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  • Articles  (4)
  • Chemistry  (4)
  • 2005-2009
  • 1995-1999  (2)
  • 1990-1994  (2)
  • Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics  (4)
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  • Articles  (4)
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  • 2005-2009
  • 1995-1999  (2)
  • 1990-1994  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 847-856 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work reports on the photodegradation of low-density polyethylene films formulated with titanium (IV) oxide actylacetonate (TAc) and titanium dioxide pigment in different proportions; no previous reports on the photoactivity of this acetylacotonate have been found. Samples of blow-extruded films were submitted to accelerated UV aging with fluorescent lamps and the polymer degradation measured. The changes in carbonyl groups, molecular weight, and film elongation at break are discussed. The results show that TAc can promote photooxidation and accelerate the film degradation. The retention percent of elongation at break (EB) is apparently proportional to the carbonyl index irrespective of the formulation but has different relations with molecular weight (Mn), time, or the number of chain scissions (n), probably as a result of microstructural differences. © 1994 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 4 (1993), S. 99-105 
    ISSN: 1042-7147
    Keywords: Proton-conducting polymer ; Sol-gel process ; Battery ; Supercapacitor ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A new proton-conducting polymer electrolyte - poly-(benzylsulfonic acid)siloxane (PBSS) - has been prepared by sol-gel process. Both the hydrolysis and the condensation reactions of triethoxybenzylsilane have been studied under different catalysis conditions. The basic material - polybenzylsiloxane (PBS) - is always soluble, no matter what the experimental conditions, reaching an average molecular weight - Mw - of 20,000 and a polydispersity index close to 5. Good yields of a water-soluble polyelectrolyte - PBSS-thermally stable up to 300°C in air according to thermogravimetric analysis (TGA), and for which the exchange capacity is close to 4.4, can be obtained by sulfonation of PBS. Conductivities ranging from 2 × 10-3 to 10-2 S/cm at room temperature have been determined by a.c. impedance spectroscopy. These high conductivities, as well as the tensile strength of the PBSS, allow its use in several electrochemical devices.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 60 (1996), S. 413-424 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The accelerated UV photodegradation process of low-density polyethylene films, formulated with two photostabilizers and two antioxidants, was studied to evaluate the effect of different combinations of UV stabilizers and antioxidants on the overall photodegradation process. An experimental design, consisting of 33 formulations with different additive ratios and a blank, was used to evaluate the performance of the four mixed additives. From each formulation, 200 micron-thick films were produced by the extrusion-blowing process. Samples from these films were submitted to accelerated UV aging, and the polymer degradation was measured by carbonyl group evolution, molecular weight distribution changes, and maximum elongation loss. The effect of the additive combination on the different degradation reactions is discussed qualitatively by using “relative variables” and a triangular diagram. © 1996 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper reports on the evaluation of a natural product, candelilla wax, as a possible lubricant for unplasticized PVC formulations stabilized with lead or barium/cadmium chemicals. The lubricant effect of two types of wax (commercial grade and purified by solvent extraction) was evaluated by torque and extrusion rheometry and by differential scanning calorimetry. Commercial lubricants (Loxiol) were used for comparison. The results show that candelilla wax may be used as a lubricant (mainly of the external type) for unplasticized PVC; however, care must be taken when designing formulations to avoid over-lubrication, specially when lead-based thermal stabilizers are used.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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