tertiary coal beds in the western United States typically contain subvertical opening-mode fractures (cleat). However, closely spaced normal faults abruptly substitute for opening-mode fractures in coal beneath some sandstone lenses having blunt terminations. Differential forced-fold compaction of coal beds around and beneath lens-shaped sandstone bodies accounts for such shifts in fracture style. Finite element modelling of coal deformation shows that shear stress is augmented in coal layers below abruptly tapering edges of sandstones lenses, favouring fault development, whereas under gradually tapering lenses shear stresses are not sufficiently enhanced to cause shifts in fracture style. Upper Cretaceous Mesaverde Group coal beds in southwest Wyoming have significant variations in fracture style over distances of a few to tens of metres. Because these faults have little or no porosity, the coal that contains them is likely to have low permeability compared to coal having typical (generally porous) opening-mode fractures. Thus, shifting fracture style may affect regional and local gas and water flow in coal beds.